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A kind of high-strength antibacterial polyethylene film and preparation method thereof

A technology of polyethylene film and polyethylene microporous film, which is applied in the field of water treatment, can solve the problems of reduced service life of the film, lack of antibacterial properties, and decreased mechanical capacity, and achieve the goals of inhibiting agglomeration, increasing antibacterial ability, and reducing interfacial energy Effect

Active Publication Date: 2022-04-22
JIANGSU HORIZON NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the strong hydrophobicity of polyethylene microporous membranes, long-term use in water treatment can easily lead to a decrease in mechanical capacity; there is a problem of protein pollution and adhesion causing pore blockage, resulting in membrane damage and reducing the service life of the membrane.
In addition, when polyethylene microporous membranes are used for water treatment, they are generally used as base membranes in combination with other hydrophilic membrane layers, which have the disadvantages of poor bonding strength and do not have antibacterial properties.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Step 1: Preparation of ethylene-vinyl alcohol copolymer film: dissolve polyhexamethyleneguanidine propionate in aqueous solution, add metal nanoparticles, set the temperature at 20°C, stir for 2.5 hours, filter, and dry at low temperature to obtain polyhexamethylene guanidine propionate Hexamethyleneguanidine / metal nanoparticles, for later use; add ethylene-vinyl alcohol copolymer to dimethyl sulfoxide, set the temperature at 65°C and stir for 2 hours; add polyvinylpyrrolidone, polyhexamethylene propionate in sequence Guanidine / metal nanoparticles, set the temperature at 45°C and sonicate for 1.5 hours to obtain a casting film solution; scrape the film on a glass plate to obtain the initial film; quickly transfer it to distilled water, set the temperature at 25°C and soak for 3 days to obtain ethylene - vinyl alcohol copolymer film;

[0035]Step 2: Preparation of polyethylene film: dry and grind the pomegranate peel into powder, mix the powder with ethanol at a mass rat...

Embodiment 2

[0038] Step 1: Preparation of ethylene-vinyl alcohol copolymer film: dissolve polyhexamethylene guanidine propionate in an aqueous solution, add metal nanoparticles, set the temperature at 18°C, stir for 2 hours, filter, and dry at low temperature to obtain polyhexamethylene guanidine propionate Hexamethyleneguanidine / metal nanoparticles, for later use; add ethylene-vinyl alcohol copolymer to dimethyl sulfoxide, set the temperature at 60°C and stir for 1 hour; add polyvinylpyrrolidone, polyhexamethylene propionate in sequence Guanidine / metal nanoparticles, set the temperature at 40°C and sonicate for 1 hour to obtain a casting film solution; scrape it on a glass plate to obtain a primary film; quickly transfer it to distilled water, set the temperature at 20°C and soak for 2 days to obtain ethylene - vinyl alcohol copolymer film;

[0039] Step 2: Preparation of polyethylene film: Dry and grind the pomegranate peel into powder, mix the powder with ethanol at a mass ratio of 1:1...

Embodiment 3

[0042] Step 1: Preparation of ethylene-vinyl alcohol copolymer film: dissolve polyhexamethyleneguanidine propionate in aqueous solution, add metal nanoparticles, set the temperature at 22°C, stir for 3 hours, filter, and dry at low temperature to obtain polyhexamethylene guanidine propionate Hexamethyleneguanidine / metal nanoparticles, for later use; add ethylene-vinyl alcohol copolymer to dimethyl sulfoxide, set the temperature at 70°C and stir for 3 hours; add polyvinylpyrrolidone, polyhexamethylene propionate in sequence Guanidine / metal nanoparticles, set the temperature at 50°C and sonicate for 2 hours to obtain a casting film solution; scrape the film on a glass plate to obtain the initial film; quickly transfer it to distilled water, set the temperature at 30°C and soak for 4 days to obtain ethylene - vinyl alcohol copolymer film;

[0043] Step 2: Preparation of polyethylene film: dry and grind the pomegranate peel into powder, mix the powder with ethanol at a mass ratio ...

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PUM

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Abstract

The invention discloses a high-strength antibacterial polyethylene film and a preparation method thereof. The polyethylene film is a film formed by chemically bonding the polyethylene microporous film and the ethylene-vinyl alcohol copolymerized film with the polyethylene microporous film as the base and the ethylene-vinyl alcohol copolymerized film as the surface layer. Beneficial effects: Add pomegranate extract to increase bond strength and antibacterial properties; use water-induced reverse phase method to prepare ethylene-vinyl alcohol copolymer film as the surface layer, and utilize the synergistic effect between polyhexamethylene guanidine propionate and PVP, Accelerate the precipitation of PVP, accelerate the formation of pores, and reduce time costs; use the acidic groups in polyhexamethyleneguanidine propionate to make polyhexamethyleneguanidine propionate / metal nanoparticles move spontaneously to the membrane surface to form a hydration layer , Antibacterial and antifouling; use polyhexamethylene guanidine propionate to chelate metal nanoparticles, attach to the surface of metal nanoparticles, inhibit the agglomeration of metal nanoparticles, and increase uniform dispersion.

Description

technical field [0001] The invention relates to the technical field of water treatment, in particular to a high-strength antibacterial polyethylene film and a preparation method thereof. Background technique [0002] In recent years, the pollution of water bodies has become more and more severe, and the reuse of water bodies has become one of the key research topics. Among them, membrane separation technology is one of the effective methods for wastewater treatment and high-quality water purification. Traditional water treatment membranes are dominated by polysulfide porous layers, but the production process is relatively complicated, and my country is still in the exploratory stage. It is difficult to produce high-quality polysulfide through independent research and development. In recent years, the extensive research on the preparation of polyethylene membranes has led to the rapid development of polyethylene microporous membrane technology. Moreover, the membrane has go...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D71/26B01D71/82B01D69/02B01D67/00
CPCB01D71/26B01D71/82B01D69/02B01D67/0006B01D67/0011B01D67/0013B01D2325/48
Inventor 翁星星刘涛涛陈朝晖
Owner JIANGSU HORIZON NEW ENERGY TECH CO LTD
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