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Welding rod for equipment such as primary device safety end and steam generator heat transfer pipe in pressurized water reactor power plant

A pressurized water reactor nuclear power plant, steam generator technology, applied in welding equipment, metal processing equipment, welding medium, etc., can solve the problems of uneven weld formation, large welding spatter, poor fluidity of molten pool, etc., and achieve weld infiltration Moderate angle, good slag fluidity, and beautiful weld shape

Inactive Publication Date: 2019-11-12
ATLANTIC CHINA WELDING CONSUMABLES +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Compared with general nickel-based welding consumables, 690 nickel-based alloys have higher technical requirements for supporting welding consumables, and its development difficulties are recognized internationally. The weld metal properties of companies in a monopoly position in the international field cannot fully meet the stringent design requirements of nuclear power plants.
[0005] Although CN201210282726.X (welding core, coating and electrode and preparation method thereof of nuclear-grade nickel-based electrode of basic slag system) discloses a welding core, coating and electrode of nuclear-grade nickel-based electrode, however, On the one hand, the content of C, Si, S, P, and Cu in the welding core is high, and the mutual ratio is unreasonable; on the other hand, the coating is made of alkaline coating, which results in poor arc stability and large welding spatter; It can well solve the problem of poor fluidity of the molten pool, resulting in poor uniformity of slag coverage, unclean slag removal, difficult cleaning of residue, and uneven weld formation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Take 100kg 690 nickel base alloy welding core, the welding core composition is (wt%): C: 0.010%, S: 0.0027%, P: 0.0014%, Si: 0.04%, Mn: 4.00%, Cr: 31.05%, Fe : 3.97%, Cu: 0.004%, Ti: 0.53%, Al: 0.48%, Co: 0.009%, and Nb: 1.68%, and the balance is Ni and unavoidable impurities.

[0051] Take the drug skin, the weight of each component in the drug skin is as follows: containing TiO 2 12kg of 95.58wt% rutile powder; 3kg of cryolite powder containing F55.15wt%; containing CaCO 3 10kg of 96.79wt% marble powder; 3kg of micro-carbon ferrochrome powder containing 65.34wt% Cr; 1.5kg of ferro-titanium powder containing 30.91wt% Ti; 3 98.92wt% barium carbonate 1kg; containing Na 2 O 11.24wt% sodium alginate 0.5kg; NaCl 0.68wt% soda ash 0.2kg; Mn 99.55wt% electrolytic manganese 2kg; Nb 52.23wt% ferroniobium powder 2kg.

[0052] After mixing the above powder evenly, add 6.3kg of potassium sodium water glass with a concentration of 38°~41° and mix evenly, then send it into the p...

Embodiment 2

[0056] This embodiment is all the same as Example 1 except that the weights of the ingredients in the drug skin are different.

[0057] In the present embodiment, the weight of each component in the medicine skin is as follows: containing TiO 2 10kg of 95.58wt% rutile powder; 6kg of cryolite powder containing F55.15wt%; containing CaCO 3 8kg of 96.79wt% marble powder; 4kg of micro-carbon ferrochrome powder containing Cr 65.34wt%; 1kg of Ti-iron powder containing 30.91wt% Ti; 4kg of reduced iron powder containing Fe 97.68wt%; 3 98.92wt% barium carbonate 1kg; containing Na 2 O 11.24wt% sodium alginate 0.8kg; NaCl 0.68wt% soda ash 0.1kg; Mn 99.55wt% electrolytic manganese 1kg; Nb 2.23wt% ferroniobium powder 2kg.

[0058] The obtained electrode was subjected to welding experiments, and the deposited metal composition C: 0.033%, Mn: 3.32%, Si: 0.29%, S: 0.0088%, P: 0.006%, Cr: 29.94%, Mo: 0.37%, Cu: 0.013%, Fe: 8.16%, Co: 0.0087%, N: 0.026%, Al: 0.062%, Ti: 0.14%, Nb+Ta: 1.79%...

Embodiment 3

[0060] This embodiment is all the same as Example 1 except that the weights of the ingredients in the drug skin are different.

[0061] In the present embodiment, the weight of each component in the medicine skin is as follows: containing TiO 2 95.58wt% rutile powder 6.5kg; containing F55.15wt% cryolite powder 8.5kg; containing CaCO 3 6kg of 96.79wt% marble powder; 5kg of micro-carbon ferrochrome powder containing Cr 65.34wt%; 1.5kg of Ti-ferro powder containing 30.91wt% Ti; 3kg of reduced iron powder containing Fe 97.68wt%;3 98.92wt% barium carbonate 2kg; containing Na 2 O 11.24wt% sodium alginate 0.8kg; NaCl 0.68wt% soda ash 0.2kg; Mn 99.55wt% electrolytic manganese 1.2kg; Nb 52.23wt% ferroniobium powder 3kg.

[0062] The welding rod was subjected to welding experiments, and its deposited metal composition: C: 0.033%, Mn: 3.32%, Si: 0.29%, S: 0.0088%, P: 0.006%, Cr: 29.94%, Mo: 0.37%, Cu: 0.013 %, Fe: 8.16%, Co: 0.0087%, N: 0.026%, Al: 0.062%, Ti: 0.14%, Nb+Ta: 1.79%, B:...

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Abstract

The invention discloses a welding rod for equipment such as a primary device safety end and a steam generator heat transfer pipe in a pressurized water reactor power plant. The welding rod is formed by a core wire and a coating covering the surface of the core wire, wherein the core wire is the 690 nickel base alloy core wire; and the 690 nickel base alloy core wire is prepared from the componentsin percentage by weight: less than or equal to 0.03 percent of C, 3.0 to 4.5 percent of Mn, less than or equal to 0.20 percent of Si, 29.0 to 32.0 percent of Cr, 3.0 to 6.0 percent of Fe, 0.5 to 1.0percent of Ti, 0.3 to 0.6 percent of Al, less than or equal to 0.03 percent of Co, 1.5 to 2.2 percent of Nb, less than or equal to 0.10 percent of Cu, less than or equal to 0.005 percent of S, less than or equal to 0.020 percent of P, and the balance Ni and inevitable impurities. Compared with the prior art, a welding process of the welding rod provided by the invention is excellent in performance; and the physical and chemical properties of weld metal meets the strict design requirement of the pressurized water reactor power plant.

Description

technical field [0001] The invention relates to welding materials, and more specifically, relates to a welding rod for equipment such as a safety end of main equipment of a pressurized water reactor nuclear power plant, a heat transfer tube of a steam generator, a preparation method, a welding method and a welding joint. Background technique [0002] 690 nickel-based alloy is a nickel-based alloy with high Cr content. It has excellent resistance to intergranular corrosion, crevice pitting corrosion and stress corrosion. It is currently widely used as heat transfer for steam generators (SG) in pressurized water reactor nuclear power plants. Preparation of tube material. The steam generator (SG) is a key component connecting the primary circuit and the secondary circuit of the pressurized water reactor nuclear power plant, and realizes the heat exchange process of the primary circuit and the secondary circuit through thousands of heat transfer tubes. [0003] Due to the low t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K35/30B23K35/40
CPCB23K35/304B23K35/40
Inventor 王若蒙蒋勇陈煜刘奇望白昶罗宏谷雨罗松
Owner ATLANTIC CHINA WELDING CONSUMABLES