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A method for treating nickel-containing wastewater by using composite adsorbent

A composite adsorption and nickel wastewater technology, applied in the direction of adsorption water/sewage treatment, multi-stage water treatment, water/sewage treatment, etc., can solve the problems of low removal rate of nickel metal and complicated operation process

Active Publication Date: 2022-05-24
ANHUI DEQI ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although there are many methods for treating nickel-containing wastewater, including chemical methods, electrolysis methods, and physical isolation and filtration methods, the existing treatment methods generally have the defects of complicated operation process and low removal rate of nickel metal.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A method for treating nickel-containing wastewater using composite adsorbent, comprising the following steps:

[0025] S1, mixing nickel-containing wastewater with composite adsorbent, shaking at room temperature, and obtaining primary treatment wastewater after solid-liquid separation;

[0026] S2, adjusting the pH value of the primary treatment wastewater to 5, adding sodium hypochlorite to carry out a stirring reaction, then adding a composite adsorbent to shake at room temperature, and obtaining secondary treatment wastewater after solid-liquid separation;

[0027] S3, adjust the pH value of the secondary treatment wastewater to 10.5, let stand for precipitation, take the upper layer liquid and add polyaluminum chloride to stir, then add polyacrylamide to stir, stand and separate solid-liquid to obtain tertiary treated wastewater;

[0028] S4. Mix the tertiary treated wastewater with the composite adsorbent, shake at room temperature and then separate the solid and ...

Embodiment 2

[0031] A method for treating nickel-containing wastewater using composite adsorbent, comprising the following steps:

[0032] S1. Mix the nickel-containing wastewater with the composite adsorbent, shake at room temperature for 10 hours, and obtain a primary treatment wastewater after solid-liquid separation; wherein, each liter of nickel-containing wastewater is mixed with 11 g of the composite adsorbent;

[0033] S2. Adjust the pH value of the primary treatment wastewater to 4, add sodium hypochlorite for stirring reaction, then add a composite adsorbent to shake at room temperature for 18 hours, and obtain secondary treatment wastewater after solid-liquid separation; The mass of sodium hypochlorite is 120mg, and 3g of composite adsorbent is added to each liter of treated wastewater;

[0034] S3. Add sodium hydroxide to adjust the pH value of the secondary treatment wastewater to 11.5, let stand for precipitation, take the upper layer liquid and add polyaluminum chloride to s...

Embodiment 3

[0038] A method for treating nickel-containing wastewater using composite adsorbent, comprising the following steps:

[0039] S1. Mix the nickel-containing wastewater with the composite adsorbent in an amount per liter of nickel-containing wastewater mixed with 8 g of the composite adsorbent, shake at room temperature for 20 hours, and obtain primary treatment wastewater after solid-liquid separation;

[0040] S2, adjust the pH value of the primary treatment wastewater to 4, add sodium hypochlorite for stirring reaction, then add a composite adsorbent and shake at room temperature for 20 hours, and obtain secondary treatment wastewater after solid-liquid separation; The mass of sodium hypochlorite is 150mg, and 6g of composite adsorbent is added to each liter of treated wastewater;

[0041] S3. Add sodium hydroxide to adjust the pH value of the secondary treatment wastewater to 11, stand for precipitation, take the upper layer liquid and add polyaluminum chloride to stir, then...

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PUM

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Abstract

The invention discloses a method for treating nickel-containing wastewater by using a composite adsorbent, comprising: mixing the nickel-containing wastewater with the composite adsorbent, shaking at room temperature, separating solid and liquid to obtain wastewater for primary treatment, and adjusting its pH value to 4- 5. Add sodium hypochlorite to stir the reaction, add composite adsorbent to vibrate at room temperature, and obtain secondary treatment wastewater after solid-liquid separation; adjust the pH value of the secondary treatment wastewater to 10.5-11.5, let it stand for precipitation, take the upper liquid and add polymerization chlorination Aluminum was stirred, then polyacrylamide was added to stir, and after standing still and solid-liquid separation, three times of treated wastewater were obtained; the three times of treated wastewater was mixed with a composite adsorbent, and solid-liquid separation was performed after shaking at room temperature; the composite adsorbent was made of modified seawater The foam stone, acid-modified fly ash and cross-linked chitosan are uniformly mixed. The method for treating nickel-containing waste water with a composite adsorbent proposed by the invention has a simple process, has better treatment effects on various forms of nickel in the water body, and has a high nickel removal rate.

Description

technical field [0001] The invention relates to the technical field of wastewater treatment, in particular to a method for treating nickel-containing wastewater by using a composite adsorbent. Background technique [0002] Nickel is one of the widely used and expensive heavy metal elements. In recent years, it has been widely used in electroplating, electronics, alloys, steel, catalysts and other fields. These fields will discharge a large amount of nickel-containing wastewater. Nickel and its compounds in nickel-containing wastewater are highly toxic substances. In the field of wastewater treatment, nickel-containing wastewater belongs to high-concentration and refractory toxic wastewater. Improper treatment will not only cause waste of nickel metal resources, but also It is easy to produce secondary pollution and can enter the human body through the food chain, causing serious harm to the human body. Therefore, according to the regulations of the environmental protection d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/04C02F1/28B01J20/24B01J20/30C02F101/20
CPCC02F9/00C02F1/281C02F1/288C02F1/286B01J20/24B01J20/12B01J20/103B01J20/22C02F1/66C02F1/5236C02F1/56C02F2101/20C02F2301/08C02F1/76
Inventor 林森
Owner ANHUI DEQI ENVIRONMENTAL PROTECTION TECH CO LTD