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Polylactic acid cigarette tow, preparation method and application thereof

A technology of polylactic acid and polylactic acid resin, which is applied in the field of cigarette tow, can solve the problems of reduced breaking strength, reduced smoking comfort, and easy occurrence of broken belts, so as to improve the elastic recovery rate of curls, improve the comfort of smoking, and improve The effect of smoking comfort

Active Publication Date: 2020-01-10
孔令孝 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] CN201310048812.9 provides a modified polylactic acid cigarette tow and filter rod and its preparation method, which mainly reduces the regularity of lactic acid molecules on the surface of polylactic acid tow by reducing the proportion of L-lactic acid units, and reduces the degree of crystallinity , so as to increase the swelling effect of the plasticizer on the surface of the tow to increase the hardness of the filter rod, and the hardness reaches 87%. However, the addition of a large amount of plasticizer will increase the suction resistance of the filter rod and affect the smoking comfort of the user.
[0005] CN201610596534.4 provides a heat-resistant polylactic acid cigarette tow and its preparation method, which adds a special inorganic crystallization nucleating agent to the polylactic acid resin to increase the crystallinity of the rolled tobacco bundle, thereby improving heat resistance, and a large amount of inorganic The addition of particles will increase the density of the tow and reduce the comfort of smoking. In addition, the addition of inorganic particles may agglomerate and lead to a decrease in breaking strength, and the tow is prone to breakage during the forming process

Method used

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  • Polylactic acid cigarette tow, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Embodiment 1 A kind of polylactic acid cigarette tow

[0040] The polylactic acid cigarette tow, in parts by weight, consists of raw materials:

[0041] 80 parts of polylactic acid resin, 1 part of nucleating agent, 0.5 parts of lubricant, 0.5 parts of antioxidant, 4 parts of foaming agent, 7 parts of foaming aid

[0042] in:

[0043] The nucleating agent is a mixture of sodium succinate, sodium benzoate and aluminum adipate, and the mixing mass ratio of the three is 1:2.5:1.1;

[0044] The lubricant is polyvinyl alcohol;

[0045] The antioxidant is N, N'-bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl]hydrazine (antioxidant 1098);

[0046] The foaming agent is a mixture of azodicarbonamide ADC and foaming agent OBSH, and the mass ratio of the two is 1:1;

[0047] Foaming aid is magnesium stearate;

[0048] The polylactic acid resin is self-made polylactic acid resin, the melt index is 5g / 10min under the load of 190℃ / 2.16KG, and the molecular weight distribution...

Embodiment 2

[0074] Embodiment 2 A kind of polylactic acid cigarette tow

[0075] The polylactic acid cigarette tow, in parts by weight, consists of raw materials:

[0076] 85 parts of polylactic acid resin, 1 part of nucleating agent, 2 parts of lubricant, 1 part of antioxidant, 5 parts of foaming agent, 10 parts of foaming aid

[0077] in:

[0078] The nucleating agent is a mixture of sodium succinate, sodium benzoate and aluminum adipate, and the mixing mass ratio of the three is 1:3:1;

[0079] The lubricant is polyvinyl alcohol;

[0080] The antioxidant is 2,6-di-tert-butyl-4-methylphenol (antioxidant 264);

[0081] The foaming agent is a mixture of azodicarbonamide ADC and foaming agent OBSH, and the mass ratio of the two is 1:1;

[0082] The foaming aid is calcium carbonate;

[0083] The polylactic acid resin is self-made polylactic acid resin, the melt index is 8g / 10min under the load of 190℃ / 2.16KG, and the molecular weight distribution is 1.9;

[0084] The preparation metho...

Embodiment 3

[0109] Embodiment 3 A kind of polylactic acid cigarette tow

[0110] The polylactic acid cigarette tow, in parts by weight, consists of raw materials:

[0111] 85 parts of polylactic acid resin, 2 parts of nucleating agent, 3 parts of lubricant, 3 parts of antioxidant, 8 parts of foaming agent, 11 parts of foaming aid

[0112] in:

[0113] The nucleating agent is a mixture of sodium succinate, sodium benzoate and aluminum adipate, and the mixing mass ratio of the three is 1: 3.0:0.8;

[0114] The lubricant is polyvinyl alcohol;

[0115] The antioxidant is 2,6-di-tert-butyl-4-methylphenol (antioxidant 264);

[0116] The foaming agent is a mixture of azodicarbonamide ADC and foaming agent OBSH, and the mass ratio of the two is 1:1;

[0117] The foaming aid is calcium carbonate;

[0118] The polylactic acid resin is self-made polylactic acid resin, the melt index is 12g / 10min under the load of 190℃ / 2.16KG, and the molecular weight distribution is 2.5;

[0119] The preparati...

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Abstract

The invention provides a polylactic acid cigarette tow. The polylactic acid cigarette tow comprises the following raw materials in parts by weight: 80-85 parts of polylactic acid resin, 1-2 parts of anucleating agent, 0.5-3 parts of a lubricant, 0.5-3 parts of an antioxidant, 4-8 parts of a foaming agent and 7-11 parts of a foaming assistant, wherein the polylactic acid resin is self-made, the melt index is 5-12 g / 10 min under the load of 190 DEG C / 2.16 KG, and the molecular weight distribution is 1.2-2.5. The polylactic acid cigarette tow prepared by adopting the method has the advantages that the density of the tow is 0.56-0.77 g / cm<3>, the breaking strength reaches 2.2 cN / dtex- 2.5cN / dtex, a filter tip rod made from the tow is small in suction resistance and good in air permeability, and the smoking comfort of a user can be greatly improved.

Description

technical field [0001] The invention relates to a cigarette tow, in particular to a polylactic acid cigarette tow, a preparation method and an application thereof. Background technique [0002] Tow for tobacco is an important material for producing cigarette filter rods, which can improve the taste of cigarettes and reduce the harm of harmful substances in smoke to human body. The traditional cigarette tow material is cellulose acetate, but a large amount of organic waste water will be generated in the process of pulping, esterification treatment and solution spinning of cellulose acetate tow, the production process is complicated, the energy consumption is high, and the pollution is large, which seriously restricts the Development of cellulose acetate tow. [0003] Polylactic acid fiber is a kind of polyester fiber made from lactic acid fermented from renewable corn, sugar beet, grain or potato starch as raw material, polymerized and spun. It not only has good biocompatib...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/92D01F1/10A24D3/10D01D5/253D01D5/08D01D5/14D01D7/00
CPCD01F6/92D01F1/10A24D3/10D01D5/253D01D5/08D01D5/14D01D7/00
Inventor 孔令孝王雅文
Owner 孔令孝