Mud-resistant polycarboxylic acid slump-retaining water reducing agent and preparation method thereof
A polycarboxylic acid, anti-mud type technology, applied in the field of concrete admixtures, can solve the problems of poor pumpability, high mud content, increased water consumption, etc., and achieves the effects of good adaptability and simple synthesis process
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Embodiment 1
[0025] (1) Weigh the raw materials, first mix 170kg of deionized water, 320kg of prenol polyoxyethylene ether, and 20kg of dimethyl diallyl ammonium chloride, stir and heat up to 65°C to dissolve, then add 3kg of hydrogen peroxide , and continue to stir to obtain a mixed solution;
[0026] (2) Mix 30kg hydroxyethyl acrylate, 22.5kg 2-hydroxyethyl methacrylate phosphate, 4kg sodium propylene sulfonate and 15kg deionized water to obtain liquid A; mix 1.0kg ascorbic acid and 0.7kg acryloyl Mix mercaptoethanol and 90kg deionized aqueous solution to obtain liquid B; add liquid A to the mixed liquid for 3 hours and liquid B for 3.5 hours respectively, keep warm for 1 hour after the addition is completed, and then add liquid caustic soda to adjust the pH to 7.0 to obtain mud-resistant polycarboxylic acid Acid slump water reducer.
Embodiment 2
[0028] (1) Weigh the raw materials, first mix 160kg of deionized water, 340kg of prenol polyoxyethylene ether, and 10kg of dimethyl diallyl ammonium chloride, stir and heat up to 60°C to dissolve, then add 4kg of hydrogen peroxide , and continue to stir to obtain a mixed solution;
[0029] (2) Mix 20kg hydroxyethyl acrylate, 30kg 2-hydroxyethyl methacrylate phosphate, 3kg sodium propylene sulfonate and 20kg deionized water to obtain liquid A; mix 0.6kg ascorbic acid and 1.0kg acryloyl mercapto Mix ethanol and 80kg deionized aqueous solution to obtain liquid B; add liquid A to the mixed liquid for 3 hours and liquid B for 3.5 hours respectively, keep warm for 1 hour after the addition is completed, and then add liquid caustic soda to adjust the pH to 6.5 to obtain mud-resistant polycarboxylic acid Slump retaining superplasticizer.
Embodiment 3
[0031] (1) Weigh the raw materials, first mix 180kg of deionized water, 300kg of prenol polyoxyethylene ether, and 10kg of dimethyl diallyl ammonium chloride, stir and heat up to 70°C to dissolve, then add 2kg of hydrogen peroxide , and continue to stir to obtain a mixed solution;
[0032] (2) Mix 40kg hydroxyethyl acrylate, 15kg 2-hydroxyethyl methacrylate phosphate, 5kg sodium propylene sulfonate and 10kg deionized water to obtain liquid A; mix 1.2kg ascorbic acid and 0.4kg acrylmercapto Mix ethanol and 100kg deionized aqueous solution to obtain liquid B; add liquid A to the mixed liquid for 3 hours and liquid B for 3.5 hours respectively, keep it warm for 1 hour after the addition is completed, and then add liquid caustic soda to adjust the pH to 7.5 to obtain mud-resistant polycarboxylic acid Slump retaining superplasticizer.
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