Preparation method and application of coumarin-modified metal organic framework hybrid material
A metal-organic framework and hybrid material technology, which is applied in the field of preparation of coumarin-modified metal-organic framework hybrid materials, can solve the problems of limiting the application of adsorption desulfurization, uncontrollable pore structure and properties, and desorption of adsorbates. Achieve the effects of adsorption, reduction of pore volume and number of micropores, and developed microporous structure
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0032] Preparation of metal-organic framework HKUST-1: Weigh 2.077g copper nitrate trihydrate and dissolve it in 15mL deionized water, then weigh 1.0g trimesic acid and dissolve it in 15mL ethanol and 15mL N,N-dimethylformamide (DMF ) in the mixed solution. The above two solutions were mixed and reacted at 100°C for 10h. Cool to room temperature, remove the supernatant, add methanol solution to soak for 24 hours, remove the supernatant again, add methane to soak for 24 hours, and dry at room temperature to obtain HKUST-1.
[0033] Preparation of coumarin-modified metal-organic framework hybrid materials: Weigh 0.171g of 7-hydroxycoumarin and dissolve it in 30mL of methanol, then add 0.0648g of sodium methoxide, and reflux at 67°C for 3h to obtain deprotonated 7-hydroxycoumarin Hydroxycoumarin. Then, weigh 0.684g of metal-organic framework HKUST-1 and dissolve it in 3mL of 67°C methanol, continue to add deprotonated 7-hydroxycoumarin, react at 67°C for 8h, filter, wash, and d...
Embodiment 2
[0037]Preparation of metal-organic framework HKUST-1: Weigh 2.077g copper nitrate trihydrate and dissolve it in 15mL deionized water, then weigh 1.0g trimesic acid and dissolve it in 15mL ethanol and 15mL N,N-dimethylformamide (DMF ) in the mixed solution. The above two solutions were mixed and reacted at 100°C for 10h. Cool to room temperature, remove the supernatant, add methanol solution to soak for 24 hours, remove the supernatant again, add methane to soak for 24 hours, and dry at room temperature to obtain HKUST-1.
[0038] Preparation of coumarin-modified metal-organic framework hybrid materials: Weigh 0.342g of 7-hydroxycoumarin and dissolve it in 30mL of methanol, then add 0.0648g of sodium methoxide, and reflux at 67°C for 3h to obtain deprotonated 7- Hydroxycoumarin. Then, weigh 0.684g metal-organic framework HKUST-1 and dissolve it in 3mL of 67°C methanol, then add deprotonated 7-hydroxycoumarin to it, react at 67°C for 8h, filter, wash, and dry. Obtain coumarin...
Embodiment 3
[0042] Preparation of metal-organic framework HKUST-1: Weigh 2.077g copper nitrate trihydrate and dissolve it in 15mL deionized water, then weigh 1.0g trimesic acid and dissolve it in 15mL ethanol and 15mL N,N-dimethylformamide (DMF ) in the mixed solution. The above two solutions were mixed and reacted at 100°C for 10h. Cool to room temperature, remove the supernatant, add methanol solution to soak for 24 hours, remove the supernatant again, add methane to soak for 24 hours, and dry at room temperature to obtain HKUST-1.
[0043] Preparation of coumarin-modified metal-organic framework hybrid materials: Weigh 0.513g of 7-hydroxycoumarin and dissolve it in 30mL of methanol, then add 0.0648g of sodium methoxide, and reflux at 67°C for 3h to obtain deprotonated 7- Hydroxycoumarin. Then, weigh 0.684g metal-organic framework HKUST-1 and dissolve it in 3mL of 67°C methanol, then add deprotonated 7-hydroxycoumarin to it, react at 67°C for 8h, filter, wash, and dry. Obtain coumari...
PUM
| Property | Measurement | Unit |
|---|---|---|
| Equilibrium adsorption | aaaaa | aaaaa |
| Equilibrium adsorption | aaaaa | aaaaa |
| Equilibrium adsorption | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More