Method for preparing high-strength transparent chitin nanofiber gelatin composite membrane by mild method
A nanofiber, high-strength technology, which is applied in the field of preparing high-strength transparent chitin nanofiber gelatin composite film by a gentle method, can solve the problems of poor mechanical properties, limit the wide range control of nanocomposites, and loss of mechanical properties, and achieve high mechanical properties. performance, antimicrobial surface properties, degradation reduction effect
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Embodiment 1
[0032] A method for gently preparing a high-strength transparent chitin nanofiber gelatin composite film, comprising the following process steps:
[0033] (1) Take 100 g of shrimp and crab shells, wash them repeatedly with deionized water, and then crush them with a crusher.
[0034] (2) Stir the crushed shrimp and crab shells in step (1) with 1000ml of 2M hydrochloric acid at room temperature for calcium decarbonation treatment, and wash thoroughly with deionized water after 1 hour until neutral.
[0035] (3) The deproteinized treatment of 1000ml of 15% sodium hydroxide at room temperature for the crushed shrimp and crab shells after the treatment in step (2) was carried out for 2 weeks.
[0036] (4) The deproteinized shrimp and crab shells in step (3) were bleached with 8% hydrogen peroxide for 12 hours, then washed until neutral pH was reached, and freeze-dried with a freeze dryer.
[0037] (5) Take 20 g of the freeze-dried sample in step (4), put it in 500 ml of 35 wt % s...
Embodiment 2
[0045] A method for gently preparing a high-strength transparent chitin nanofiber gelatin composite film, comprising the following process steps:
[0046] (1) Take 200g of shrimp and crab shells, wash them repeatedly with deionized water, and then crush them with a crusher.
[0047] (2) Stir the crushed shrimp and crab shells in step (1) with 1000ml of 2M hydrochloric acid at room temperature for calcium decarbonation treatment, and wash thoroughly with deionized water until neutral after 2 hours.
[0048] (3) The crushed shrimp and crab shells processed in step (2) are deproteinized with 1000ml of 25% sodium hydroxide at room temperature for 1 week.
[0049] (4) The deproteinized shrimp and crab shells in step (3) were bleached with 8% hydrogen peroxide for 12 hours, then washed until neutral pH was reached, and freeze-dried with a freeze dryer.
[0050] (5) Take 20 g of the freeze-dried sample in step (4), place it in 500 ml of 30 wt % sodium hydroxide, heat and stir at 90°...
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