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Neutral metal surface coarsening treatment solution with super-hydrophilicity and super-oleophilicity, and preparation method and application thereof

A neutral metal and surface roughening technology, which is applied in the field of neutral metal surface roughening treatment liquid and its preparation, can solve the problems of not necessarily meeting the coating adhesion requirements, meeting the requirements is unknown, and insufficient adhesion, etc. , to achieve the effect of improving surface energy value and adhesion, high metal surface adhesion, and low processing cost

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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But this invention only checks the adhesion of the rubber elastic element bonding material, which belongs to the solvent-diluted oil-based material, and has good bonding and adhesion with conventional metals, while for other such as water-based materials or water-based oil-based mixed materials, This roughening method does not necessarily meet the requirements of coating adhesion; the metals treated by this roughening method are only general steel, stainless steel and aluminum. It is not known whether the roughening effect is uniform and whether the adhesion meets the requirements; for special coating materials with higher adhesion requirements and both water-based and oil-based materials, such as nano-scale high-temperature-resistant and wear-resistant coating materials, the roughening The treatment can only reach the micron size, and the roughening layer does not meet the required micro-nano crystal phase morphology, which will obviously lead to insufficient adhesion; the stronger the acidity of the roughening treatment solution, the better the roughening effect and the shorter the treatment time. However, strong acidity will cause environmental and safety hazards for use and waste liquid post-treatment.

Method used

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  • Neutral metal surface coarsening treatment solution with super-hydrophilicity and super-oleophilicity, and preparation method and application thereof
  • Neutral metal surface coarsening treatment solution with super-hydrophilicity and super-oleophilicity, and preparation method and application thereof
  • Neutral metal surface coarsening treatment solution with super-hydrophilicity and super-oleophilicity, and preparation method and application thereof

Examples

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Embodiment 1

[0076]This embodiment provides a super-amphiphilic neutral metal surface roughening treatment solution, the super-amphiphilic neutral metal surface roughening treatment solution is based on its total mass of 100%, including the following components: Lanification component A 10 %, haze component B 28% and haze component C 62%;

[0077] The dehydration component A includes alkylsiloxane-modified nano silicon dioxide solution and 1-(3-propanesulfonyl)-2-pyrrolidone bisulfate; the dehydration component B includes C14 fatty acid and The hydroalcoholic liquid of C16 fatty acid and 1-(3-propanesulfonyl)-2-pyrrolidone p-toluenesulfonate; Based on the total mass of the metal surface roughening treatment liquid as 100%, the haze component C Including N, N-dimethyl-N-(2-hydroxyethyl) 2-hydroxyhexadecyl quaternary ammonium phosphate (lane accelerator) 2%, DL-sodium malate (lane dispersant) 3 %, polyethylene glycol diglycidyl ether (penetrating agent) 5%, disodium edetate (water softener)...

Embodiment 2

[0088] This embodiment provides a super-amphiphilic neutral metal surface roughening treatment solution, the super-amphiphilic neutral metal surface roughening treatment solution is based on its total mass of 100%, including the following components: Lanification component A 10 %, haze component B18% and haze component C 72%;

[0089] The dehydration component A includes alkylsiloxane-modified nano-silica solution and 1-(3-propanesulfonyl)-2-pyrrolidone trifluoroacetate; the dehydration component B includes C16 Hydroalcoholic liquid of fatty acid and 1-(3-propanesulfonyl)-2-pyrrolidone trifluoromethanesulfonate; based on the total mass of the metal surface roughening treatment liquid as 100%, the haze component C Including N,N-Dimethyl-N-(2-hydroxyethyl) 2-hydroxyhexadecyl quaternary ammonium phosphate (lane accelerator) 5%, dextran sodium sulfate (lane dispersant) 5% %, ethylene glycol diglycidyl ether (penetrating agent) 10%, disodium edetate (water softener) 5%, 1-hydroxyb...

Embodiment 3

[0100] This embodiment provides a super-amphiphilic neutral metal surface roughening treatment liquid, the super-amphiphilic neutral metal surface roughening treatment liquid includes the following components based on its total mass of 100%: Lanification component A 5 %, haze component B 30% and haze component C 65%;

[0101] The dehydration component A includes alkylsiloxane-modified nano-silica solution and 1-(3-propanesulfonyl)-2-pyrrolidone trifluoroacetate; the dehydration component B includes C16 Hydroalcoholic liquid of fatty acid and 1-(3-propanesulfonyl)-2-pyrrolidone p-toluenesulfonate; based on the total mass of the metal surface roughening treatment liquid as 100%, the haze component C includes N,N-Dimethyl-N-(2-hydroxyethyl) cetyl quaternary ammonium phosphate (lane accelerator) 4%, sodium lauryl sulfate (lane dispersant) 8%, butylene glycol Diglycidyl ether (penetrating agent) 5%, trisodium nitrilotriacetate (water softener) 10%, methyl benzotriazole (metal corr...

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Abstract

The invention provides a neutral metal surface coarsening treatment solution with super-hydrophilicity and super-oleophilicity, and a preparation method and application thereof. The neutral metal surface coarsening treatment solution with super-hydrophilicity and super-oleophilicity comprises the following components according to the total mass of 100%: 2%-10% of chemical components A, 3%-30% of chemical components B and 60%-95% of chemical components C; and the chemical components A comprise mixtures of alkyl siloxane modified nano-silica solutions and catalysts, and the chemical components Acomprise mixtures of fatty acid water alcohol liquid and catalysts. According to the metal surface coarsening treatment solution, through "binary synergy" principles of micro-nano materials, the micro-nano coarsening of the metal surface is achieved, and the super-hydrophilic and super-oleophilic effects of the surface are achieved; and the compatibility of the surface coating materials is higher, and the metal surface adhesion is higher. The coarsening treatment solution provided by the invention is neutral, and is environmentally friendly, safe and recyclable; and zero discharge can be achieved, and the coarsening treatment solution has broad application prospects.

Description

technical field [0001] The invention relates to the technical field of metal surface engineering materials, in particular to a metal surface roughening treatment liquid and its preparation method and application, in particular to a neutral metal surface roughening treatment liquid with superhydrophilic and superlipophilic effects and its Preparation methods and applications. Background technique [0002] At present, the main ways to improve the adhesion of metal surfaces are: physical mechanical methods, such as shot blasting, sandblasting, etc.; chemical methods, such as pickling and phosphating, silanization, vitrification, etc. The purpose of these several treatment methods is to increase the metal surface adhesion by increasing the specific surface area or increasing the roughness of the metal surface. [0003] Physical mechanical processes such as sandblasting and shot blasting mainly use physical mechanical force to physically strike the metal surface, so that uneven ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F1/14
CPCC23F1/14
Inventor 周建辉廖景文刘文锋邓建青
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