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Environment-friendly conductive elastic copper alloy and preparation method thereof and application in connectors

An elastic copper alloy, environment-friendly technology, applied in conductive materials, conductive materials, metal/alloy conductors, etc. Poor bending performance, unable to meet the needs of functional terminal connector materials, etc., to achieve the effect of good stress relaxation resistance, good comprehensive performance, and excellent corrosion resistance in complex environments

Pending Publication Date: 2020-12-22
NINGBO XINGYE SHENGTAI GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, beryllium bronze is the main copper alloy elastic material used in high-reliability connectors at home and abroad. However, because the beryllium bronze alloy contains the highly toxic substance beryllium and the stress relaxation rate increases sharply in an environment higher than 150 ° C, it is easy to cause elastic elements The contact pressure of the device in the working state changes, causing the connector to fail
In addition, since the tin phosphor bronze alloy is a work-hardening alloy, the alloy is poor in bending forming, high temperature stress relaxation resistance and electrical conductivity, which cannot meet the needs of high-end connectors
[0004] Copper-titanium and copper-nickel-tin alloys have high strength, elasticity and other properties comparable to beryllium bronze, as well as superior processing and forming properties, corrosion resistance and high temperature stress relaxation resistance. The above two alloys have been successively studied by the United States, Japan and other countries Developed and industrialized, the typical grades are C19900, NKT322 and C72700, C72900, etc. The former has more excellent bending forming performance and meets the needs of more miniaturized structural connectors, while the latter has more excellent corrosion resistance and meets corrosion resistance The use requirements of environmental connectors are used in important fields such as aerospace, communication, and mobile terminals. However, due to insufficient conductivity, they cannot meet the use requirements of functional terminal connector materials. The new generation of high-strength conductive materials is Cu-Ni- The yield strength of Co-Si alloys in industrial production is 800~850MPa, and the strength needs to be improved. At the same time, the bending performance of Cu-Ni-Co-Si alloys is also poor.

Method used

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  • Environment-friendly conductive elastic copper alloy and preparation method thereof and application in connectors
  • Environment-friendly conductive elastic copper alloy and preparation method thereof and application in connectors
  • Environment-friendly conductive elastic copper alloy and preparation method thereof and application in connectors

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preparation example Construction

[0037] The present invention also provides a preparation method of the environment-friendly conductive elastic copper alloy described in the above scheme, comprising the following steps:

[0038] (1) Melting and casting copper alloy raw materials to obtain ingots;

[0039] (2) The ingot is sequentially subjected to hot rolling, initial rolling, intermediate annealing treatment, intermediate rolling, rapid solution treatment, finish rolling and aging treatment to obtain an environmentally friendly conductive elastic copper alloy.

[0040] In the invention, copper alloy raw materials are smelted and cast to obtain ingots. In the present invention, ingredients are prepared according to the mass percentages of the elements in the copper alloy, and then the copper alloy raw materials are sequentially melted and cast. In the present invention, the copper alloy raw material is preferably electrolytic copper, electrolytic nickel, nickel-silicon alloy, copper-manganese alloy and coppe...

Embodiment 1

[0054] The composition of the alloy is shown in Table 1.

[0055] 1. Melting: Add electrolytic copper, electrolytic nickel, nickel-silicon alloy, and copper-manganese alloy into a non-vacuum induction furnace, and control the melting temperature to 1260°C. After the above materials are melted, continue to add copper-magnesium alloy until the melt is completely melted Finally, pour the melt into the holding furnace and stir evenly, hold it for 20 minutes and then cast it at 1160°C to obtain an ingot.

[0056] 2. Hot rolling: the above-mentioned cast ingot is heated in a walking box furnace at a temperature of 950°C, and the holding time is 3 hours, and then hot rolled, and the final rolling temperature is controlled at 800°C, followed by water cooling.

[0057] 3. Preliminary rolling: Preliminary rolling is carried out after milling the water-cooled alloy billet, and the cold rolling processing rate is 65%.

[0058] 4. Intermediate annealing treatment: Place the bloom in a bel...

Embodiment 2

[0065] The composition of the alloy is shown in Table 1.

[0066] 1. Melting: Add electrolytic copper, electrolytic nickel, nickel-silicon alloy, and copper-manganese alloy into a non-vacuum induction furnace, and control the melting temperature to 1250°C. After the above materials are melted, continue to add copper-magnesium alloy until the melt is completely melted Finally, pour the melt into the holding furnace and stir evenly, hold it for 20 minutes and then cast it at 1150°C.

[0067]2. Hot rolling: The obtained ingot is heated in a walking box furnace at a temperature of 930°C, and the holding time is 5 hours, and then hot rolled, and the final rolling temperature is controlled at 780°C, followed by water cooling.

[0068] 3. Preliminary rolling: Preliminary rolling is carried out after milling the water-cooled alloy billet, and the cold rolling processing rate is 70%.

[0069] 4. Intermediate annealing treatment: place the bloom in a bell-type annealing furnace for int...

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Abstract

The invention belongs to the technical field of non-ferrous metal processing, and provides an environment-friendly conductive elastic copper alloy and a preparation method and application thereof. Thecopper alloy comprises, by weight, 2.0-4.3% of Ni, 0.5-0.85% of Si, 0.05-0.4% of Mn, 0.01-0.2% of Mg, 0.01-1.0% of rare earth element and the balance of Cu. The copper alloy can keep high conductivity while having ultrahigh strength, has the characteristics of being high-temperature-resistant, stress-relaxation- resistant, complex-environment-corrosion-resistant and high in elasticity, is excellent in forming performance and high in reliability, can meet the use requirements of connectors in different application scenes, and is a new generation of alloy material for the connectors. Accordingto the preparation method, the copper alloy is prepared through smelting, casting, hot rolling, primary rolling, intermediate annealing, intermediate rolling, rapid solution treatment, finish rollingand aging treatment, so that the microstructure of the copper alloy can be effectively controlled, and various properties of the copper alloy are guaranteed.

Description

technical field [0001] The invention relates to the technical field of nonferrous metal processing, in particular to an environment-friendly conductive elastic copper alloy, a preparation method thereof and an application in a connector. Background technique [0002] As a key component of current or signal connection, the connector is an important part of the industrial system. It is widely used in military, communication, automobile, electronics and other fields. Among them, high-performance copper alloy material is the key raw material for the connector to realize its function. With the rapid development of 5G communications, mobile terminals, artificial intelligence, aerospace and other important fields, connector technology is mainly developing in the direction of miniaturization, integration, intelligence, high performance and user-friendly use, which requires connectors Not only is the size smaller, but the performance is required to develop in the direction of high fr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/06C22C1/02C22F1/08C22F1/02H01B1/02
CPCC22C1/02C22C9/06C22F1/02C22F1/08H01B1/026
Inventor 刘峰杨振马吉苗雷伏庆蒋志晶陈军郑芸王平刘宁
Owner NINGBO XINGYE SHENGTAI GROUP
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