4-chlorophenol molecular imprinting electrochemical sensor and preparation method thereof
A chlorophenol molecular and electrochemical technology, applied in the field of electrochemical sensing, can solve the problems of deep imprinted holes, affecting the mass transfer process, and complicated construction process of molecularly imprinted electrochemical sensors, etc., and achieves good electrical conductivity and Catalytic performance, the effect of sensitive and specific recognition
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Embodiment 1
[0026] (1) Pass Al first 2 o 3 Polish the glassy carbon electrode with polishing powder (0.05 μm), then ultrasonically clean it in absolute ethanol and secondary water for 20 s, take it out and blow it dry with nitrogen, and then dry it with 1 mmol L -1 K 3 [Fe(CN) 6 ] and 0.1mol L -1 In the KCl solution, the cyclic voltammetry scan was carried out in the potential range of -0.2 ~ 0.6V until a stable redox peak appeared, that is, the polishing of the glassy carbon electrode was considered to be completed.
[0027] (2) 200ul, 0.13mol L -1 4-Chlorophenol was added to 20ml of Tris-HCl buffer solution with pH = 8.3, ultrasonically mixed evenly, then 20mg of dopamine hydrochloride was added, and reacted for 3 hours at room temperature under stirring conditions to obtain a molecularly imprinted polymer solution containing 4-chlorophenol ; 300ul, 0.023mol L -1 The cupric chloride solution was added to the above-mentioned molecularly imprinted polymer solution containing 4-chlo...
Embodiment 2
[0030] (1) The electrode polishing process is the same as in Example 1.
[0031] (2) 200ul, 0.13mol L -1 4-Chlorophenol was added to 20ml of Tris-HCl buffer solution with pH = 8.2, ultrasonically mixed evenly, then 15mg of dopamine hydrochloride was added, and reacted at room temperature for 3.3h under stirring conditions to obtain a molecularly imprinted polymer containing 4-chlorophenol Solution; 300ul, 0.02mol L -1 Add the copper chloride solution to the molecularly imprinted polymer solution containing 4-chlorophenol, and add 500ul, 0.02mol L dropwise while stirring. -1Sodium hypophosphite solution, stirred and reacted at 43°C for 1.7h, then heated up to 83°C at a rate of 3°C / min, continued to react for 27min, then centrifuged, washed, and 4-chlorophenol was removed with absolute ethanol to obtain Loaded with Cu@Cu 2 4-Chlorophenol molecularly imprinted polymers for O-composite nanoporous materials.
[0032] (3) The loaded Cu@Cu 2 The 4-chlorophenol molecularly impri...
Embodiment 3
[0034] (1) The electrode polishing process is the same as in Example 1.
[0035] (2) 200ul, 0.13mol L -1 4-Chlorophenol was added to 20ml of Tris-HCl buffer solution with pH = 8.4, ultrasonically mixed evenly, then 25mg of dopamine hydrochloride was added, and reacted at room temperature for 2.8h under stirring conditions to obtain a molecularly imprinted polymer containing 4-chlorophenol Solution; 300ul, 0.025mol L -1 Add the copper chloride solution to the molecularly imprinted polymer solution containing 4-chlorophenol, and add 500ul, 0.02mol L dropwise while stirring. -1 Sodium hypophosphite solution, stirred and reacted at 47°C for 1.3h, then heated up to 87°C at a rate of 2°C / min, continued to react for 23min, then centrifuged, washed, and 4-chlorophenol was removed with absolute ethanol to obtain Loaded with Cu@Cu 2 4-Chlorophenol molecularly imprinted polymers for O-composite nanoporous materials.
[0036] (3) The loaded Cu@Cu 2 The 4-chlorophenol molecularly imp...
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