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A preparation method of high-performance modified polyimide flexible substrate

A polyimide flexible and polyimide technology is applied in the field of preparation of high-performance modified polyimide flexible substrates, and can solve the problem of high dielectric loss and moisture absorption, complex preparation process and mechanical strength. and insufficient toughness, to achieve good high-voltage insulation, mechanical strength and toughness, simple preparation process, and ensure the effect of stickiness

Active Publication Date: 2022-06-28
四川铂利明德科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] With the rapid development of the electronics industry, electronic devices such as personal computers, mobile phones, servers, GPS navigation devices and other household electronic devices are becoming more and more popular. At the same time, electronic devices are getting smaller and smaller, with more and more functions. It is becoming more and more powerful, which makes the current electronic and electrical equipment develop towards "thinning" and "miniaturization". Flexible substrates are an indispensable core component in the field of electronic circuits, and the products are restricted by environmental protection such as RoHS and REACH. Regulations also put forward higher requirements for flexible substrates as core components, as shown in: ①The current conventional flexible substrates have relatively high dielectric constant (Dk), dielectric loss (Df) and moisture absorption , unable to meet the high-frequency and high-speed requirements in 5G applications; ② Insufficient high-voltage insulation performance, unable to meet high-voltage insulation and high current carrying requirements, especially in the application of ultra-thin insulating films (≦5um); ③ Insufficient mechanical strength and toughness , cannot be made into ultra-thin films (≦5um), and are easy to break and have poor bendability compared with thin films (≦10um), and the film-forming process is complicated, the production efficiency is low, the production yield is low, and the cost is high; ④The preparation process is complex, The yield rate is high and the cost is high, which cannot meet the requirements of wide process window (such as medium and low temperature, medium and low pressure process) and low equipment investment and low processing cost

Method used

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  • A preparation method of high-performance modified polyimide flexible substrate
  • A preparation method of high-performance modified polyimide flexible substrate
  • A preparation method of high-performance modified polyimide flexible substrate

Examples

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Embodiment 1

[0040] A preparation method of a high-performance modified polyimide flexible substrate, comprising the following steps:

[0041] Step 1: Add the modified polyimide (MPI) glue, antioxidant, toughening agent, curing agent, anti-aging agent and flame retardant to the mixed solvent of methyl ethyl ketone and xylene, after pretreatment and grinding It is formulated into MPI glue; the pretreatment is distillation pretreatment;

[0042] Step 2: Coat the MPI glue obtained in step 1 on a copper foil with a thickness of 0.005mm, and the coating thickness is 0.001mm, and then enter the tunnel oven at a temperature of 1m / min to dry and pre-cure it at a temperature of 80°C. The glue becomes a pre-cured adhesive layer, and the release film / paper is applied at 320° C. and 0.06 MPa to obtain a single-sided semi-cured MPI adhesive layer substrate. The single-sided semi-cured MPI adhesive layer substrate includes a semi-cured adhesive layer and a foil layer;

[0043] Step 3: Unwind the single...

Embodiment 2

[0046] A preparation method of a high-performance modified polyimide flexible substrate, comprising the following steps:

[0047] Step 1: Add the modified polyimide (MPI) glue and antioxidants, toughening agents, stabilizers, and plasticizers to a mixed solvent of N-methylpyrrolidone (NMP), methanol and chloroform, and pass MPI glue is prepared after pretreatment and grinding; the pretreatment is stirring pretreatment;

[0048] Step 2: Coat the MPI glue obtained in Step 1 on a silver foil with a thickness of 0.5mm, with a coating thickness of 3mm, and then enter a tunnel oven at a temperature of 280°C at a line speed of 26m / min for drying and pre-curing to make the glue It becomes a pre-cured adhesive layer, and the release film / paper is applied at 60°C and 10MPa to obtain a single-sided semi-cured MPI adhesive layer substrate, and the single-sided semi-cured MPI adhesive layer substrate includes a semi-cured adhesive layer and a foil layer;

[0049] Step 3: Preheat the singl...

Embodiment 3

[0053] A preparation method of a high-performance modified polyimide flexible substrate, comprising the following steps:

[0054] Step 1: Add modified polyimide (MPI) glue and stabilizer, plasticizer, UV absorber to N,N-dimethylformamide (DMF), phenol, cyclohexanone and chloroform MPI glue is prepared in the mixed solvent after pretreatment and grinding; the pretreatment is preheating pretreatment;

[0055] Step 2: Coat the MPI glue obtained in Step 1 on an aluminum foil with a thickness of 0.025mm, and the coating thickness is 0.010mm, and then enter a tunnel oven at a temperature of 200 m / min at a line speed of 20m / min for drying and pre-curing to make the glue It becomes a pre-cured adhesive layer, and the release film / paper is applied at 200°C and 0.175MPa to obtain a single-sided semi-cured MPI adhesive layer substrate, and the single-sided semi-cured MPI adhesive layer substrate includes a semi-cured adhesive layer and a foil layer;

[0056] Step 3: Preheat the single-s...

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Abstract

The invention discloses a method for preparing a high-performance modified polyimide flexible substrate. Modified polyimide (MPI) glue and performance-enhancing components are added to an organic solvent, pretreated, and ground to produce MPI glue, and then apply or sputter the MPI glue on the metal foil, and then perform pre-curing, post-curing, and tempering processes to obtain a high-performance MPI flexible substrate. The composite film prepared by the present invention has a lower dielectric constant, dielectric loss and moisture absorption rate, which can meet the high-frequency and high-speed requirements in 5G applications; and has better high-voltage insulation, mechanical strength and toughness; and the preparation The process is simple, and the yield rate is as high as 92%, which meets the needs of various process windows and low-cost production.

Description

technical field [0001] The invention belongs to the technical field of electronic materials, and particularly relates to a preparation method of a high-performance modified polyimide flexible substrate. Background technique [0002] With the rapid development of the electronics industry, electronic devices such as personal computers, mobile phones, servers, GPS navigation devices and other household electronic devices are becoming more and more popular. More and more powerful, the current electronic and electrical equipment is developing towards "thinning" and "miniaturization". The flexible substrate is an essential core component in the field of electronic circuits, and the products are limited by environmental protection such as RoHS and REACH. Regulations have also put forward higher requirements for flexible substrates as core components, which are embodied in: ① The current conventional flexible substrates have high dielectric constant (Dk), dielectric loss (Df) and mo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29D7/01B29C65/52B29C65/02B29C71/02C09J7/28B32B15/20B32B7/12B32B7/06B32B33/00
CPCB29D7/01B29C65/52B29C65/02B29C71/02C09J7/28B32B15/20B32B7/12B32B7/06B32B33/00C09J2479/08B32B2255/06B32B2255/26B32B2307/306B32B2307/206B32B2307/558B29C2071/027
Inventor 钱令习张维熙郑全智宛如晴陈伟
Owner 四川铂利明德科技有限公司