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A kind of coating for ozone decomposition and its preparation method and application

An ozone decomposition and coating technology, applied in chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, etc., can solve structural damage, lack of ozone decomposition performance, and endanger human health and other problems, to achieve the effect of good uniformity and rich and diverse decorative effects

Active Publication Date: 2022-02-08
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, the presence of excessively high concentrations of ozone indoors may endanger human health
[0003] CN108285735A discloses a method for preparing a coating, which comprises the following components in parts by weight: 10-20 parts of diisocyanate, 50-80 parts of polyester polyol, 5-15 parts of dimethylol propionic acid, light carbonic acid 2-5 parts of calcium, 1-3 parts of wollastonite powder, 1.5-2 parts of nano-clay, 0.8-1.5 parts of nano-boron carbide, 8-15 parts of polyacrylamide, 2-3 parts of latent curing agent, 0.5-1 part of dispersant parts, 0.5-1 part of coupling agent, 1-3 parts of defoamer, 0.3-0.8 part of catalyst, 2-5 parts of chain extender, 30-40 parts of deionized water; CN109423087A discloses a preparation method of coating, It mixes water, butyl propionate, quartz sand powder, silicon powder and hydroxypropyl methylcellulose, boils, cools down to 30°C after 2 hours and adds methanol, keeps warm for 30 minutes, then cools down to room temperature, and adds alumina Powder and titanium dioxide are mixed evenly; CN104725970A discloses a coating, which includes the following components by mass: 35-45 parts of emulsion, 48-56 parts of pigment, 2-4 parts of filler, 3 ~6 parts of additives, the emulsion contains hollow spherical latex particles dispersed in water; the coatings described in the above schemes do not have the performance of ozonolysis, and are prone to structural damage due to ozonation

Method used

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  • A kind of coating for ozone decomposition and its preparation method and application
  • A kind of coating for ozone decomposition and its preparation method and application
  • A kind of coating for ozone decomposition and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0095] Taking the quality of coating as 100%, the coating described in this embodiment comprises the following components:

[0096]

[0097]

[0098] The calculation results of the above mass percentages retain one significant figure after the decimal point.

[0099]In the coating preparation process described in this embodiment, the selection of raw materials is as follows, the emulsion is a water-based acrylic emulsion, the deozone catalyst is a NiFe hydrotalcite structure catalyst, the particle size of the sand is 80-120 mesh, the The anti-settling agent is magnesium aluminum silicate, the dispersant is SN-5040, the wetting agent is LCN407, the antifreeze is propylene glycol, the film-forming aid is alcohol ester-12, the preservative is CBJ-4, and the thickener is hydroxyethyl Base cellulose and acrylic acid alkali swelling;

[0100] The molar ratio of nickel element and iron element in the NiFe hydrotalcite structure catalyst adopted in the present embodiment is 3:1...

Embodiment 2

[0117] Taking the mass of the coating as 100%, the coating in this embodiment comprises the following components in terms of mass percentages:

[0118]

[0119] The calculation results of the above mass percentages retain one significant figure after the decimal point.

[0120] The composition of the deozone catalyst and auxiliary agent used in this embodiment is the same as that of Embodiment 1.

[0121] The preparation method of deozone catalyst predispersion slurry, described method comprises the following steps:

[0122] (a) Add 100g of water in the sand mill cylinder, add the dispersant, then add the zirconium beads 100g and deozone catalyst powder with a particle size of 1mm in turn, wherein the dispersant and deozone catalyst powder mass ratio is 1:100, at 2200rpm Sand mill and stir for 30 minutes under the condition of the deozone catalyst to disperse the particle size of the deozone catalyst to below 50 microns; filter with a 200-mesh filter screen, remove the zir...

Embodiment 3

[0134] Taking the mass of the coating as 100%, the coating in this embodiment comprises the following components in terms of mass percentages:

[0135]

[0136] The calculation results of the above mass percentages retain one significant figure after the decimal point.

[0137] The composition of the deozone catalyst and auxiliary agent used in this embodiment is the same as that of Embodiment 1.

[0138] The preparation method of deozone catalyst predispersion slurry, described method comprises the following steps:

[0139] (a) Add 100g of water in the sand mill cylinder, add the dispersant, then add the zirconium beads 100g and deozone catalyst powder with a particle size of 1mm in turn, wherein the dispersant and deozone catalyst powder mass ratio is 1:100, at 2200rpm Sand mill and stir for 30 minutes under the condition of the deozone catalyst to disperse the particle size of the deozone catalyst to below 50 microns; filter with a 200-mesh filter screen, remove the zir...

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Abstract

The invention relates to a coating for ozonolysis, a preparation method and application thereof; the coating comprises emulsion, titanium dioxide, deozonation catalyst, filler, color paste, sand, auxiliary agent and water, and the above-mentioned components are according to specific If the paint is mixed in a proportion, the components in the paint are uniform, the paint can be stable in storage in a natural state, and the coating formed after the paint is applied has the property of promoting ozone decomposition under natural conditions.

Description

technical field [0001] The invention belongs to the field of environmental catalysis, and relates to a coating for ozonolysis, a preparation method and application thereof. Background technique [0002] Ozone is one of the common pollutants in indoor air. It has strong oxidizing and corrosive properties, and can cause certain harm to the materials, animals, plants, and human body in its environment. Ozone not only brings irritating odor, but also can react with different organic substances indoors. The reaction products include carcinogens such as formaldehyde and acrolein, irritating substances such as carbonyl, dicarbonyl, acids, etc., and Free radicals, secondary organic aerosols, etc. Therefore, the presence of excessively high concentrations of ozone indoors may endanger human health. [0003] CN108285735A discloses a method for preparing a coating, which comprises the following components in parts by weight: 10-20 parts of diisocyanate, 50-80 parts of polyester polyo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B26/06C04B26/16C04B26/08C04B14/36B01J23/34B01J23/755
CPCC04B26/06C04B26/16C04B26/08C04B14/36B01J23/34B01J23/755C04B2111/00482C04B2111/00025C04B2111/00017C04B2111/00525C04B2111/00534C04B24/045C04B2103/61C04B14/06C04B2103/54C04B24/383C04B24/2641C04B14/042C04B14/28C04B14/305C04B2103/408C04B2103/0068C04B24/02C04B22/00
Inventor 贺泓马金珠张仁哲陈莹法刘东华赵雅文詹明佳张娟房晓梅
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI