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A kind of resin material for oil and gas well casing plugging and preparation method thereof

A technology of resin materials and oil and gas wells, applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve problems such as inability to cure at right angles, insufficient air tightness, cracks, etc., to facilitate ground construction operations and simple and easy construction process The effect of small line and volume change rate

Active Publication Date: 2021-03-09
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Casing subsidy technology can easily cause the diameter of the casing to shrink, which brings inconvenience to the later operation
Conventional chemical plugging mainly relies on cement, and its main problems are low compressive strength, pressure wells cannot be injected into the annulus, and cement is easy to shrink, resulting in cracks or micro-cracks, resulting in poor cement quality and other problems
Conventional gel and thermosetting resin plugging agent systems also have the following problems: (1) the amount of plugging agent used is large, and the construction cost is high; (2) the system cannot be cured at right angles, and the volume shrinks, resulting in water-proof sealing; (3) after curing Insufficient pressure bearing capacity and other issues, especially the complete wellbore of 55MPa required for horizontal well fracturing
[0003] Chinese Patent No.: CN106800389A discloses a high wall-building sealing channeling plugging agent, which is mainly cement, there are cracks after curing, and the air tightness is insufficient; Chinese Patent No.: CN 108166944 A discloses a kind of oil and gas well damage Casing repair method and rapid fluid loss plugging slurry, which is a pre-filter loss system such as walnut shells and fibers, followed by a gel system based on ABS resin, and its compressive strength can reach oil well production or drilling plugging , failing to meet the fracturing requirements after casing repair
Chinese Patent No.: CN 107474808 A discloses a resin plugging agent for casing plugging in oil and gas wells. The plugging agent is based on industrial urea formaldehyde and curing agent. Its own strength is low and its compressive strength is insufficient.

Method used

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  • A kind of resin material for oil and gas well casing plugging and preparation method thereof
  • A kind of resin material for oil and gas well casing plugging and preparation method thereof
  • A kind of resin material for oil and gas well casing plugging and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A resin material for oil and gas well casing plugging, including polyester resin, curing agent, filler, coupling agent, additive and polyol solvent; the proportion of each composition is: 65%-85% polyester resin , 0.6%-3% curing agent, 3%-5% filler, 0.5%-1.5% coupling agent, 1%-3% additive, and the rest are polyol solvents; the polyester resin is ethylene One or more of methyl toluene, vinyl acetate, terephthalic acid, and trimellitic anhydride.

[0034] In actual use, the initial viscosity is 20-80mPa·s, the system undergoes a polymerization and curing reaction, and the gap between the formation and the casing is cemented and sealed. The curing time is 4-24 hours at a reservoir temperature of 50-70°C. Pressure resistance 15-65MPa can be adjusted according to specific construction requirements.

[0035] The resin material for oil and gas well casing leak plugging of the present invention has high strength, good cementation, and a small volume change rate, and is not on...

Embodiment 2

[0037] A resin material for oil and gas well casing plugging, which is different from Embodiment 1 in that the curing agent is one or more of naphthalene peroxide, benzoyl peroxide, and cyclohexanone peroxide.

[0038] In actual use, the curing agent is one or more technical solutions in naphthalene peroxide, benzoyl peroxide, and cyclohexanone peroxide, which can reduce the viscosity of the corresponding resin, make it fluid, and have good Injection.

Embodiment 3

[0040] A resin material for oil and gas well casing plugging, which is different from Embodiment 1 in that the filler is one or more of silicon dioxide, calcium carbonate, and mica powder.

[0041] In actual use, the filler is one or more technical solutions of silicon dioxide, calcium carbonate, and mica powder, which effectively enhances the mechanical properties of the resin material for plugging.

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Abstract

The invention belongs to the technical field of petroleum exploitation, and in particular relates to a resin material for leakage plugging of oil and gas well casings and a preparation method thereof. The present invention prepares polyester with a mass percentage of 65%-85% through five steps of preparing a polyester resin mixture, adding a coupling agent, adding a curing agent, adding a filler, adding an additive and a polyol solvent. Resin, 0.6%-3% curing agent, 3%-5% filler, 0.5%-1.5% coupling agent, 1%-3% additive, and the rest is polyol solvent for oil and gas well casing plugging Resin material. The invention has high strength, good cementation and small volume change rate, and is not only suitable for leak plugging of casing damage in production wells, but also suitable for plugging of casing damage in fracturing of new wells and plugging of old fractures in old wells. The invention has low initial viscosity, and after shearing, the viscosity decreases, which is convenient for ground construction operation, and the viscosity is gradually increased to solidification after reaching the reservoir. The raw materials used in the invention are easy to obtain, the preparation process is simple, and the construction process is simple and easy.

Description

technical field [0001] The invention belongs to the technical field of petroleum exploitation, and in particular relates to a resin material for leakage plugging of oil and gas well casings and a preparation method thereof. Background technique [0002] With the increase of the production life of multi-layer oilfields, coupled with the influence of geological conditions and engineering factors, casing damage and leakage of fluid outside the casing often occur, which affects the stable production of the oilfield and the smooth implementation of the development plan, and even causes production shutdown, seriously affecting It improves the effective water injection and ultimate recovery of the reservoir. Casing deformation of oil and water wells is aggravated, which increases the cost of workover and production operations. At present, the commonly used channeling and leakage sealing technologies mainly include casing subsidy and chemical leakage sealing. Casing subsidy techno...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/42C08G63/183C08G63/127C08F112/12C08F118/08C08F2/44
CPCC08F2/44C08F112/12C08F118/08C08G63/127C08G63/183C09K8/426
Inventor 郭钢戚建晶杨立华李明星程碧海孙雨来卢文伟姜毅杨会丽
Owner PETROCHINA CO LTD
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