Polyester chip for producing automotive interior fiber and preparation method thereof

A technology for polyester chips and automotive interiors, applied in the field of polyester chips and its preparation, can solve the problems of low strength, crystallinity, low cleanliness, high melting point of polyester chips, etc., and achieve excellent flexibility and strength , the appearance size is easier to grasp, and the effect of high reliability of the finished product

Active Publication Date: 2021-06-25
TIANJIN HUAXIN YINGJU POLYESTER MATERIAL SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. Polyester chips for ordinary fibers have a high melting point, high energy consumption ratio for heating and bonding, and polyester fibers are prone to deformation at high temperatures. For forming fabrics, the setting result is uncontrollable;
[0005] 2. Polyester chips for ordinary fibers are not modified, and the chain segments are too regular. After heating and bonding, the strength is generally not high and the flexibility is insufficient. In subsequent use, delamination, disconnection and deformation will occur due to poor reliability. A series of problems, such as durability and anti-aging performance, are not suitable for long-term use;
[0006] 3. Polyester chips for ordinary fibers generally have low viscosity due to polymerization control, wide molecular weight distribution range, low crystallinity and cleanliness, which are very unfavorable for the production of filaments in subsequent composite spinning, which limits the extension of its use

Method used

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preparation example Construction

[0024] The preparation method of polyester chips for producing automotive interior fiber of the present invention comprises the following steps:

[0025] (1) Synthesis of polyester chip bottom material

[0026] ① Put the mixture of isophthalic acid and terephthalic acid into the ethylene glycol solution, in which isophthalic acid accounts for 5%-15% of the total acid mole fraction, and the ratio of the total ethylene glycol moles to the total acid moles 1.20-1.35, uniformly pump the mixed slurry into the esterification reaction kettle to obtain a uniform slurry of BHET and its derivative intermediates;

[0027] ②When the temperature of the slurry in step ① is stabilized to 245-265°C, pour the slurry obtained in step ① into the polycondensation reactor;

[0028] ③After the mixed slurry enters the polycondensation tank, add reactive antimony catalysts and stabilizers, control the reaction temperature at 270-290°C, and carry out negative pressure polymerization reaction. The vac...

Embodiment 1

[0045] ①Esterification reaction stage: Add 8% isophthalic acid and 92% terephthalic acid (percentages are mole fractions, the same below) to the slurry mixing tank, totaling 2 tons, and then according to the acid-alcohol molar ratio of 1 : 1.20 Dosing ethylene glycol, after mixing evenly, pump it into an esterification reaction kettle at a constant speed through a pipeline pump, and carry out esterification reaction at 250-255°C to obtain a homogeneous mixed slurry of BHET and its derivatives.

[0046] ②Use nitrogen to press the mixed slurry obtained in step ① into the polycondensation reactor through a 25μm stainless steel filter for polymerization reaction, add 1300g of ethylene glycol antimony and 500mL of trimethyl phosphate, control the internal temperature to 270°C, and the vacuum degree to be ≤30pa , After 4.0 hours of reaction, the intrinsic viscosity is reached and the material is discharged.

[0047] ③Put 2.3 tons of polyester chips obtained in step ② into the solid-...

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Abstract

The invention discloses a polyester chip for producing automobile interior decoration fibers and a preparation method thereof. Firstly, the polyester chip that meets the technical requirements is synthesized: using a two-pot process semi-continuous polymerization reaction device, by introducing isocyanate in the esterification reaction Construct and replace carboxylic acid to reduce the melting point of the product to the target range, and then add reactive catalyst, stabilizer, auxiliary materials, etc. in the polycondensation reaction to control the reaction temperature and vacuum degree, and the final synthetic intrinsic viscosity is 0.730‑0.740dl / g The target polyester chip base material; the synthesized product is passed through the solid phase drum device water steam crystallization process to complete the pre-crystallization of the polyester chip; the pre-crystallized polyester chip is obtained by temperature control without cooling down. The continuous negative pressure processing technology completes the drying of polyester chips. After drying, the water content of polyester chips is not higher than 0.05%, and the intrinsic viscosity is not lower than 0.715dl / g. Through the above three steps, the special polyester chips for automotive interior fibers that meet the requirements of industrial production can be prepared.

Description

technical field [0001] The invention relates to a polyester chip and a preparation method thereof, in particular to a polyester chip used for producing automobile interior fiber and a preparation method thereof. Background technique [0002] As an important raw material for textiles, polyester fiber has been used in the production of automotive interiors for a long time, especially in the automotive industry that first started abroad, and has already formed a relatively mature set of standards for the supply of raw materials for automotive interiors. Because polyester fiber has good abrasion resistance, high tear strength, mildew resistance, excellent UV resistance, easy cleaning, good resilience and wrinkle resistance, and the price is relatively cheap, accounting for the largest share of automotive textile decorative fabrics. More than 90% of the market. With the continuous development of the domestic automobile industry in recent years, major automobile manufacturers hav...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/181C08G63/183C08G63/86
CPCC08G63/181C08G63/183C08G63/866
Inventor 王淑生冯艳宾王树刚田庆海李凤春
Owner TIANJIN HUAXIN YINGJU POLYESTER MATERIAL SCI & TECH
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