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Environment-friendly odorless foaming sole material and method for preparing sole

A sole material and environmental protection technology, applied in the field of polyurethane elasticity, can solve the problems of poor mechanical properties of polyurethane materials, not conforming to green environmental protection, unfavorable to human health, etc., and achieve good economic benefits, good biocompatibility, and improved mechanical properties.

Inactive Publication Date: 2020-08-07
ZHEJIANG NIRUAN NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the polyurethane material produced by the above method has poor mechanical properties and is not suitable for making shoe soles
[0006] Patent CN110105538A discloses a polyurethane elastomer material for shoe soles. The main material is 75-80 parts of polyester polyol, 7-9 parts of chain extender, 35-40 parts of MDI, 0.8-1.3 parts of antioxidant, 0.3- 0.5 parts of catalyst, 4 to 6 parts of modified multi-walled carbon nanotubes, 0.1 to 0.3 parts of organic silicon, 0.2 to 0.4 parts of epoxy soybean oil, and 0.2 to 0.5 parts of sodium stearate. However, the modified Multi-walled carbon nanotubes are carcinogens, which are not conducive to human health and do not meet the requirements of green environmental protection

Method used

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  • Environment-friendly odorless foaming sole material and method for preparing sole
  • Environment-friendly odorless foaming sole material and method for preparing sole
  • Environment-friendly odorless foaming sole material and method for preparing sole

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] An environmentally friendly and odorless foam sole material is made from the following weights:

[0027]

[0028] Wherein the cross-linking agent is a mixture of glycerin, diethanolamine and triethanolamine, glycerol by mass ratio: diethanolamine: triethanolamine=1:1:1;

[0029] Wherein the catalyst is a mixture of triethylenediamine and triethanolamine, which is triethylenediamine in mass ratio: triethanolamine=2:1;

[0030] Wherein the isocyanate is 4,4-diphenylmethane diisocyanate.

[0031] A kind of environmental protection tasteless foaming sole of the present invention, its preparation method is carried out according to the following steps:

[0032] Step 1, according to the above ratio, put starch acetate, silk fibroin, sodium stearate, foaming agent and catalyst into reaction kettle 1 at room temperature, and stir for 2 hours to obtain mixture A;

[0033] Step 2: According to the above ratio, put the polyether polyol into the reaction kettle 2 at room temper...

Embodiment 2

[0036] An environmentally friendly and odorless foam sole material is made from the following weights:

[0037]

[0038] Wherein the cross-linking agent is a mixture of glycerin, diethanolamine and triethanolamine, glycerol by mass ratio: triethanolamine=1:1;

[0039] Wherein the catalyst is triethylenediamine;

[0040] Wherein the isocyanate is 2,4-diphenylmethane diisocyanate.

[0041] A kind of environmental protection tasteless foaming sole of the present invention, its preparation method is carried out according to the following steps:

[0042] Step 1: Put starch acetate, silk fibroin, sodium stearate, foaming agent and catalyst into reaction kettle 1 at room temperature according to the above ratio, and stir for 1 hour to obtain mixture A;

[0043] Step 2: According to the above ratio, put the polyether polyol into the reaction kettle 2 at normal temperature, stir and heat up to 120°C, vacuumize to -0.1MPa, dehydrate and degas for 3.5 hours, then cool down to 60°C, ...

Embodiment 3

[0046] An environmentally friendly and odorless foam sole material is made from the following weights:

[0047]

[0048] Wherein the catalyst is a mixture of triethylenediamine and triethanolamine, which is triethylenediamine in mass ratio: triethanolamine=1:1;

[0049] The isocyanate is a mixture of 2,4-diphenylmethane diisocyanate and 4,4-diphenylmethane diisocyanate, and the mass ratio of the two is 2:1.

[0050] A kind of environmental protection tasteless foaming sole of the present invention, its preparation method is carried out according to the following steps:

[0051] Step 1: Put acetate starch, silk fibroin, sodium stearate, foaming agent and catalyst into reaction kettle 1 at room temperature according to the above-mentioned ratio, and stir for 1.5 hours to obtain mixture A;

[0052] Step 2: According to the above ratio, put the polyether polyol into the reaction kettle 2 at normal temperature, stir and heat up to 120°C, vacuumize to -0.1MPa, dehydrate and dega...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention belongs to the technical field of polyurethane elasticity, and particularly relates to an environment-friendly odorless foaming sole material. An environment-friendly odorless foaming sole is prepared from 60-90 parts of acetate starch, 20-40 parts of silk fibroin, 10-30 parts of polyether polyol, 50-80 parts of isocyanate, 1-4 parts of a cross-linking agent, 0.2-0.8 part of a foaming agent, 5-10 parts of nano bamboo fibers, 5-10 parts of nano silicon dioxide, 5-10 parts of zinc oxide, 1-5 parts of activated carbon, 1-2 parts of silicon carbide, 0.2-0.5 part of sodium stearate and 0.1-0.3 part of a catalyst. The sole product provided by the invention has good mechanical properties and use stability, has biodegradability, and reduces white pollution.

Description

technical field [0001] The invention belongs to the technical field of polyurethane elasticity, and in particular relates to an environmentally friendly and odorless foamed shoe sole material and a method for preparing the shoe sole. [0002] technical background [0003] Shoes are a necessity for human life, and with the continuous development of human civilization, the types of shoes are also constantly enriched, such as men's leather shoes, women's leather shoes, casual shoes, sports shoes, canvas shoes, chemical shoes, sandals, slippers and safety shoes And other kinds of shoes. [0004] The full name of polyurethane is polyurethane, which is a general term for macromolecular compounds containing repeated urethane groups on the main chain. It is a polymer compound obtained by the interaction of binary or polyvalent organic isocyanates and polyol compounds. According to its physical properties and uses, polyurethane can generally be divided into rigid polyurethane foam, f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/48C08G18/64C08G18/32C08K13/04C08K3/36C08K3/22C08K7/24C08K3/34C08K5/098A43B13/04C08G101/00
CPCC08G18/6688C08G18/4081C08G18/48C08G18/6484C08G18/6446C08G18/6492C08G18/3206C08G18/3281C08G18/3275C08K13/04C08K3/36C08K3/22C08K7/24C08K3/34C08K5/098C08K2201/011C08K2003/2296C08G2110/0083
Inventor 倪益玲朱益军
Owner ZHEJIANG NIRUAN NEW MATERIAL CO LTD
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