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A low-temperature-resistant two-component solvent-free epoxy coating for pipe joints

An epoxy coating, two-component technology, applied in epoxy resin coatings, anti-corrosion coatings, rubber derivative coatings, etc., can solve the problems of poor low-temperature bending resistance, high low-temperature brittleness, and non-curing, and achieve low-temperature bending resistance Excellent performance, excellent resistance to hot water immersion, excellent thermal shock resistance

Active Publication Date: 2021-05-04
CYG CHANGTONG NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] With the promotion and use of two-component solvent-free epoxy coatings in the field of oil and gas pipeline joints, the existing two-component solvent-free epoxy coatings on the market have the following defects: ①The commonly used two-component solvent-free epoxy coatings for pipeline joints When the temperature is lower than 0 ℃, the curing speed of oxygen coating is very slow or even not curing, which is not conducive to the winter construction of pipeline joint anticorrosion in northern my country; , in the northern region of my country (the temperature can reach minus 30°C in winter), low-temperature cracking is prone to occur, resulting in anti-corrosion failure; ③The conventional two-component solvent-free epoxy coating has poor low-temperature bending resistance. In the northern region, during winter construction, When the pipe is welded and anti-corrosion, when it goes down the ditch, when the pipe is slightly bent, cracks are prone to occur at the joint part of the epoxy coating, which directly leads to the failure of the joint anti-corrosion

Method used

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  • A low-temperature-resistant two-component solvent-free epoxy coating for pipe joints
  • A low-temperature-resistant two-component solvent-free epoxy coating for pipe joints
  • A low-temperature-resistant two-component solvent-free epoxy coating for pipe joints

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] A low temperature resistant two-component solvent-free epoxy coating, consisting of A component and B component. in:

[0043] (1) Preparation of component A: 40 parts of bisphenol F epoxy resin (YDF-162), 5 parts of bisphenol A epoxy resin (E-51), epoxy nitrile prepolymer (Jiadida Chemical industry 86840) 5 parts, glycidyl ether active diluent (AGE) 5 parts, according to add into the mixing tank, heat to 50 ℃, stir for 15 minutes, the stirring speed is 1000 rpm, after stirring evenly, the stirring speed is reduced to 200 RPM, then add 0.9 parts of thixotropic agent (MT6650), 0.3 parts of leveling agent (Deqian 879), 0.3 parts of dispersant (BYK110), 0.4 parts of defoamer (TEGO AIREX 902W), 0.1 parts of carbon black, Stir for 10 minutes, and finally add 20 parts of silane coupling agent modified silicon micropowder, 9 parts of titanium dioxide, 7 parts of aluminum dihydrogen tripolyphosphate, and 7 parts of muscovite powder, increase the stirring speed to 500 rpm, and s...

Embodiment 2

[0051] A low temperature resistant two-component solvent-free epoxy coating, consisting of A component and B component. in:

[0052] (1) Preparation of component A: 30 parts of bisphenol F epoxy resin (NPEF-170), 10 parts of bisphenol A epoxy resin (E-52), epoxy nitrile prepolymer (Jiadida Chemical industry 86840) 10 parts, glycidyl ether reactive diluent (691) 6 parts, press into the mixing tank, heat to 50 ° C, stir for 10 minutes, stirring speed 1000 rpm, after stirring evenly, the stirring speed is reduced to 200 RPM, then add 0.8 parts of thixotropic agent (OPTIMA), 0.3 parts of leveling agent (KMT-5510), 0.4 parts of dispersant (BYK190), 0.3 parts of defoamer (BYK A535), 0.2 parts of carbon black, and stir For 10 minutes, finally add 19 parts of titanate coupling agent modified silicon micropowder, 12 parts of titanium dioxide, 6 parts of aluminum dihydrogen tripolyphosphate, and 5 parts of muscovite powder, increase the stirring speed to 400 rpm, stir for 35 Minutes, ...

Embodiment 3

[0060] A low temperature resistant two-component solvent-free epoxy coating, consisting of A component and B component. in:

[0061] (1) Preparation of component A: 35 parts of bisphenol F epoxy resin (YDF-162), 7 parts of bisphenol A epoxy resin (E-51), epoxy nitrile prepolymer (Jiadida Chemical industry 86840) 8 parts, glycidyl ether active diluent (AGE) 4 parts, according to add to the mixing tank, heat to 50 ℃, stir for 12 minutes, the stirring speed is 1000 rpm, after stirring evenly, the stirring speed is reduced to 200 RPM, then add 1.2 parts of thixotropic agent (8461), 0.4 parts of leveling agent (BYK333), 0.4 parts of dispersant (BYK-P104S), 0.5 parts of defoamer (2566), 0.5 parts of carbon black, and stir for 10 minutes, finally add 22 parts of silane coupling agent modified silicon micropowder, 11 parts of titanium dioxide, 5 parts of aluminum dihydrogen tripolyphosphate, and 5 parts of muscovite powder, and the stirring speed is increased to 450 rpm, stirring for...

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Abstract

A low-temperature resistant two-component solvent-free epoxy coating, which is composed of A component and B component, wherein in weight percentage, A component includes: bisphenol F type epoxy resin 30-45%, bisphenol A type Epoxy resin 5‑10%, epoxy nitrile prepolymer 5‑10%, glycidyl ether reactive diluent 3‑7%, modified silica powder 15‑25%, titanium dioxide 8‑15%, tripolyphosphoric acid Aluminum dihydrogen 3‑10%, mica powder 4‑10%, thixotropic agent 0.6‑1.4%, dispersant 0.2‑0.5%, leveling agent 0.2‑0.5%, defoamer 0.3‑0.7%, carbon black 0.1‑ 0.7%; B component includes: Mannich base 50-75%, thiourea-polyamine condensate 25-50%. Compared with ordinary epoxy coatings, the low-temperature resistant two-component solvent-free epoxy coating for pipe jointing of the present invention has fast curing speed at low temperature, no crystallization and no precipitation, excellent low-temperature bending resistance, excellent low-temperature impact resistance, and heat resistance Excellent water immersion performance, excellent thermal shock resistance and other characteristics.

Description

technical field [0001] The invention relates to a low-temperature-resistant two-component solvent-free epoxy anticorrosion coating for jointing of oil and gas pipelines, belonging to the technical field of oil and gas pipeline anticorrosion. Background technique [0002] At present, most of the main anti-corrosion layers of domestic oil and gas pipelines use 3PE anti-corrosion layers, while most of the joint anti-corrosion materials still use radiation cross-linked polyethylene heat shrinkable tape. Since the insulation resistance of radiation cross-linked polyethylene is very large, it will shield the cathodic protection current, resulting in the failure of the cathodic protection current. Two-component solvent-free epoxy coating, as a new type of sealing material, has the advantages of simple coating process, easy repair, reliable inspection results, no cathodic protection current shielding, etc., and has developed rapidly in the field of domestic pipeline joint anticorros...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/00C09D115/00C09D5/08C09D7/61C09D7/62
CPCC08K2003/2241C08K2003/327C08L2201/08C08L2205/025C08L2205/03C09D5/08C09D163/00C09D7/61C09D7/62C08L63/00C08L15/00C08K13/06C08K9/06C08K3/36C08K3/22C08K3/32C08K3/34
Inventor 张真易王洲洲夏梦军谭南枢谢志坚吴强陈君
Owner CYG CHANGTONG NEW MATERIAL
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