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A kind of chromium carbide gradient composite coating and preparation method thereof

A composite coating and chromium carbide technology, which is applied in the field of composite wear-resistant chromium carbide coating and its preparation, composite wear-resistant carbide coating and its preparation, can solve the problem of thin reaction layer, strict control of type and content, Cladding coatings are prone to cracks and other problems, achieving the effect of simple composition, improved mechanical properties, and easy control of the thickness of the reaction layer

Active Publication Date: 2020-08-04
XIAN UNVERSITY OF ARTS & SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the cladding process, there are still the following problems that need to be solved urgently: (1) Due to the large temperature gradient between the cladding coating and the substrate, and the large performance difference between the alloy powder and the substrate material, the cladding coating The layer is prone to defects such as cracks and pores, so the types and contents of various alloying elements in the cladding alloy powder need to be strictly controlled; (2) The thickness of the reaction layer is relatively thin, which cannot well meet the requirements of use; (3) Due to the overall reaction Complete in an instant, the thickness of the reaction layer cannot be controlled

Method used

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  • A kind of chromium carbide gradient composite coating and preparation method thereof
  • A kind of chromium carbide gradient composite coating and preparation method thereof

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preparation example Construction

[0034] Such as figure 1 Shown, the preparation method of chromium carbide gradient composite coating of the present invention comprises the steps:

[0035] 1) After pickling the surface of the metal substrate sequentially, select 800 mesh Al 2 o 3 Sanding, rust removal with sandpaper, and then ultrasonic cleaning with alcohol or acetone; the metal substrate is low carbon steel 15 or 20 or low carbon alloy steel 15Cr, 20Cr, 20Mn2, 20MnV, 20CrMn, 20CrMnTi, 20MnTiB, 20MnVB, 18Cr2Ni4WA, 20Cr2Ni4 or 12Cr2Ni4 ; The metal matrix structure is one or more of pearlite, martensite, ferrite, bainite, austenite and sorbite according to the different heat treatment methods.

[0036] 2) Coat a layer of carburizer with a thickness of 0.2-1.0mm on the surface of the metal substrate after derusting and cleaning, adjust the carburizer to a fine paste with alcohol or acetone, and then coat it on low-carbon steel or low-carbon alloy Steel surface; Carburizer chooses any one of HYCPC-01, HYCPC-0...

Embodiment 1

[0050] 1) First, carry out surface derusting (pickling) on ​​the surface of 15 steel to be surface strengthened. The first step of pickling is to use 300ml / L hydrochloric acid, and then rinse with running water; the second step is to use 300ml / L hydrofluoric acid for pickling Acid, then rinse with running water; the third step is surface grinding, using 800 mesh Al 2 o 3 sandpaper, and finally ultrasonically cleaned with alcohol;

[0051] 2) Then apply a layer of recarburizing agent HYCPC-01 on the surface of 15 steel, and adjust it to a thin paste with alcohol;

[0052] 3) Apply the recarburizing agent on the surface of 15 steel with a thickness of 0.2mm; then coat it with a layer of thermal insulation coating with a thickness of 1mm;

[0053] Its thermal insulation coating composition is: sodium silicate nine hydrate 10%, deionized water 40%, nano-SiO 2 2%, hollow ceramic microspheres 25%, aluminum silicate fibers 3%, SiO 2 Airgel slurry 8%, potassium hexatitanate whiske...

Embodiment 2

[0062] 1) First carry out surface derusting (pickling) on ​​the 20Cr to be surface strengthened. The first step of pickling is to use 300ml / L hydrochloric acid, and then rinse with running water; the second step is to use 300ml / L hydrofluoric acid for pickling , and then washed with running water; the third step is surface grinding, using 800 mesh Al 2 o 3 sandpaper, and finally ultrasonically cleaned with alcohol;

[0063] 2) Then apply a layer of carburant HYCPC-02 on the surface of 20Cr, and adjust it to a thin paste with acetone;

[0064] 3) Apply the recarburizing agent on the surface of 20Cr, and then apply a layer of thermal insulation coating on it, with a thickness of 0.8mm; wherein, the thickness of the thermal insulation coating is 1.5mm;

[0065] Its thermal insulation coating composition is: sodium silicate nine hydrate 10%, deionized water 30%, nano-SiO 2 4%, hollow ceramic microspheres 20%, aluminum silicate fibers 9%, SiO 2 Airgel slurry 17%, potassium hexa...

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Abstract

The invention discloses a chromium carbide gradient composite coating and a preparation method thereof. The preparation method comprises the following steps: carrying out surface treatment on a metalmatrix, preparing a recarburizing agent, coating the recarburizing agent and an insulated coating on the surface, recarburizing the surface layer, conveying chromium-iron powder to the surface of themetal matrix, pre-drying, carrying out laser scanning, carrying out multi-overlapping cladding, preserving heat, cooling along with a furnace and obtaining a composite wear-resistant chromium-carbidecoating on the surface of the metal matrix. The composite wear-resistant chromium-carbide coating comprises a Cr7C3 dense ceramic layer and also further comprises a composition area of granular (Fe, Cr)7C3 type chromium carbide and the matrix, a composition area of lath-shaped (Fe, Cr)7C3 type chromium carbide and the matrix and a ferrite area with less carbon content and chromium content, all theareas are in gradient distribution, and the composite wear-resistant chromium-carbide coating can be applied on the surface of the metal matrix. The gradient composite coating disclosed by the invention has the beneficial effects that an external carbon source is externally introduced on the metal matrix obtained by laser cladding and a chromium composition, then heating and insulation are carried out, the composite wear-resistant chromium-carbide coating is formed on the surface of the metal matrix, and metallurgical bonding is adopted between the coating and the matrix, so that the bondingforce is very strong, and the wear resistance of the surface of the metal matrix is greatly improved.

Description

technical field [0001] The invention relates to a wear-resistant coating and a preparation method thereof, in particular to a composite wear-resistant chromium carbide coating and a preparation method thereof, in particular to a composite wear-resistant carbonization applied to the surface of low-carbon steel or low-carbon alloy steel Coatings and their preparation methods. Background technique [0002] Carbide has the characteristics of high hardness and excellent wear resistance. Covering the surface of the metal alloy substrate by coating can improve the wear resistance and life of the parts made of the substrate material. Chromium is a strong carbide-forming element. The in-situ reaction between metal chromium and carbon can generate different types of chromium carbides. The common types of carbide chromium are Cr 3 C 2 、Cr 7 C 3 、Cr 23 C 6 Three, their formation conditions and microstructure have been recognized by materials scholars. where Cr 7 C 3 Type carbid...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C28/00C23C8/66C23C24/10
CPCC23C8/66C23C24/103C23C28/325C23C28/341
Inventor 叶芳霞
Owner XIAN UNVERSITY OF ARTS & SCI