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Graphene wave absorbing composite material with high thermal conductivity and preparation method thereof

A technology of high thermal conductivity graphite and composite materials, applied in radiation-absorbing coatings, epoxy resin coatings, unspecified rubber coatings, etc., can solve the problems of poor surface elasticity, fragility, and low thermal conductivity of materials, and achieve strong tensile strength Effects of performance, toughness and hardness

Inactive Publication Date: 2019-08-23
常州威斯双联科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at present, the main preparation method of graphene and wave-absorbing materials is to simply add graphene to the wave-absorbing agent, and obtain a graphene-like wave-absorbing film through carbonization and graphitization, and the thermal conductivity of the graphene-like wave-absorbing film prepared by this method Low, the surface elasticity of the material is poor and fragile, and it is prone to fragmentation when used with devices. Therefore, the graphene-based wave-absorbing film prepared by this method has been hindered in practical applications, and the technology needs to be improved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A high thermal conductivity graphene wave-absorbing composite material, using self-made wave-absorbing material as a substrate, the substrate is coated with several graphene film layers, and the raw materials of the graphene film layers include: graphene, organic polymer solution, resin, Its mass parts composition is as follows: (0.1-10) : (1-20 ) : (0.5-1).

[0023] The preparation method of the above-mentioned high thermal conductivity graphene wave-absorbing composite material is as follows: adding 1g of single-layer graphene to 200g acrylic acid solution, adding 0.3g KH550 and 0.5g rosin and mixing to obtain graphene / acrylic acid solution, and adding 150 g of acrylic acid solution. o C, coating and drying at a speed of 10m / min to obtain a 5μm graphene film, and the graphene film was dried at 400N, 200 o Under the condition of C, it is pressed with a wave absorbing material with a thickness of 5 μm and a magnetic permeability of 240 for 0.5 hours to obtain a graphene...

Embodiment 2

[0025] The high thermal conductivity graphene wave-absorbing composite material in this embodiment is the same as that in Embodiment 1.

[0026] The preparation method of above-mentioned high thermal conductivity graphene wave-absorbing composite material is as follows: adding 100g multi-layer graphene to 10g rubber solution, adding 200g toluene, 0.5g KH550 and 1g dicyclopentadiene resin and mixing to obtain graphene / rubber solution, 60 o C, coating and drying at a speed of 10 m / min to obtain a 100 μm graphene film. o Under the condition of C, it is laminated with a wave absorbing material with a thickness of 100 μm and a magnetic permeability of 280 for 24 hours to obtain a graphene wave absorbing material with a thickness of 80 μm. The graphene wave absorbing material prepared by the above preparation method has a magnetic permeability of 280 and a thermal conductivity of 3000 W / m.k.

Embodiment 3

[0028] The high thermal conductivity graphene wave-absorbing composite material in this embodiment is the same as that in Embodiment 1.

[0029] The preparation method of above-mentioned high thermal conductivity graphene wave-absorbing composite material is as follows: adding 50g graphene oxide to 100g epoxy resin solution, adding 130g toluene, 0.5g KH550 and 1g rosin, 5g dicyclopentadiene resin, 2g alkyl phenolic The resin was mixed to obtain a graphene / epoxy resin solution at 80 o C, coating and drying at a speed of 8 m / min to obtain a 200 μm graphene film. o Under the condition of C, it is laminated with a wave absorbing material with a thickness of 200 μm and a magnetic permeability of 280 for 12 hours to obtain a graphene wave absorbing material with a thickness of 300 μm. The graphene wave absorbing material prepared by the above preparation method has a magnetic permeability of 280 and a thermal conductivity of 2500 W / m.k.

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Abstract

The invention belongs to the technical field of composite materials, in particular to a graphene wave absorbing composite material with high thermal conductivity and a preparation method thereof. Thecomposite material is based on a wave absorbing material, and a plurality of graphene film layers are coated on the substrate. The raw materials of the graphene film layer include graphene, an organicpolymer solution and a resin, and the mass components of the graphene film layer are as follows: (0.1-10): (1-20): (0.5-1); the high thermal conductivity graphene wave absorbing composite material ofthe invention adopts the graphene film and the wave absorbing material to prepare the graphene wave absorbing material, and the performance of the wave absorbing material is not affected, and the heat dissipation performance of the whole wave absorbing material is greatly improved because of the excellent thermal conductivity of the graphene; the high thermal conductivity graphene wave absorbingcomposite material of the invention adopts a multi-layer coating mode, which is different from the traditional graphene as an additive, and the surface of the prepared graphene wave absorbing materialhas stronger toughness and hardness, and can be applied to various kinds of machining without fragmentation or deformation.

Description

technical field [0001] The invention belongs to the technical field of composite materials, and in particular relates to a high thermal conductivity graphene wave absorbing composite material and a preparation method. Background technique [0002] With the gradual popularization and promotion of 5G technology, various popular applications including wireless medical treatment, connected smart cars, smart manufacturing, and smart power have received widespread attention, and the corresponding electromagnetic radiation pollution has become increasingly serious. It will not only interfere with the normal work of electronic instruments and equipment, but also affect people's health. At present, based on the above problems, the main solution is to use absorbing materials. The absorbing materials have the advantages of strong absorption, wide frequency band, thin thickness, good stability, and no pollution. They can convert electromagnetic radiation into heat energy to consume and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/04C09D121/00C09D163/00C09D175/04C09D183/04C09D5/32B05D5/00B05D7/24C08L33/04C08L21/00C08L63/00C08L75/04C08L83/04C08L93/04C08K7/00C08K3/04C08K5/544C08J5/18
CPCB05D5/00B05D7/24C08J5/18C08J2321/00C08J2333/04C08J2363/00C08J2375/04C08J2383/04C08J2493/04C08K5/544C08K7/00C09D5/32C09D121/00C09D133/04C09D163/00C09D175/04C09D183/04C08K3/042C08L93/04C08L45/00C08L61/06
Inventor 钱祺蔡二利姜学广林洋
Owner 常州威斯双联科技有限公司
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