High compatibility modifier for plastic processing

A technology of compatibility and modifying agent, which is applied in the field of plastic processing aids, can solve the problems that the product performance cannot meet expectations, the performance of the modifying agent is poor, and the effect of the application of the modifying agent is affected, etc., to achieve excellent whiteness enhancement And weather resistance, good fluidity and uniformity of modification, excellent compatibility

Inactive Publication Date: 2018-12-28
NANJING CONCORD FERTILIZER CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to overcome the disadvantages of poor flexibility, high brittleness and poor impact resistance of plastic products, it is generally necessary to add plasticizers, tougheners, anti-impact agents, lubricants and other modifiers
For the processing of recycled engineering plastics, the performance requirements for modifiers must be higher. However, most of the existing modifiers have single functions and only have a certain function. Therefore, in the production process of a plastic product, it often needs Adding a variety of modifiers will virtually increase the cost of the product, not to mention the low utilization rate of raw materials and the poor performance of each modifier. Most of the performance improvement effects are poor, and the timeliness is short. The overall quality Difference
In addition, the existing modifiers contain a variety of additives with different performance improvement requirements. In the plastic production process, when used, there are problems of mutual antagonism, poor dispersion, and low utilization rate, which greatly affects the modification. Therefore, it is necessary to design a plastic processing modifier with comprehensive performance modification, high degree of coordination between raw materials, and good comprehensive compatibility and dispersion.

Method used

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  • High compatibility modifier for plastic processing

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A highly compatible modifier for plastic processing, comprising the following components in parts by weight: 10 parts of nano-calcium carbonate, 8 parts of chlorinated polyethylene, 8 parts of silicon acrylic emulsion, 4 parts of polydimethylsiloxane copolyol, 1 part of branched polyether polyol, 6 parts of polyethylene glycol, 0.5 part of ethyl p-aminobenzoate, 0.5 part of heat stabilizer, 0.5 part of coupling agent, and 0.3 part of surfactant.

[0022] Among them: the grafted polyether polyol is made of methacrylate grafted polyether polyol, and the hydroxyl value is 34.5±0.3mgKOH / g; the heat stabilizer is compounded with calcium zinc stabilizer and organotin stabilizer, the quality The ratio is 1:0.8; the coupling agent is compounded with silane coupling agent and titanate coupling agent, and the mass ratio of the two is 1:3, of which A151 is used as the silane coupling agent, and TMC is used as the titanate coupling agent -105, TMC-114, TMC-TE composition, the molar...

Embodiment 2

[0029] A highly compatible modifier for plastic processing, comprising the following components in parts by weight: 5 parts of nano-calcium carbonate, 8 parts of chlorinated polyethylene, 5 parts of silicon acrylic emulsion, 4 parts of polydimethylsiloxane copolyol, 2 parts of branched polyether polyol, 6 parts of polyethylene glycol, 0.6 part of ethyl p-aminobenzoate, 0.4 part of heat stabilizer, 0.8 part of coupling agent, and 0.2 part of surfactant.

[0030] Among them: the grafted polyether polyol is made of methacrylate grafted polyether polyol, and the hydroxyl value is 34.5±0.3mgKOH / g; the heat stabilizer is compounded with calcium zinc stabilizer and organotin stabilizer, the quality The ratio is 1:0.5; the coupling agent is compounded with silane coupling agent and titanate coupling agent, and the mass ratio of the two is 1:2, of which A151 is used as the silane coupling agent, and TMC is used as the titanate coupling agent -105, TMC-114, TMC-TE composition, the molar...

Embodiment 3

[0037] A high-compatibility modifier for plastic processing, comprising the following components in parts by weight: 12 parts of nano-calcium carbonate, 6 parts of chlorinated polyethylene, 8 parts of silicon-acrylic emulsion, 3 parts of polydimethylsiloxane copolyol, 1.5 parts of branched polyether polyol, 6 parts of polyethylene glycol, 1 part of ethyl p-aminobenzoate, 0.5 part of heat stabilizer, 0.5 part of coupling agent, and 0.3 part of surfactant.

[0038] Among them: the grafted polyether polyol is made of methacrylate grafted polyether polyol, and the hydroxyl value is 34.5±0.3mgKOH / g; the heat stabilizer is compounded with calcium zinc stabilizer and organotin stabilizer, the quality The ratio is 1:0.6; the coupling agent is compounded with silane coupling agent and titanate coupling agent. The composition of TMC-105, TMC-114, and TMC-TE is selected, and the molar ratio of the three is 1:1:0.5; the surfactant is a combination of sorbitan monostearate and N-acyl amino...

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Abstract

The invention provides a high compatibility modifier for plastic processing. The high compatibility modifier for plastic processing comprises, by weight parts, 5-15 parts of nano calcium carbonate, 5-10 parts of chlorinated polyethylene, 5-10 parts of silicone acrylic emulsion, 2-5 parts of dimethicone copolyol, 0.5-2 parts of grafted polyether polyol, 3-10 parts of polyethylene glycol, 0-1 part of ethyl p-aminobenzoate, 0-1 part of heat stabilizer, 0-1 part of coupling agent and 0-0.5 part of surfactant. Through the reasonable raw material ratio, the made modifier has excellent dispersibilityand compatibility for plastic processing and improves plastic product quality stability. In addition, the high compatibility modifier also has excellent weather resistance, UV resistance and toughness, the comprehensive quality is obviously improved, the practical benefit is improved, and the high compatibility modifier is worth promoting.

Description

technical field [0001] The invention relates to the technical field of plastic processing aids, in particular to a highly compatible modifier for plastic processing. Background technique [0002] Polyvinyl chloride (PVC) is one of the five general-purpose synthetic resins in synthetic materials, and its output is second only to polyethylene, ranking second. PVC is one of the most widely used plastics in the world. Only half of the raw material comes from petroleum, and the other half comes from rich ore, so it is widely used in construction industry, packaging materials, household daily necessities and automobile industry. However, the recycling problem of PVC and the potential impact on the environment have not been solved, and the restrictions on PVC still exist in many occasions. Therefore, attention must still be paid to the application development and recycling of PVC. At present, in order to reduce the industrial hazards of PVC plastics as much as possible, most PVC ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/28C08L33/04C08L51/08C08L71/02C08K3/26C08K5/18C08K5/57C08K13/02
CPCC08L23/286C08K2003/265C08K2201/011C08L43/04C08L71/02C08L2201/08C08L2205/035C08L51/08C08K3/26C08K5/18C08K5/57C08K13/02
Inventor 黄艳
Owner NANJING CONCORD FERTILIZER CHEM
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