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Method for producing alloy through processing slag of autothermal furnace with direct current electric arc furnace

A DC electric arc furnace, a technology for producing alloys, applied in the direction of improving process efficiency, etc., can solve the problems of ineffective use of valuable components, large disturbances in the production system, and difficult control of the production process, so as to save cable materials and achieve good Stirring effect, the effect of saving refractory consumption

Inactive Publication Date: 2020-10-16
JINCHUAN GROUP LIMITED
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Since there is no good treatment method, the slag produced by the self-heating furnace system has been piled up for a long time, which not only occupies a large amount of land, but also affects the surrounding ecological environment. Nickel, copper, iron, cobalt, gold, silver, etc. in the self-heating furnace slag have If the valence components are not effectively utilized, this resource will be greatly wasted
[0004] According to the different raw material conditions and smelting process, at present, a small amount of slag from the autothermal furnace is added to the converter and top-blown furnace for processing, which has the disadvantages of large disturbance to the normal production system, more metal losses such as nickel and copper, and the production process is difficult to control.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] 1. Mix the cold self-heating furnace slag with a particle size of less than 5mm, reducing agent and calcium flux evenly, then feed it into the DC electric arc furnace through the feeding port, and heat it up to 1400°C to form a molten slag pool.

[0033] 2. The Ni+Cu grade of autothermal furnace slag is 16.30%, the addition amount of reducing agent granular coal is 8.00%, and the addition amount of flux limestone is 20.00%.

[0034] 3. The molten slag pool was reduced and smelted at 1400°C for 45 minutes.

[0035] 4. After the holding time is over, liquid metal and tailings are discharged respectively to obtain copper-nickel alloy.

[0036] 5. The Ni+Cu grade of the produced copper-nickel alloy is 94.75%, the recovery rate of Ni is 99.20%, and the recovery rate of Cu is 98.90%.

Embodiment 2

[0038] 1. Mix the cold self-heating furnace slag with a particle size of less than 5mm, reducing agent and calcium flux evenly, then feed it into the DC electric arc furnace through the feeding port, and heat it up to 1400°C to form a molten slag pool.

[0039] 2. The Ni+Cu grade of autothermal furnace slag is 16.30%, the addition amount of reducing agent granular coal is 10.00%, and the addition amount of flux limestone is 25.00%.

[0040] 3. The molten slag pool was reduced and smelted at 1400°C for 45 minutes.

[0041] 4. After the holding time is over, liquid metal and tailings are discharged respectively to obtain copper-nickel alloy.

[0042] 5. The Ni+Cu grade of the produced copper-nickel alloy is 95.80%, the recovery rate of Ni is 99.50%, and the recovery rate of Cu is 99.15%.

Embodiment 3

[0044] 1. Mix the cold self-heating furnace slag with a particle size of less than 5mm, reducing agent and calcium flux evenly, then feed it into the DC electric arc furnace through the feeding port, and heat it up to 1400°C to form a molten slag pool.

[0045] 2. The Ni+Cu grade of autothermal furnace slag is 16.30%, the addition amount of reducing agent granular coal is 15.00%, and the addition amount of flux limestone is 30.00%.

[0046] 3. The molten slag pool was reduced and smelted at 1400°C for 45 minutes.

[0047] 4. After the holding time is over, liquid metal and tailings are discharged respectively to obtain copper-nickel alloy.

[0048] 5. The Ni+Cu grade of the produced copper-nickel alloy is 95.15%, the recovery rate of Ni is 99.10%, and the recovery rate of Cu is 98.70%.

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Abstract

The invention discloses a method for producing an alloy through processing slag of an autothermal furnace with a direct current electric arc furnace, and relates to a comprehensive processing method of nickel copper smelting slag. The method for producing the alloy through processing slag of the autothermal furnace with the direct current electric arc furnace is characterized in that a process ofthe method is to uniformly mix the slag of the autothermal furnace, reducing agent and calcic flux, then, perform reduction smelting at the direct current electric arc furnace, automatically layer reduction products according to different specific gravity, and respectively discharge a liquid metal and tailings, wherein the liquid metal is a copper nickel alloy. The method provided by the inventioncan fully use molten hot slag of the autothermal furnace, also can process stacked cold slag, can realize efficient synchronous separation and recycling of nickel and copper metals by adjusting amount of the reducing agent, the flux and reducing time, can solve problems of too much stockpiling of the slag and environment pollution, can optimize a technological process and simultaneously can effectively improve operation technology economic indicators of a system.

Description

technical field [0001] A method for producing alloys by treating autothermal furnace slag with a DC electric arc furnace, involving comprehensive treatment of nickel-copper smelting slag, in particular a method for producing copper-nickel alloys by using a DC electric arc furnace to reduce and smelt autothermal furnace slag to recover valuable metals . Background technique [0002] In the smelting and production of nickel and copper, the concentrates containing nickel and copper are processed by a high-sulfur mill-floating system to obtain secondary nickel concentrates and secondary copper concentrates, respectively. The main raw material for the self-heating furnace system of the pyromelting system is secondary copper concentrate, and its reaction zone is located in the slag layer. Sulfur blister copper and slag are released intermittently, and the produced slag is a desulfurized high-grade oxide slag with high copper content and low nickel content, in which the Ni+Cu grad...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B7/04C22B5/10C22B15/00C22B23/02
CPCC22B5/10C22B7/001C22B7/04C22B15/0054C22B23/021Y02P10/20
Inventor 马晓东邓民晖吕清华张鹏钱文元苏俊敏王玉芳迟刚赵秀丽王瑄
Owner JINCHUAN GROUP LIMITED
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