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Manufacturing method of lithium ion battery negative electrode structure and lithium ion battery negative electrode structure

A lithium-ion battery and manufacturing method technology, applied in electrode manufacturing, battery electrodes, negative electrodes, etc., can solve the problems of large surface of nano-materials, difficult to filter and wash, affecting battery performance, etc., and achieve good crystallinity and high production efficiency. , to ensure the effect of battery performance

Inactive Publication Date: 2020-10-02
SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the preparation of nano-Fe 3 o 4 Most of the methods of materials are hydrothermal method, thermal decomposition, co-precipitation method, etc. Co-precipitation method is simple, convenient and easy to implement, but most of the precipitates are in colloidal state, which is difficult to filter and wash, and it is easy to introduce impurities. Large, easy to aggregate together, ferromagnetic material is ferromagnetic, and there is magnetic attraction between particles, so it is easier to aggregate together
Therefore, the agglomeration phenomenon of the product obtained by the co-precipitation method is very obvious, and it will seriously affect the performance of the battery when used as the negative electrode of the battery.
Although the agglomeration phenomenon has been alleviated by the hydrothermal method, it still exists obviously, and it will also affect the performance of the battery when used as the negative electrode of the battery.
The thermal decomposition method first needs to synthesize ferric oleate as a thermal decomposition precursor; the synthesis of ferric oleate has a great influence on the subsequent results, the system is relatively complex, and impurities are easily introduced, and the use of the negative electrode of the battery will also affect the performance of the battery

Method used

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  • Manufacturing method of lithium ion battery negative electrode structure and lithium ion battery negative electrode structure
  • Manufacturing method of lithium ion battery negative electrode structure and lithium ion battery negative electrode structure
  • Manufacturing method of lithium ion battery negative electrode structure and lithium ion battery negative electrode structure

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Embodiment 1

[0058] A kind of manufacturing method of lithium-ion battery negative electrode structure, such as figure 1 shown, including the following steps:

[0059] Provide a collector plate 1;

[0060] Attach a porous nano-template 2 on the current collector plate 1;

[0061] Forming a plurality of nano-array columns 3 in the holes 21 of the porous nano-template 2 by means of pulsed laser deposition;

[0062] The porous nano-template 2 is removed, and the nano-array pillars 3 are fixed on the current collector plate 1 in a protruding array to obtain a lithium-ion battery negative electrode structure.

[0063] The lithium-ion battery negative electrode structure prepared by the present invention includes a current collector plate 1 and a plurality of nano-array columns 3 protrudingly arrayed and fixed on the current collector plate 1, wherein the diameter of the nano-array columns 3 is between 90-300nm, and the nano-array The height of the columns 3 is between 50-400nm, and the spaci...

Embodiment 2

[0069] A method for manufacturing a lithium-ion battery negative electrode structure, comprising the steps of: figure 1 As shown, a current collector plate 1 is provided; the current collector plate 1 is copper foil.

[0070] Attach a porous nano-template 2 on the current collector plate 1;

[0071] A plurality of nano-array columns 3 are formed in the holes 21 of the porous nano-template 2 by means of pulsed laser deposition; the nano-array columns 3 are Fe 3 o 4 Nano-array column 3; the copper foil is heated to 300-500° C. before pulsed laser deposition, the laser energy is 250-350 mJ, and the laser frequency is 5-10 Hz.

[0072] The porous nano-template 2 is removed, and the nano-array column 3 is fixed on the current collector plate 1 in a protruding array, wherein the diameter of the nano-array column 3 is between 90-300nm, and the height of the nano-array column 3 is between 50-400nm, The distance between nano-array pillars 3 is 65-125nm.

[0073] Fe 3 o 4 The nano...

Embodiment 3

[0076] A kind of manufacturing method of lithium-ion battery negative electrode structure, such as figure 1 shown, including the following steps:

[0077] (1) Cut the metal foil and clean and pre-treat it;

[0078] (2) Soak the PMMA / AAO template in an organic solvent to separate the PMMA support layer, and then attach it to the cleaned and pretreated metal foil to prepare the metal foil attached to the AAO template;

[0079] (3) On the metal foil bonded with the AAO template obtained in the above step (2), a highly ordered Fe 3 o 4 Nanoarray;

[0080] (4) For the Fe prepared in the above step (3) 3 o 4 The nano-array sample is cooled, and then the AAO template is glued off.

[0081] Wherein the organic solvent preferably uses acetone.

[0082] Preferably in this embodiment, the metal foil is copper foil, and step (1) specifically includes the following steps:

[0083] a. Soak the Cu foil in acetone and ultrasonically clean it for 5-20 minutes;

[0084] b. Then immerse t...

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Abstract

The invention relates to the technical field of battery negative electrode structures, in particular to a manufacturing method of a lithium ion battery negative electrode structure and the lithium ionbattery negative electrode structure. The method comprises the following steps of providing a current collector plate; attaching a porous nano template to the current collector plate; forming a plurality of nano array columns in holes of the porous nano template in a pulse laser deposition manner; and removing the porous nano template, fixing the removed nano array columns to the current collector plate in a protruding array manner, wherein the diameter of the nano array columns ranges from 90 nm to 300 nm, the height of the nano array columns ranges from 50 nm to 400 nm, and the distance between the nano array columns ranges from 65 nm to 125 nm. The method is reliable in preparation process, high in repeatability, simple in raw material and good in sample crystallinity, and the introduction of impurities can be well avoided. The nano array columns on the battery negative electrode are highly ordered and are tightly combined with the current collector plate, so that excellent conductivity and ultralow ion diffusion resistance can be provided.

Description

technical field [0001] The invention relates to the technical field of battery negative pole structures, in particular to a manufacturing method of the lithium ion battery negative pole structure and the lithium ion battery negative pole structure. Background technique [0002] With the continuous consumption of fossil energy and the pursuit of clean and non-polluting energy, the development of new energy is one of the eternal themes of contemporary times. Rechargeable batteries are widely used in the field of electrochemical energy storage. Among them, lithium-ion batteries have dominated the market in consumer electronics, electric vehicles and other fields due to their high energy density, small size, light weight, and long service life. status. At present, carbon materials are usually used for the negative electrode of lithium-ion batteries, and graphite has been used in commercial lithium-ion battery negative electrodes. However, the theoretical specific capacity of c...

Claims

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Application Information

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IPC IPC(8): H01M4/1391H01M4/04H01M4/131H01M4/52H01M10/0525C01G49/08B82Y40/00
CPCB82Y40/00C01G49/08H01M4/0423H01M4/131H01M4/1391H01M4/523H01M10/0525H01M2004/021H01M2004/027Y02E60/10
Inventor 钟高阔訾孟飞任传来安峰李江宇
Owner SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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