Unlock instant, AI-driven research and patent intelligence for your innovation.

A method for preparing color-controllable transparent glass ceramics by using silicomanganese slag

A technology of transparent glass and silicomanganese slag, which is applied in glass furnace equipment, glass manufacturing equipment, manufacturing tools, etc., can solve problems such as complex composition, accelerated crystallization of basic glass, and reduced glass viscosity, so as to achieve simple preparation method and comprehensive Utilization, the effect of short experiment period

Active Publication Date: 2020-11-20
UNIV OF SCI & TECH BEIJING
View PDF1 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The problem about the comprehensive utilization of silicomanganese slag is that the main chemical component in silicomanganese slag is SiO 2 and CaO, followed by Al 2 o 3 , MgO and MnO
However, the composition of silicomanganese slag is relatively complex, SiO 2 The content of CaO and CaO is very high, and the amount of CaO required in the glass composition is small, so adding a certain amount of slag will make the CaO in the raw material relatively surplus, reduce the viscosity of the glass, and eventually lead to accelerated crystallization of the base glass during heat treatment Devitrification of glass ceramics due to growth
Compared with transparent glass-ceramics prepared with all pure raw materials, silicomanganese slag has complex chemical composition and phase, and is irreproducible under the same raw material ratio and heat treatment system. No report

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A method for preparing color-controllable transparent glass ceramics by using silicomanganese slag
  • A method for preparing color-controllable transparent glass ceramics by using silicomanganese slag
  • A method for preparing color-controllable transparent glass ceramics by using silicomanganese slag

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Firstly, the massive silicomanganese slag is crushed into powder in a magnetic vibrating crusher, and sieved through a 200-mesh sieve. Weigh 10% silicon manganese slag, 29.62% silicon dioxide, 28.84% aluminum oxide, 4.57% magnesium oxide, 1.54% calcium oxide and 25.43% calcium fluoride respectively by mass percentage. The above raw materials are mixed evenly, placed in an alumina crucible, and kept in a high-temperature melting furnace at 1400°C for 3 hours to obtain a high-temperature liquid. Then the high-temperature liquid was quickly poured into a stainless steel mold preheated at 500°C, kept in a muffle furnace at 500°C for 6 hours, and then cooled to room temperature to obtain a transparent basic glass. The base glass was cut into 1mm-thick sheets with a cutting machine, and then placed in a tube furnace at 630°C for heat treatment and kept for 1 hour to obtain transparent glass ceramics. The obtained flake glass ceramics were characterized after being ground and...

Embodiment 2

[0032] Firstly, the massive silicomanganese slag is crushed into powder in a magnetic vibrating crusher, and sieved through a 200-mesh sieve. Weigh 20% silicon manganese slag, 24.59% silicon dioxide, 26.85% aluminum oxide, 2.76% magnesium oxide, 1.05% calcium oxide and 24.75% calcium fluoride respectively according to mass percentage. Mix the above raw materials evenly, place them in an alumina crucible, and keep them in a high-temperature melting furnace at 1450°C for 2 hours to obtain a high-temperature liquid. Then the high-temperature liquid was quickly poured into a stainless steel mold preheated at 550°C, kept in a muffle furnace at 550°C for 5 hours, and then cooled to room temperature to obtain a transparent basic glass. The basic glass was cut into 1mm-thick sheets with a cutting machine, and then placed in a tube furnace at 680°C for heat treatment and kept warm for 2 hours to obtain transparent glass ceramics. The obtained flake glass ceramics were characterized af...

Embodiment 3

[0035] Firstly, the massive silicomanganese slag is crushed into powder in a magnetic vibrating crusher, and sieved through a 200-mesh sieve. Weigh 30% silicomanganese slag, 21.15% silicon dioxide, 23.03% aluminum oxide, 2.26% magnesium oxide and 23.56% calcium fluoride respectively by mass percentage. The above raw materials are mixed evenly, placed in an alumina crucible, and kept in a high-temperature melting furnace at 1480° C. for 1 hour to obtain a high-temperature liquid. Then the high-temperature liquid was quickly poured into a stainless steel mold preheated at 600°C, kept in a muffle furnace at 600°C for 4 hours, and then cooled to room temperature to obtain a transparent basic glass. The basic glass was cut into 1mm-thick sheets with a cutting machine, and then placed in a tube furnace at 710°C for heat treatment and kept for 3 hours to obtain transparent glass ceramics. The obtained flake glass ceramics were characterized after being ground and polished on both si...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
transmittivityaaaaaaaaaa
transmittivityaaaaaaaaaa
transmittivityaaaaaaaaaa
Login to View More

Abstract

The invention relates to a method for preparing a color-adjustable transparent glass ceramic from silicomanganese slag, belongs to the technical field of synthesis of inorganic nonmetallic materials,and particularly relates to the field of preparing functional glass ceramics from solid wastes. The color-adjustable transparent glass ceramic is mainly prepared from the silicomanganese slag, silicondioxide, calcium oxide, magnesium oxide, aluminum oxide and calcium fluoride, wherein the calcium fluoride is used as a nucleating agent. By adding different quantity of silicomanganese slag, the color-adjustable transparent glass ceramic is finally prepared by using a basic glass heating method. The method has the advantages that the basic glass heating method is used as the preparation method,the operation method is simple, and the preparation period is relatively short; the utilization rate of the raw material silicomanganese slag is effectively improved, comprehensive utilization of thesolid wastes is achieved, and environmental pollution is reduced. The functional element manganese in the slag is utilized, it is achieved that the color of the product is adjusted, and on the basis of utilizing the slag, high-value of utilization of the slag is achieved.

Description

technical field [0001] The invention relates to the technical field of synthesis of inorganic non-metallic materials, in particular to the field of preparing functional glass ceramics from solid waste. Background technique [0002] Silicon-manganese alloy is mainly composed of silicon, iron, manganese and a small amount of carbon. It is a ferroalloy with wide application and large output. Silicon-manganese alloy is a compound deoxidizer commonly used in steelmaking, and it is also a reducing agent for the production of medium and low carbon ferromanganese and the production of metal manganese by electrosilicothermal method. Silico-manganese slag is a kind of porous granular or dense block formed by water quenching or air cooling of the high-temperature slag discharged when ferroalloy enterprises use manganese ore, manganese-rich slag, lime, coke, silica and other raw materials to smelt silicon-manganese alloys in submerged arc furnaces. Green industrial waste. According to...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C03C10/16C03C6/10C03B5/16C03B25/00C03B32/02
CPCC03B5/16C03B25/00C03B32/02C03C1/002C03C10/0036C03C10/0063C03C10/16
Inventor 张梅郭敏苗希望唐书杰刘磊
Owner UNIV OF SCI & TECH BEIJING