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Application of sulfur/phosphorus hybrid polyether modified polycarboxylic acid

A technology for converting polyether and polycarboxylic acid, which is applied in the application field of sulfur/phosphorus hybrid polyether modified polycarboxylic acid, can solve the problems of high dosage of dispersant and low dispersion efficiency, and achieves enhanced dispersibility and expanded application. range, low temperature effect

Active Publication Date: 2019-09-27
中科广化(重庆)新材料研究院有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The invention relates to the technical field of coatings, in which the phthalocyanine blue powder has a high dispersion content, but the amount of dispersant is too high and the dispersion efficiency is low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] (1) Weigh 20g of acrylic acid, 10g of APEG and 50g of water, stir evenly, and heat up to 50°C.

[0034] (2) Add 2 g of potassium permanganate solution with a mass concentration of 1%, keep stirring, and react at 50° C. for 6 h.

[0035] (3) Add 18 g of sodium polysulfide solution with a mass concentration of 20%, stop heating, continue stirring for 30 min, and cool down to room temperature to obtain sulfur / phosphorus polyether modified polycarboxylic acid.

[0036] Sulfur / phosphorylated polyether modified polycarboxylic acid is used as a dispersant to test the dispersibility of organic pigments: take the example of dispersing organic pigment copper phthalocyanine, add 5% of the dispersant (accounting for water mass fraction) in water, mix Uniformly obtain an aqueous solution containing a dispersant, then gradually add copper phthalocyanine solid powder into the aqueous solution under magnetic stirring at 200 rpm, until the copper phthalocyanine in the aqueous solution b...

Embodiment 2

[0039] (1) Weigh 30g of acrylic acid, 6g of TPEG and 43.9g of water, stir evenly, and heat up to 100°C.

[0040] (2) Add 0.1 g of potassium dichromate solution with a mass concentration of 2%, continue stirring, and react at 100° C. for 2 hours.

[0041] (3) Add 20 g of sodium hypophosphite solution with a mass concentration of 30%, stop heating, continue stirring for 30 min, and cool down to room temperature to obtain a sulfur / phosphorylated polyether-modified polycarboxylic acid.

[0042] Sulfur / phosphorylated polyether modified polycarboxylic acid is used as a dispersant to test the dispersibility of organic pigments: take the example of dispersing organic pigment copper phthalocyanine, add 5% of the dispersant (accounting for water mass fraction) in water, mix Uniformly obtain an aqueous solution containing a dispersant, then gradually add copper phthalocyanine solid powder into the aqueous solution under magnetic stirring at 200 rpm, until the copper phthalocyanine in the...

Embodiment 3

[0045] (1) Weigh 28g of acrylic acid, 1g of polyethylene glycol-polypropylene glycol block copolymer and 43g of water, stir evenly, and heat up to 80°C.

[0046] (2) Add 10 g of ammonium persulfate solution with a mass concentration of 5%, continue stirring, and react at 80° C. for 3 h.

[0047] (3) Add 18 g of sodium dimethyl dithiocarbamate solution with a mass concentration of 10%, stop heating, continue stirring for 30 min, and cool down to room temperature to obtain sulfur / phosphorus polyether modified polycarboxylic acid.

[0048] Sulfur / phosphorylated polyether modified polycarboxylic acid is used as a dispersant to test the dispersibility of organic pigments: take the example of dispersing organic pigment copper phthalocyanine, add 5% of the dispersant (accounting for water mass fraction) in water, mix Uniformly obtain an aqueous solution containing a dispersant, and then gradually add copper phthalocyanine solid powder into the aqueous solution under magnetic stirring a...

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PUM

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Abstract

The invention discloses application of sulfur / phosphorus hybrid polyether modified polycarboxylic acid in the fields of paint, printing ink, ceramics, adhesives and solar cells, and particularly relates to application of the sulfur / phosphorus hybrid polyether modified polycarboxylic acid in dispersing an organic pigment in water or an aqueous solution. The sulfur / phosphorus hybrid polyether modified polycarboxylic acid is prepared in the steps that by mass, 10-30 parts of acrylic acid, 1-10 parts of polyether and 20-50 parts of water are evenly mixed and heated to 50-100 DEG C, then 0.1-10 parts by mass of an initiator solution is added, a heat preservation reaction is carried out for 2-6 hours, and 6-20 parts by mass of a chain transfer agent solution is added to stop the reaction. The preparation method is wide in raw material source, green in preparation, simple and convenient to use and environmentally friendly. The problem that the organic pigment phthalocyanine copper is difficult to disperse in water is solved, and the application range of phthalocyanine copper is widened. A phthalocyanine copper water dispersion solution can be applied to the fields of paint, printing ink, ceramics, adhesives and solar cells.

Description

technical field [0001] The invention belongs to the field of pigment dispersants, and in particular relates to the application of a sulfur / phosphorus hybrid polyether modified polycarboxylic acid. Background technique [0002] Copper phthalocyanine was discovered in the 1930s and attracted attention due to its surprising stability to concentrated acids, alkalis, and high temperatures. Copper phthalocyanine molecules have a large conjugated system, which not only has excellent chemical stability, thermal stability, flame retardancy, light resistance and radiation resistance, but also has electrical conductivity, photoconductivity, gas sensitivity, electrical Luminescence, optical storage, catalytic activity and biomimetic properties. At present, copper phthalocyanine is developing into a multifunctional material, which will be widely used in industry and daily life, such as pigments, dyes, inks, solar cells, organic semiconductors with sensitive properties to gases, etc. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01F17/44C09B67/20C08F283/06C08F220/06C08F2/38C09K23/44
CPCC09B67/0067C09B67/0032C08F283/06C08F283/065C09K23/14
Inventor 宋斌黄月文王斌
Owner 中科广化(重庆)新材料研究院有限公司
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