Microfluidic fuel cell having diaphragm
A fuel cell, separator membrane technology, applied in the direction of fuel cells, circuits, electrical components, etc., can solve the problems of fuel or oxidant permeation, battery performance impact, battery performance degradation, etc., to achieve low cost, improve battery performance, and make simple Effect
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Embodiment 1
[0019] Example 1, see Figure 1 to Figure 3 , a microfluidic fuel cell with a separator, comprising an upper cover plate 1, a lower cover plate 3, a cathode 5, an anode 2, an inlet plate 4 and an outlet plate 6; it is characterized in that: the cathode 5, the anode 2, the inlet Both the plate 4 and the outlet plate 6 are placed on the lower cover plate 3, located below the upper cover plate 1; the anode 2 and the cathode 5 are arranged opposite to each other on the left and right, and there is a gap 12 between the cathode 5 and the anode 2, and the gap 12 serves as A main channel for the solution to flow; the main channel is provided with a separation membrane 7, and the separation membrane 7 divides the main channel into left and right flow channels; the separation membrane 7 is a porous filter paper with hydrophilicity; The inlet plate 4 and the outlet plate 6 are respectively arranged on the front and rear sides of the main channel; the inlet plate 4 is provided with two in...
Embodiment 2
[0025] Example 2 is different from Example 1 in that: the separation membrane 7 is a nylon membrane prepared by an in-situ chemical reaction synthesis method.
[0026] Specifically: the solution obtained by dissolving the hexamethylenediamine aqueous solution and the adipoyl chloride solution in the organic solvent is injected into the two inlet channels 8 and 9 respectively at a flow rate of 60-100 μL / min, enters the main channel, and forms in the main channel At the water-oil interface, hexamethylenediamine and adipoyl chloride molecules in the solution diffuse to the water-oil interface to undergo polycondensation reaction to produce polyamide. After continuous reaction, a layer of porous nylon membrane is formed in the main channel. Finally, ethanol is injected into the inlet channel first. Rinse the nylon membrane in the process, inject a deionized aqueous solution into the inlet channel to rinse the nylon membrane, and then inject nitrogen gas into the inlet channel to pu...
Embodiment 3
[0029] Embodiment 3: the microfluidic fuel cell with separation membrane that operation embodiment 1 makes, and described anode 2 oxidizes fuel and produces electron and produces CO 2gas bubbles, the cathode 5 reduces persulfate ions in the oxidizer and combines electrons to generate sulfate ions. Catalysts such as Pd on the anode catalytic layer perform electrocatalytic oxidation of fuels such as formic acid to generate carbon dioxide, electrons and hydrogen ions. The electrons reach the cathode 5 through the load through the external circuit to generate electric energy. After a period of reaction, the carbon dioxide produced at the anode is released to form CO 2 The air bubbles are restricted on the anode side by the separator, and finally the air bubbles are discharged along the flow channel.
[0030] see Figure 4 , Figure 4 It is the power density curve figure of the microfluidic fuel cell of embodiment 1 and the microfluidic fuel cell without filter paper separating...
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