Wear-resistant antibacterial degradable polymer composite material and preparation method thereof

A composite material and polymer technology, which is applied in the field of wear-resistant and antibacterial degradable polymer composite materials and its preparation, can solve the problems of difficult degradation of waste, failure to achieve balance, insufficient environmental protection, etc., to achieve improved degradability, Increased elasticity, strength and hardness enhancement effects

Inactive Publication Date: 2021-02-12
汕头市先图新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing polymer materials cannot achieve a balance in the above two characteristics, and because most of the waste of polymer materials are difficul...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0020] A method for preparing a wear-resistant and antibacterial degradable polymer composite material, characterized in that it comprises the following steps:

[0021] (1) ABS material, carbon fiber, ethylene pure fiber, polylactic acid, chitosan, plant fiber, tributyltin chloride, trichlorodiphenyl urea, polyaniline, ultra-high molecular weight wear-resistant agent, Coupling agent, curing agent, compatibilizer;

[0022] (2) Put the raw materials weighed in step (1) into a stirring tank and heat to 170-180° C., stir and mix evenly to obtain a blend, the stirring speed is 350-600r / min, and the stirring time is 20-30min. fully stir;

[0023] (3) Cool down the blend in step (2) to 55-65°C, continue to stir for 10-15 minutes, and then add it to a twin-screw extruder to melt and extrude to pelletize. The extrusion temperature is 350-410°C, and the extrusion rate The temperature is 160-170r / min, the granulation is naturally cooled, and the preparation is completed.

no. 1 example

[0026] A wear-resistant and antibacterial degradable polymer composite material, characterized in that it is composed of the following raw materials in parts by weight: 60 parts of ABS material, 10 parts of carbon fiber, 5 parts of ethylene pure fiber, 10 parts of polylactic acid, shell 20 parts of polysaccharide, 60 parts of sawdust fiber, kombu fiber and flax fiber, 5 parts of tributyltin chloride, 2 parts of trichlorodiphenyl urea, 2 parts of polyaniline, 2 parts of ultra-high molecular weight anti-wear agent, KH560 coupling agent 8 parts, curing agent 5 parts, styrene maleic anhydride graft 2 parts.

[0027] Preferably, the compatibilizer is a maleic anhydride grafted polyolefin or a styrene maleic anhydride graft.

[0028] Preferably, the plant fiber is one or more combinations of wood chip fiber, kombu fiber, flax fiber and kapok fiber.

[0029] Preferably, the coupling agent is one of aluminate coupling agent, γ-aminopropyltriethoxysilane or KH560.

no. 2 example

[0031] A wear-resistant and antibacterial degradable polymer composite material is characterized in that it is composed of the following raw materials in parts by weight: 35 parts of ABS material, 10 parts of carbon fiber, 3 parts of pure vinyl fiber, 5 parts of polylactic acid, shell 20 parts of polysaccharide, 20 parts of flax fiber, 3 parts of tributyltin chloride, 1 part of trichlorodiphenyl urea, 2 parts of polyaniline, 2 parts of ultra-high molecular weight wear-resistant agent, 2 parts of aluminate coupling agent, curing 3 parts of agent, 2 parts of maleic anhydride grafted polyolefin.

[0032] Preferably, the compatibilizer is a maleic anhydride grafted polyolefin or a styrene maleic anhydride graft.

[0033] Preferably, the plant fiber is one or more combinations of wood chip fiber, kombu fiber, flax fiber and kapok fiber.

[0034] Preferably, the coupling agent is one of aluminate coupling agent, γ-aminopropyltriethoxysilane or KH560.

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Abstract

The invention relates to the field of high polymer materials, in particular to a wear-resistant antibacterial degradable high polymer composite material. The composite material is prepared from the following raw materials in parts by weight: an ABS material, carbon fibers, ethylene pure fibers, polylactic acid, chitosan, plant fibers, tributyltin chloride, trichlorobenzeneurea, polyaniline, an ultra-high molecular weight wear-resistant agent, a coupling agent, a curing agent and a compatilizer. The high-molecular composite material has the advantages that the ABS material and the ultra-high molecular weight wear-resistant agent are added into the high-molecular composite material, so that the strength and hardness of the high-molecular composite material are obviously improved, the wear resistance is greatly improved, and meanwhile, the elasticity, toughness and antibacterial persistence of the material are improved by combining other raw material components; the application range of the polymer composite material is greatly widened, and the polymer material is mainly prepared from environment-friendly fiber material components, so that the degradability is greatly improved, and the environmental pollution rate is low.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a wear-resistant, antibacterial and degradable polymer composite material and a preparation method thereof. Background technique [0002] With the rapid development of modern industry, the application of polymer materials is becoming more and more extensive. Many products that people come into contact with in daily life are made of polymer materials. Polymer material products have been closely related to life. Polymer materials have also become polymer materials. Composed of materials. Polymer materials are widely used in various industries such as electrical and electronic industry, aerospace industry, construction industry, medical equipment, pharmaceutical packaging, transportation industry, household appliances, and agriculture. Polymer materials are divided into rubber, fiber, plastic, polymer adhesive, polymer coating and polymer-based composite materials according to the...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08L67/04C08L5/08C08L97/02C08L1/02C08L101/00C08K13/04C08K7/06C08K5/57C08K5/21
CPCC08L1/02C08L55/02C08L97/02C08L2201/06C08L2205/025C08L2205/035C08L2205/08C08L2205/16C08L67/04C08L5/08C08L101/00C08K13/04C08K7/06C08K5/57C08K5/21
Inventor 陈龙
Owner 汕头市先图新材料科技有限公司
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