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Preparation method of high-performance modified polyimide (MPI) flexible substrate

A polyimide flexible and high-performance technology, applied in chemical instruments and methods, flat products, film/sheet adhesives, etc., can solve the problem of high dielectric loss and high moisture absorption, which cannot meet high-voltage insulation With high current carrying requirements, easy breakage and bendability, etc., it achieves good high-voltage insulation, mechanical strength and toughness, meets the process window and low-cost production, and improves high temperature resistance and stickiness.

Active Publication Date: 2020-09-29
四川铂利明德科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the rapid development of the electronics industry, electronic devices such as personal computers, mobile phones, servers, GPS navigation devices and other household electronic devices are becoming more and more popular. At the same time, electronic devices are getting smaller and smaller, with more and more functions. It is becoming more and more powerful, which makes the current electronic and electrical equipment develop towards "thinning" and "miniaturization". Flexible substrates are an indispensable core component in the field of electronic circuits, and the products are restricted by environmental protection such as RoHS and REACH. Regulations also put forward higher requirements for flexible substrates as core components, as shown in: ①The current conventional flexible substrates have relatively high dielectric constant (Dk), dielectric loss (Df) and moisture absorption , unable to meet the high-frequency and high-speed requirements in 5G applications; ② Insufficient high-voltage insulation performance, unable to meet high-voltage insulation and high current carrying requirements, especially in the application of ultra-thin insulating films (≦5um); ③ Insufficient mechanical strength and toughness , cannot be made into ultra-thin films (≦5um), and are easy to break and have poor bendability compared with thin films (≦10um), and the film-forming process is complicated, the production efficiency is low, the production yield is low, and the cost is high; ④The preparation process is complex, The yield rate is high and the cost is high, which cannot meet the requirements of wide process window (such as medium and low temperature, medium and low pressure process) and low equipment investment and low processing cost

Method used

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  • Preparation method of high-performance modified polyimide (MPI) flexible substrate
  • Preparation method of high-performance modified polyimide (MPI) flexible substrate
  • Preparation method of high-performance modified polyimide (MPI) flexible substrate

Examples

Experimental program
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Effect test

Embodiment 1

[0040] A method for preparing a high-performance modified polyimide flexible substrate, comprising the steps of:

[0041] Step 1: Add the modified polyimide (MPI) glue and antioxidant, toughening agent, curing agent, antiaging agent and flame retardant to the mixed solvent of butanone and xylene, after pretreatment and grinding Prepared as MPI glue; the pretreatment is distillation pretreatment;

[0042] Step 2: Coat the MPI glue obtained in step 1 on a copper foil with a thickness of 0.005mm, and the thickness of the coating is 0.001mm, and then enter the tunnel oven at a temperature of 80°C at a line speed of 1m / min to dry and pre-cure, so that The glue becomes a pre-cured adhesive layer, and the release film / paper is applied at 320°C and 0.06MPa to obtain a single-sided semi-cured MPI adhesive-layer substrate, which includes a semi-cured adhesive layer and a foil layer;

[0043] Step 3: Unwind the single-sided semi-cured MPI adhesive layer substrate obtained in step 2 and ...

Embodiment 2

[0046] A method for preparing a high-performance modified polyimide flexible substrate, comprising the steps of:

[0047] Step 1: Add modified polyimide (MPI) glue and antioxidant, toughening agent, stabilizer, plasticizer to N-methylpyrrolidone (NMP), in the mixed solvent of methyl alcohol and chloroform, through Prepare MPI glue after pretreatment and grinding; the pretreatment is stirring pretreatment;

[0048] Step 2: Coat the MPI glue obtained in step 1 on a silver foil with a thickness of 0.5mm, and the coating thickness is 3mm, and then enter a tunnel oven at a temperature of 280°C at a line speed of 26m / min for drying and pre-curing, so that the glue Become a pre-cured adhesive layer, apply a release film / paper at 60°C and 10MPa to obtain a single-sided semi-cured MPI adhesive-line substrate, and the single-sided semi-cured MPI adhesive-line substrate includes a semi-cured adhesive layer and a foil layer;

[0049] Step 3: Preheat the single-sided semi-cured MPI adhesi...

Embodiment 3

[0053] A method for preparing a high-performance modified polyimide flexible substrate, comprising the steps of:

[0054] Step 1: Add modified polyimide (MPI) glue and stabilizer, plasticizer, UV absorber to N,N-dimethylformamide (DMF), phenol, cyclohexanone and chloroform In the mixed solvent, it is prepared into MPI glue after pretreatment and grinding; the pretreatment is preheating pretreatment;

[0055] Step 2: Coat the MPI glue obtained in step 1 on an aluminum foil with a thickness of 0.025mm, and the coating thickness is 0.010mm, and then enter a tunnel oven at a temperature of 200°C at a line speed of 20m / min to dry and pre-cure, so that the glue Become a pre-cured adhesive layer, apply a release film / paper at 200°C and 0.175MPa to obtain a single-sided semi-cured MPI adhesive-line substrate, and the single-sided semi-cured MPI adhesive-line substrate includes a semi-cured adhesive layer and a foil layer;

[0056] Step 3: Preheat the single-sided semi-cured MPI adhes...

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Abstract

The invention discloses a preparation method of a high-performance modified polyimide (MPI) flexible substrate. An MPI adhesive and performance strengthening components are added into an organic medium solvent, MPI glue is prepared by grinding after pretreatment, then metal foil is coated with the MPI glue or the MPI glue is sputtered on the metal foil, then precuring, postcuring and tempering treatment processes are carried out, and thus the high-performance MPI flexible substrate is obtained. A composite film prepared by the preparation method has the low dielectric constant, dielectric lossand moisture absorption rate, and can meet the high-frequency and high-speed requirements in 5G application; good high-voltage insulation resistance, mechanical strength and toughness are realized; and the preparation process is simple, the yield is up to 92% or above, and the demands of various process windows and low-cost production are met.

Description

technical field [0001] The invention belongs to the technical field of electronic materials, and in particular relates to a method for preparing a high-performance modified polyimide flexible substrate. Background technique [0002] With the rapid development of the electronics industry, electronic devices such as personal computers, mobile phones, servers, GPS navigation devices and other household electronic devices are becoming more and more popular. At the same time, electronic devices are getting smaller and smaller, with more and more functions. It is becoming more and more powerful, which makes the current electronic and electrical equipment develop towards "thinning" and "miniaturization". Flexible substrates are an indispensable core component in the field of electronic circuits, and the products are restricted by environmental protection such as RoHS and REACH. Regulations also put forward higher requirements for flexible substrates as core components, as shown in:...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29D7/01B29C65/52B29C65/02B29C71/02C09J7/28B32B15/20B32B7/12B32B7/06B32B33/00
CPCB29D7/01B29C65/52B29C65/02B29C71/02C09J7/28B32B15/20B32B7/12B32B7/06B32B33/00C09J2479/08B32B2255/06B32B2255/26B32B2307/306B32B2307/206B32B2307/558B29C2071/027
Inventor 钱令习张维熙郑全智宛如晴陈伟
Owner 四川铂利明德科技有限公司
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