Preparation method of fireproof material

A refractory material and refractory technology, applied in the field of refractory materials, can solve problems such as reducing the service life of refractory materials, increasing the damage rate of refractory products, and affecting thermal shock resistance, so as to improve thermal shock resistance, small reburning line changes, Effect of low thermal expansion coefficient

Inactive Publication Date: 2019-01-25
湖州南浔研艺斋工艺品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The poor mechanical toughness of inorganic non-metallic materials is a common problem in inorganic non-metallic materials and materials. As refractory materials that belong to inorganic non-metallic materials, their mechanical toughness is also poor. However, its poor mechanical toughness also affects its thermal shock resistance at high temperatures. Due to the large temperature difference between rapid cooling and rapid heating and use, refractory materials are prone to cracking and peeling under the action of thermal expansion and contraction. The situation that affects the integrity of refractory materials reduces the service life of refractory materials; at the same time, for those refractory products that need to be moved frequently, their poor mechanical toughness will greatly increase the damage rate of refractory products and affect their daily use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A method for preparing a refractory material, comprising the following preparation steps:

[0025] a. Mix the carbonaceous material, refractory base material and alumina into a ball mill tank for 3 hours, then add an organic solvent, and stir evenly to obtain a slurry;

[0026] b. Mix partly stabilized zirconia, zirconium carbide particles, acrylic amine, methylenebisacrylamide and ammonium persulfate, introduce it into a high mixer, stir at a speed of 3000r / min for 10-15min, and then use ultrasonic oscillation for 20min , after uniform dispersion, material 1 was obtained;

[0027] c. Add catalyst and binder to material 1, stir and dissolve at 60°C for 10 minutes, then introduce the slurry, heat and stir at 90°C for 20 minutes to obtain a green body;

[0028] d. Put the green body in a constant temperature drying oven at 70°C, dry it for 20 minutes, crush it to pass through a 200-mesh sieve, perform secondary drying treatment, and then cool it and press it to form a fi...

Embodiment 2

[0037] A method for preparing a refractory material, comprising the following preparation steps:

[0038] a. Mix the carbonaceous material, refractory base material and alumina into a ball mill tank for 3 hours, then add an organic solvent, and stir evenly to obtain a slurry;

[0039] b. Mix partly stabilized zirconia, zirconium carbide particles, acrylic amine, methylenebisacrylamide and ammonium persulfate, introduce into a high-mixer, stir at a speed of 2000r / min for 10min, and then use ultrasonic oscillation for 20min to disperse After uniformity, material 1 is obtained;

[0040] c. Add catalyst and binder to material 1, stir and dissolve at 60°C for 5 minutes, then introduce the slurry, heat and stir at 80°C for 20 minutes to obtain a green body;

[0041] d. Put the green body in a constant temperature drying oven at 60°C, dry it for 15 minutes, crush it to pass through a 200-mesh sieve, perform secondary drying treatment, and then cool it and press it to form a finished...

Embodiment 3

[0050]A method for preparing a refractory material, comprising the following preparation steps:

[0051] a. Mix the carbonaceous material, refractory base material and alumina into a ball mill tank for 5 hours, then add an organic solvent, and stir evenly to obtain a slurry;

[0052] b. Mix partly stabilized zirconia, zirconium carbide particles, acrylic amine, methylene bisacrylamide and ammonium persulfate, introduce into a high-mixer, stir at a speed of 3000r / min for 15min, and then use ultrasonic oscillation for 25min to disperse After uniformity, material 1 is obtained;

[0053] c. Add catalyst and binder to material 1, stir and dissolve at 80°C for 10 minutes, then introduce the slurry, heat and stir at 90°C for 25 minutes to obtain a green body;

[0054] d. Put the green body in a constant temperature drying oven at 70°C, dry it for 20 minutes, crush it to pass through a 300-mesh sieve, perform secondary drying treatment, and then cool it and press it to form a finishe...

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Abstract

The invention provides a preparation method of a fireproof material. The method comprises the following preparation steps: a, mixing a carbon-containing material, a fireproof base material and aluminum oxide; guiding the mixture into a ball milling tank; performing ball milling; then, adding an organic solvent; stirring to obtain slurry; b, mixing partial stable zirconium oxide, zirconium carbideparticles, acrylated amine, methylene bisacrylamide and ammonium persulfate; guiding the materials into a high mixing machine; performing stirring and ultrasonic oscillation to obtain a first material; c, adding a catalyst and a bonding agent into the first material; performing stirring and dissolution; then, guiding the slurry; heating and stirring to obtain a blank; d, drying and crushing the blank; then, performing secondary drying treatment; next, performing cooling and pressing shaping. Compared with a conventional fireproof material, the prepared fireproof material has the advantages that the air porosity is lower; the bulk density is higher; the expansion rate and the linear change on reheating are smaller; the stability is better; the heat shock performance is more excellent; the wear-resistant performance is better.

Description

technical field [0001] The invention belongs to the technical field of refractory materials, and in particular relates to a preparation method of refractory materials. Background technique [0002] In the traditional sense, refractory materials refer to inorganic non-metallic materials with a refractoriness of not less than 1580 °C. And parts of the material, and can withstand the corresponding physical and chemical changes and mechanical action. [0003] Most refractory materials are made of natural ores (such as refractory clay, silica, magnesite, dolomite), and some industrial raw materials and synthetic raw materials (such as industrial alumina, silicon carbide, synthetic mullite, Synthetic spinel, etc.) are also increasing, so there are many types of refractory materials. According to the mineral composition, refractories can be divided into silica, aluminum silicate, magnesia, dolomite, olivine, spinel, carbonaceous, zirconium-containing refractories and special refr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66
CPCC04B35/66
Inventor 郑晓明
Owner 湖州南浔研艺斋工艺品有限公司
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