Double-layer solid film pre-coated on surface of stamp-forming sheet and preparation method of double-layer solid film

A technology of stamping and forming, solid film, applied in the direction of coating, conjugated diene coating, anti-corrosion coating, etc., can solve the problem that the lubricating performance of aluminum alloy stamping has not been evaluated in depth, the dispersion of lubricant imparting agent has not been explained, and it is disadvantageous. Large-scale industrial production and other problems, to achieve the effects of excellent protection ability, reduced mold wear, and good weather resistance

Active Publication Date: 2019-04-26
WUHAN RES INST OF MATERIALS PROTECTION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] However, in the current invention of solid lubricants for stamping aluminum alloy sheets, these problems have not been fully considered
For example, CN100509181C discloses a resin lubricating film containing polyethylene glycol and paraffin. Although the lubricating film can provide better stamping lubrication performance, the preparation process is relatively complicated, which is not conducive to large-scale industrial production, and the resin after stamping is finished. Alkaline solution must be used to remove
However, the aluminum alloy is very easy to react chemically with the alkali solution, which will cause corrosion on the surface of the formed part and affect the surface quality of the formed part.
In addition, the patent does not describe the dispersion of the lubricating agent
CN102808169A discloses a method for lubricating aluminum alloys. On the basis of the phosphating treatment of aluminum alloys, the method is placed in fatty sodium to form a layer of sodium stearate as a lubricant, although the method improves the phosphating layer and the matrix binding force, but the processing method is more complex and cumbersome, and the stamping lubrication performance of processing aluminum alloys has not been evaluated in depth

Method used

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  • Double-layer solid film pre-coated on surface of stamp-forming sheet and preparation method of double-layer solid film
  • Double-layer solid film pre-coated on surface of stamp-forming sheet and preparation method of double-layer solid film
  • Double-layer solid film pre-coated on surface of stamp-forming sheet and preparation method of double-layer solid film

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preparation example Construction

[0038] Preparation of bilayer solid films

[0039] The surface of the aluminum alloy cup sample plate is degreased, washed and dried.

[0040] After adding lubricity imparting agent A and wetting and dispersing agent C to organic coating B, adding diluent to dilute, and mixing by mechanical stirring, the weight percentage of each component satisfies the scope of the present invention. There is no particular limitation on the coating method of the organic lubricating layer 2 of the present invention, and a dipping method, a spraying method and other methods can be used, and it should be noted that the coating thickness is between 5 and 35 microns. After coating, the lubricating layer is dried and cured after natural surface drying at room temperature for 10 minutes. Subsequently, the organic coating D is added to another diluent, and it is completely dissolved by mechanical stirring, and is uniformly coated on the surface of the prepared solid lubricating layer by dipping meth...

Embodiment

[0055] In the organic lubricating layer 2, the lubricating imparting agent is selected as polytetrafluoroethylene particles with an average particle diameter of 2.8 microns, and the number of parts by mass is selected as 15 parts. The organic coating is selected as polyvinyl butyral, and the number of parts by mass is selected as 83.5 parts. Disponer 904S was selected as the dispersant, 1 part by mass, and Defom 6500 was selected as the defoamer, 0.5 part by mass. The organic coating in the protective layer 1 is a butadiene-styrene copolymer, and the number of parts by mass is selected as 100 parts. The prepared solid lubricating film was coated on the same aluminum alloy disc sample as that of Comparative Example 1 and Comparative Example 2 to perform a cupping test. The dispersion of the lubricant imparting agent was detected by the Micromeasure2 white light confocal three-dimensional topography instrument produced by the French STIL company. The detection parameters were sc...

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Abstract

The invention discloses a double-layer solid film pre-coated on the surface of a stamp-forming sheet and a preparation method of the double-layer solid film. The double-layer solid film comprises an organic lubrication layer coated on the surface of an aluminum alloy sheet and a protective layer coated on the surface of the organic lubrication layer; the organic lubrication layer comprises a lubrication performance endowing agent A, an organic coating B served as a lubrication endowing agent binder and a wetting dispersant C for improving the dispersity of the lubrication performance endowingagent A; the protective layer is an organic coating D for improving the acid-base corrosion resistance of the organic lubrication layer. The preparation method comprises the following steps: firstly,adding the lubrication endowing agent A and the wetting dispersant C into the organic coating B, uniformly mixing and coating a mixture on the surface of a to-be-lubricated material, and carrying outnatural surface drying to form the organic lubrication layer; then coating the organic coating D served as the protective layer on the organic lubrication layer to form the double-layer solid film. The double-layer solid film disclosed by the invention has the advantages of being high in acid-base corrosion resistance, weather resistance, and lubrication performance, and easy to remove after stamping; in addition, the surfaces of the sheet and a mold are protected and formed parts have excellent surface quality.

Description

technical field [0001] The invention belongs to the auxiliary technical field of stamping and forming of aluminum alloy plates, relates to a surface lubricating film for stamping and forming of aluminum alloy plates, and in particular relates to a double-layer solid film pre-coated on the surface of stamping and forming plates and a preparation method thereof. Background technique [0002] Due to the special requirements for strength, formability, surface accuracy, bake hardening, etc. of automotive aluminum sheet coverings, the lubrication process in the simple transplanting of the original steel sheet stamping is very prone to defects, which not only cannot meet the manufacturing requirements, but also bring resources. waste and environmental pollution. At present, countries all over the world are strengthening the basic research on the surface treatment of aluminum alloy sheets for vehicles and lubricating materials, and have formed a series of lubricating material produc...

Claims

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Application Information

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IPC IPC(8): C09D129/14C09D127/18C09D7/40C09D109/06C09D5/08
CPCC09D109/06C09D129/14C09D5/08C09D7/40
Inventor 段海涛凃杰松李健詹胜鹏贾丹顾卡丽魏雷
Owner WUHAN RES INST OF MATERIALS PROTECTION
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