Method for using gas fat coal as carbonaceous reducing agent

A technology for gas fertilizer coal and reducing agent, which is applied in chemical instruments and methods, silicon compounds, inorganic chemistry, etc., can solve the problems of shortage of raw carbon reducing agent materials, affecting the gas permeability of furnace materials, and large price increases. The effect of improving charge permeability, low cost and increasing output

Pending Publication Date: 2019-08-30
河南普绿环保科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the expansion of my country's industrial silicon products in domestic and foreign markets, the supply shortage and price rise of the main original carbonaceous reducing agent materials used in silicon industry production have been caused. Among them, the supply of charcoal and petroleum coke is very tight, and the price has risen sharply. The quality is unstable, which undoubtedly makes industrial silicon production face great difficulties
Although the use of petroleum coke can be used as a carbonaceous reducing agent, due to the high degree of graphitization with the increase of the calcination temperature, the electrical conductivity increases, and the specific resistance drops sharply; moreover, the crusting on the furnace surface seriously affects the gas permeability of the furnace charge, irritating The fire is serious and the furnace condition is difficult to control
Although charcoal is the most ideal carbonaceous reducing agent for industrial silicon production, a large number of trees need to be cut down to burn charcoal, which destroys the ecological environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] (1) Send 950k of gas-fertilized coal into the mixing mixer in proportion;

[0018] (2) Add 50kg of modified starch to the above mixture, and continue stirring for 5-8 minutes;

[0019] (3) Send the evenly stirred mixture into the molding machine for molding;

[0020] (4) The formed agglomerate particles are steam-dried at 200°C to 300°C for 2 hours to obtain the carbonaceous reducing agent product.

Embodiment 2

[0022] (1) Mix 800kg of gas fertilizer coal and 200kg of silica powder in proportion and stir evenly;

[0023] (2) Add 30kg of resin powder to the above mixture, and continue to stir for 5-8 minutes;

[0024] (3) Send the evenly stirred mixture into the molding machine for molding;

[0025] (4) The formed agglomerate particles are steam-dried at 200°C to 300°C for 1.5 hours to obtain the carbonaceous reducing agent product.

Embodiment 3

[0027] (1) Mix and stir 700kg of gas fertilizer coal and 300kg of silica powder in proportion;

[0028] (2) Add 20kg of tackifier to the above mixture, and continue to stir for 5-8 minutes;

[0029] (3) Send the evenly stirred mixture into the molding machine for molding;

[0030] (4) The formed agglomerate particles are steam-dried at 200°C to 300°C for 1 hour to obtain the carbonaceous reducing agent product.

[0031] The present invention uses the carbonaceous reducing agent formed by gas fertilizer coal and silica dust for industrial silicon smelting production. Compared with the traditional use of petroleum coke, charcoal, semi-coke, etc. as the reducing agent, the ash content is reduced by 1.6%, and the carbon content is increased by 8.5%. , which improves the purity of industrial silicon and reduces the proportion of reducing agent; due to the characteristics of high strength, thermal stability and high specific resistance of the agglomerates formed by gas fertilizer c...

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Abstract

The invention relates to a method for using gas fat coal as a carbonaceous reducing agent in silicon industry. According to the method, gas fat coal, silica powder and a binder are used as raw materials, and the mixture is molded and dried through a hot press molding process to prepare the carbonaceous reducing agent product with characteristics of low ash, high carbon, good chemical activity, high specific resistance and high mechanical strength. According to the present invention, the high-temperature dry distillation carbonization and sintering process is not required, and the dried agglomerate particles can be directly used as the carbonaceous reducing agent for furnace smelting, and can replace carbonaceous materials such as petroleum coke, charcoal, semi coke and the like, wherein the gas generated in the smelting process is used for producing coal gas through the recovery device, and the agglomerate particles after the pyrolysis and dry distillation have the technical indexes superior to the traditional carbonaceous reducing agent standard, and have characteristics of good gas permeability, high porosity, low production cost, low power consumption, improved product quality,resource recycling and the like.

Description

technical field [0001] The invention belongs to the technical field of silicon industry smelting, and in particular relates to a method for using gas-fertilized coal as a carbonaceous reducing agent in the silicon industry. Background technique [0002] At present, most of the carbonaceous reducing agents used in the smelting of my country's silicon industry are traditional mixed carbonaceous reducing agents composed of charcoal, petroleum coke, wood blocks, and semi-coke according to a certain ratio. With the expansion of my country's industrial silicon products in domestic and foreign markets, the supply shortage and price rise of the main original carbonaceous reducing agent materials used in silicon industry production have been caused. Among them, the supply of charcoal and petroleum coke is very tight, and the price has risen sharply. Unstable quality undoubtedly makes industrial silicon production face great difficulties. Although the use of petroleum coke can be used...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B33/025
CPCC01B33/025
Inventor 蔡永红周广宇许英陈宝元周玺周康
Owner 河南普绿环保科技有限公司
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