A modified high blood-sucking polyurethane sponge, preparation method and use thereof

A polyurethane sponge, modified technology, applied in the direction of absorbent pads, bandages, medical science, etc., can solve the problems of increased biological toxicity, poor absorption performance, and decreased mechanical properties, so as to reduce the reduction of absorption capacity and improve blood absorption capacity , the effect of increasing biosecurity

Active Publication Date: 2022-07-12
WANHUA CHEM GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it uses organotin as a catalyst and dichloromethane as a blowing agent, and the residues of the two chemicals will increase biological toxicity and affect its application in the medical and health field
[0004] Invention patent CN 110577627A discloses a method for preparing an absorbent material with high absorption capacity. The polyols used in this method are all polyether polyols. The obtained polyurethane foam will swell severely after sucking blood, and its mechanical properties will drop significantly. Affect the user experience; at the same time, the material has poor degradability, and the swelling is serious after absorbing blood, and the mechanical properties drop significantly after absorbing blood
Large porosity, poor absorption performance, unable to overcome gravity to effectively distribute fluid, resulting in poor liquid permeability of foam, low absorption utilization rate, and poor absorption effect
Secondly, excessive fluid confinement interacts with SAP particles and polyoxyethylene segment soft segments, resulting in severe local expansion after fluid absorption and rapid strength decline, which affects its application and promotion in the field of hygiene products
[0008] 2) Polyurethane foam containing SAP has poor blood absorption
At present, SAP-containing polyurethane high-absorbency foam can effectively absorb simple fluids such as water and urine, but blood, a complex fluid, contains dissolved organic matter such as blood cells and proteins, metal ions, etc.; blood cells and proteins will cause the fluid to have a high viscosity. At the same time, after absorption, it covers the surface of the absorber to inhibit further blood absorption; metal ions coordinate with the surface of the absorber, causing the absorber to lose its absorbing capacity, which greatly affects the ability of the foam absorber to absorb and store blood, resulting in utilization. Low and poor usability

Method used

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  • A modified high blood-sucking polyurethane sponge, preparation method and use thereof
  • A modified high blood-sucking polyurethane sponge, preparation method and use thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0079] A, take by weight respectively: a kind of modified high blood-sucking polyurethane sponge is made by the raw material that comprises following weight portion: 30 parts of isocyanates, wherein the mass ratio of methyl isocyanate and hexamethylene isocyanate is 6:4 , 18 parts of polylactic acid glycol, 42 parts of PEG-2000, 15 parts of fluff pulp, 30 parts of super absorbent WHS 300, 5 parts of chitosan, 90 parts of water, hydrophilic surfactant ( PE6400: 188=1:2) 5 parts, chain extender TMP 2 parts, inorganic filler 300 mesh diatomaceous earth 20 parts, antioxidant IRGASTAB PUR 68 0.3 parts;

[0080] B. Place isocyanate, polyether polyol, polyester polyol, polymer polyol, chain extender, and antioxidant at 80°C for 12 hours to react to obtain a polyol modified prepolymer;

[0081] C. Mix the fluff pulp fiber, chitosan, hydrophilic surfactant, inorganic filler with water to obtain white material, and keep it at 20±2℃;

[0082] D. Heat the prepolymer to 40°C, then mix ...

Embodiment 2

[0086] A, take by weighing respectively by weight: a kind of modified high blood-sucking polyurethane sponge is made by the raw material that comprises following weight portion: 30 parts of isocyanates, wherein the ratio of methyl isocyanate and hexamethylene isocyanate is 6:4, 36 parts of polylactic acid glycol, 84 parts of PEG-2000, 15 parts of fluff pulp, 30 parts of superabsorbent WHS 300, 5 parts of chitosan, 90 parts of water, hydrophilic surfactant ( PE6400: 188=1:2) 5 parts, chain extender TMP 2 parts, inorganic filler 300 mesh diatomaceous earth 20 parts, antioxidant IRGASTAB PUR 68 0.3 parts;

[0087] B. Place isocyanate, polyether polyol, polyester polyol, polymer polyol, chain extender, and antioxidant at 80°C for 12 hours to react to obtain a polyol modified prepolymer;

[0088] C. Mix the fluff pulp fiber, chitosan, hydrophilic surfactant, inorganic filler with water to obtain white material, and keep it at 20±2℃;

[0089] D. Heat the prepolymer to 40°C, then...

Embodiment 3

[0093] A, take by weighing respectively by weight: a kind of modified high blood-sucking polyurethane sponge is made by the raw material that comprises following weight portion: 30 parts of isocyanates, wherein the ratio of methyl isocyanate and hexamethylene isocyanate is 6:4, 30 parts of polylactic acid glycol, 70 parts of PEG-2000, 15 parts of fluff pulp, 30 parts of superabsorbent WHS 300, 15 parts of chitosan, 90 parts of water, hydrophilic surfactant ( PE6400: 188=1:2) 5 parts, chain extender TMP 2 parts, inorganic filler 300 mesh diatomaceous earth 20 parts, antioxidant IRGASTAB PUR 68 0.3 parts;

[0094] B. Place isocyanate, polyether polyol, polyester polyol, polymer polyol, chain extender, and antioxidant at 80°C for 12 hours to react to obtain a polyol modified prepolymer;

[0095] C. Mix the fluff pulp fiber, chitosan, hydrophilic surfactant, inorganic filler with water to obtain white material, and keep it at 20±2℃;

[0096] D. Heat the prepolymer to 40°C, the...

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Abstract

The invention provides a modified high blood-absorbing polyurethane sponge, a preparation method and use thereof. The polyurethane sponge is made from raw materials comprising the following components: isocyanate, polyol, superabsorbent resin, fluff pulp, cationic polysaccharide, Water, hydrophilic surfactants, chain extenders, inorganic fillers, antioxidants. The polyurethane sponge prepared by the invention has the advantages of strong liquid conductivity, high utilization rate of absorbing foam, strong blood absorption capacity, low blood reverse osmosis rate, low swelling rate after blood sucking, etc., and can maintain high strength after blood sucking, and is suitable for use in Disposable blood-absorbing hygiene products, such as sanitary napkins and medical dressings.

Description

technical field [0001] The invention relates to the field of polyurethane foam material products, in particular to a modified high blood-absorbing polyurethane sponge, a preparation method and its application in the medical and health field. Background technique [0002] With the improvement of people's living standards, people's demand for the use of disposable sanitary products has gradually increased, and higher requirements have been placed on the quality of disposable sanitary products. With the industrialization of acrylic-based superabsorbent resins, superabsorbent disposable hygiene products (including feminine hygiene products, baby diapers, etc.) filled with superabsorbent resins have developed rapidly, but the conventional carriers of superabsorbent resins have many problems, including dispersion If it is not uniform, it is easy to cause problems such as gel blockage and poor comfort after liquid absorption. At the same time, with the diversification of user expe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/66C08G18/48C08G18/42C08G18/62C08G18/64C08G18/32C08G18/12C08K7/26A61L15/26A61L15/42A61L15/60C08G101/00
CPCC08G18/6611C08G18/4081C08G18/4833C08G18/428C08G18/6216C08G18/6484C08G18/3206C08G18/12C08K7/26A61L15/26A61L15/42A61L15/425A61L15/60C08G2101/00C08G18/40C08L75/04
Inventor 周伟琦尹金超杨晓珂韩洋田云
Owner WANHUA CHEM GRP CO LTD
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