Mud-resistant polycarboxylic acid slump-retaining water reducing agent and preparation method thereof

A polycarboxylic acid, anti-mud type technology, applied in the field of concrete admixtures, can solve the problems of poor pumpability, high mud content, increased water consumption, etc., and achieves the effects of good adaptability and simple synthesis process

Pending Publication Date: 2021-06-15
山东惠邦建材科技股份有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Poor grading of aggregates and high mud content lead to problems such as affecting the workability, strength and durability of concrete when preparing concrete. Conventional methods increase the amount of cementitious materials and concrete sand ratio, resulting in an increase in the amount of concrete cement and water consumption. , poor pumpability and concrete cracking, etc., which affect the quality of the project and the production cost
So now there is a need for a preparation method of mud-resistant polycarboxylate slump-retaining water-reducing agent to solve the problems of increased concrete cement consumption, increased water consumption, poor pumpability, and concrete cracking.

Method used

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  • Mud-resistant polycarboxylic acid slump-retaining water reducing agent and preparation method thereof
  • Mud-resistant polycarboxylic acid slump-retaining water reducing agent and preparation method thereof
  • Mud-resistant polycarboxylic acid slump-retaining water reducing agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) Weigh the raw materials, first mix 170kg of deionized water, 320kg of prenol polyoxyethylene ether, and 20kg of dimethyl diallyl ammonium chloride, stir and heat up to 65°C to dissolve, then add 3kg of hydrogen peroxide , and continue to stir to obtain a mixed solution;

[0026] (2) Mix 30kg hydroxyethyl acrylate, 22.5kg 2-hydroxyethyl methacrylate phosphate, 4kg sodium propylene sulfonate and 15kg deionized water to obtain liquid A; mix 1.0kg ascorbic acid and 0.7kg acryloyl Mix mercaptoethanol and 90kg deionized aqueous solution to obtain liquid B; add liquid A to the mixed liquid for 3 hours and liquid B for 3.5 hours respectively, keep warm for 1 hour after the addition is completed, and then add liquid caustic soda to adjust the pH to 7.0 to obtain mud-resistant polycarboxylic acid Acid slump water reducer.

Embodiment 2

[0028] (1) Weigh the raw materials, first mix 160kg of deionized water, 340kg of prenol polyoxyethylene ether, and 10kg of dimethyl diallyl ammonium chloride, stir and heat up to 60°C to dissolve, then add 4kg of hydrogen peroxide , and continue to stir to obtain a mixed solution;

[0029] (2) Mix 20kg hydroxyethyl acrylate, 30kg 2-hydroxyethyl methacrylate phosphate, 3kg sodium propylene sulfonate and 20kg deionized water to obtain liquid A; mix 0.6kg ascorbic acid and 1.0kg acryloyl mercapto Mix ethanol and 80kg deionized aqueous solution to obtain liquid B; add liquid A to the mixed liquid for 3 hours and liquid B for 3.5 hours respectively, keep warm for 1 hour after the addition is completed, and then add liquid caustic soda to adjust the pH to 6.5 to obtain mud-resistant polycarboxylic acid Slump retaining superplasticizer.

Embodiment 3

[0031] (1) Weigh the raw materials, first mix 180kg of deionized water, 300kg of prenol polyoxyethylene ether, and 10kg of dimethyl diallyl ammonium chloride, stir and heat up to 70°C to dissolve, then add 2kg of hydrogen peroxide , and continue to stir to obtain a mixed solution;

[0032] (2) Mix 40kg hydroxyethyl acrylate, 15kg 2-hydroxyethyl methacrylate phosphate, 5kg sodium propylene sulfonate and 10kg deionized water to obtain liquid A; mix 1.2kg ascorbic acid and 0.4kg acrylmercapto Mix ethanol and 100kg deionized aqueous solution to obtain liquid B; add liquid A to the mixed liquid for 3 hours and liquid B for 3.5 hours respectively, keep it warm for 1 hour after the addition is completed, and then add liquid caustic soda to adjust the pH to 7.5 to obtain mud-resistant polycarboxylic acid Slump retaining superplasticizer.

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Abstract

The invention discloses a mud-resistant polycarboxylic acid slump-retaining water reducing agent, which is prepared from the following components in parts by weight: 300 to 340 parts of isopentenol polyoxyethylene ether, 10 to 30 parts of dimethyl diallyl ammonium chloride, 2 to 4 parts of an initiator, 20 to 40 parts of hydroxyethyl acrylate, 15 to 30 parts of 2-hydroxyethyl methacrylate phosphate, 3 to 5 parts of sodium alpha-allylsulfonate, 0.6 to 1.2 parts of a reducing agent, 0.4 to 1.0 part of a chain transfer agent, and 250 to 300 parts of deionized water. The preparation method comprises the following steps: mixing deionized water, isopentenol polyoxyethylene ether and dimethyl diallyl ammonium chloride, and then adding an initiator to obtain a mixed solution; and respectively dropwise adding a solution A and a solution B, and adding liquid caustic soda to adjust the pH value. Compared with the traditional slump retaining agent, the product provided by the invention has a certain water-reducing rate, does not influence the setting time and mechanical properties of concrete, and has good adaptability under the condition of high clay content; and the synthesis process is simple, and has the advantages of energy conservation and consumption reduction.

Description

technical field [0001] The invention relates to the technical field of concrete admixtures, in particular to a mud-resistant polycarboxylate slump-retaining water reducer and a preparation method thereof. Background technique [0002] In the past 20 years, with the rapid development of domestic infrastructure and the increasing pressure of environmental protection, concrete raw materials, which are bulk materials for infrastructure construction, have been consumed in large quantities, and high-quality raw materials have become less and less. River sand is a bulk building material in the building materials industry. With the strengthening of environmental protection and the continuous development of infrastructure, river mining is basically restricted, resulting in the gradual development of fine aggregate in the concrete industry in the direction of machine-made sand. The most significant difference between machine-made sand and natural sand is that the particle shape and pa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/06C08F226/02C08F230/02C08F220/20C08F228/02C04B24/16C04B103/30
CPCC08F283/065C04B24/165C04B2103/30
Inventor 孙希刚李强陶正良张金镯隋善耘
Owner 山东惠邦建材科技股份有限公司
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