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Flame retardant and application thereof

A flame retardant and flame retardant technology, applied in the field of flame retardant, can solve the problems of large amount of smoke, toxicity, and large amount of flame retardants, etc., so as to improve the poor performance of high temperature fire resistance, improve the efficiency of flame retardant, and make a good transition The effect of action

Pending Publication Date: 2021-01-01
ZHEJIANG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Traditional flame retardants are gradually being replaced by a new generation of environmentally friendly flame retardants due to their serious shortcomings such as large additions, large amounts of smoke, and generation of toxic and corrosive gases.

Method used

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  • Flame retardant and application thereof
  • Flame retardant and application thereof
  • Flame retardant and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056]Weigh 16g fumed white carbon black, 0.2g sodium dodecylbenzene sulfonate, 1g maleic anhydride, mix them in a high-speed mixer (temperature 115℃, time 5min, 800r / min), then add 160g low linearity Density polyethylene particles (Yuyao Changying Plastic Chemical Co., Ltd., model LLDPE-5110), after being uniformly mixed, pelletized by single screw extrusion (temperature 120~180℃) to obtain 174g of reinforced carbon chain polymerization Masterbatch.

[0057]Weigh 40g aluminum hypophosphite, 20g sorbitol, 40g melamine in proportion, dissolve them with 1300ml 92% alcohol aqueous solution, stir magnetically for 5min, add 2g sodium lauryl sulfate, 0.5g sodium persulfate, and heat to Keep the temperature at 45°C and stir for 2h. After the mixture is uniform, cool at room temperature. 1g of vinyl triethoxy silane was dropped into the mixed solution, the temperature was raised to 65°C, kept for 3h and stirred, the mixture was cooled to room temperature, and suction filtered, the solid obtain...

Embodiment 2

[0060]Weigh 20g fumed white carbon black, 0.2g sodium dodecylbenzene sulfonate, 1g maleic anhydride, mix them in a high-speed mixer (temperature 115℃, time 5min, 800r / min), then add 160g polypropylene The particles (Yuyao Changying Plastic Chemical Co., Ltd., model is PP-T30S), after being mixed uniformly, pelletized by single screw extrusion (temperature 120~180℃) to obtain 178g reinforced carbon chain polymer masterbatch .

[0061]Weigh 50g of aluminum hypophosphite, 15g of sorbitol, and 35g of melamine in proportion, dissolve them with 1300ml of 92% alcohol aqueous solution, magnetically stir for 5min, add 3g of sodium lauryl sulfate and 0.5g of sodium persulfate, and heat to Keep the temperature at 45°C, stir for 2h, and cool down at room temperature after mixing. 3g of vinyl triethoxy silane was dropped into the mixed solution, the temperature was raised to 65°C, kept for 3h and stirred, the mixture was cooled to room temperature, and filtered with suction. The obtained solid was ...

Embodiment 3

[0064]Weigh 16g fumed white carbon black, 0.2g sodium dodecylbenzene sulfonate, 1g maleic anhydride, mix them in a high-speed mixer (temperature 115℃, time 5min, 800r / min), then add 160g ethylene- Vinyl acetate copolymer particles (Jiangsu Feimai Plastics and Chemical Co., Ltd., model 3170), after mixing uniformly, granulate by single screw extrusion (temperature 120~180℃) to obtain 174g reinforced carbon chain polymer masterbatch .

[0065]Weigh 40g aluminum hypophosphite, 20g sorbitol, 40g melamine in proportion, dissolve them with 1300ml 92% alcohol aqueous solution, stir magnetically for 5min, add 2g sodium lauryl sulfate, 0.5g sodium persulfate, and heat to Keep the temperature at 45°C and stir for 2h. After the mixture is uniform, cool at room temperature. 1g of vinyl triethoxy silane was dropped into the mixed solution, the temperature was raised to 65 ℃, kept for 3 hours and stirred, the mixture was cooled to room temperature, and suction filtration, the obtained solid was wash...

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Abstract

The invention provides a flame retardant and application thereof in preparation of a flame-retardant and fire-resistant cable sheath material. The flame retardant is prepared from, by mass, 40-50 parts of aluminum hypophosphite, 15-20 parts of sorbitol, 30-40 parts of melamine, 2-3 parts of lauryl sodium sulfate, 0.5 part of sodium persulfate and 1-3 parts of vinyltriethoxysilane. By adding the self-made flame retardant into the fire-resistant cable sheath material, the flame-retardant efficiency is remarkably improved, the addition amount of the flame retardant is reduced by 50% or above under the same flame-retardant effect of the prepared product, and the problem of poor high-temperature fire resistance caused by large filling amount of the flame retardant of a traditional flame-retardant and fire-resistant cable is solved; and the cable sheath material has better mechanical properties at 800 DEG C, plays a good transition role in porcelain formation at high temperature, and ensuresthe fire resistance of the cable sheath.

Description

Technical field[0001]The present invention relates to the field of flame retardant technology, in particular to a flame retardant and its application in the preparation of a halogen-free polyolefin cable sheath material with flame retardant and high temperature fire resistance.Background technique[0002]Ordinary flame-retardant PVC wires and cables have good flame-retardant properties, but will release a large amount of smoke and toxic hydrogen chloride gas when burned. They are non-environmentally friendly products. With the increase of domestic requirements for flame-retardant, my country's PVC wire and cable The consumption has begun to show a downward trend, and the environmentally friendly halogen-free flame-retardant cable materials have been greatly developed in recent years. Although traditional flame-retardant cables have good flame-retardant effects, are non-flammable and self-extinguishing, they cannot maintain the integrity of the circuit if the fire lasts for a long time...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K3/32C08K5/053C08K5/3492C08K5/41C08K5/5425C08L23/12C08L23/08C08L23/06C08L91/06C08L83/04C08K13/04C08K7/26C08K3/38C08K3/34C08K3/36C08K3/40C08K5/098H01B3/44
CPCC08K3/32C08K5/053C08K5/34922C08K5/41C08K5/5425C08K13/04C08K7/26C08K3/38C08K3/34C08K3/36C08K3/40C08K5/098C08K5/1345C08L23/12C08L23/0853C08L23/0815H01B3/441C08L2201/02C08L2203/202C08K2003/387C08K2201/014C08L23/06C08K3/346C08L91/06C08L83/04
Inventor 盛嘉伟沈佳培张俭孙青
Owner ZHEJIANG UNIV OF TECH