A kind of high-strength antibacterial polyethylene film and preparation method thereof
A technology of polyethylene film and polyethylene microporous film, which is applied in the field of water treatment, can solve the problems of reduced service life of the film, lack of antibacterial properties, and decreased mechanical capacity, and achieve the goals of inhibiting agglomeration, increasing antibacterial ability, and reducing interfacial energy Effect
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Embodiment 1
[0034] Step 1: Preparation of ethylene-vinyl alcohol copolymer film: dissolve polyhexamethyleneguanidine propionate in aqueous solution, add metal nanoparticles, set the temperature at 20°C, stir for 2.5 hours, filter, and dry at low temperature to obtain polyhexamethylene guanidine propionate Hexamethyleneguanidine / metal nanoparticles, for later use; add ethylene-vinyl alcohol copolymer to dimethyl sulfoxide, set the temperature at 65°C and stir for 2 hours; add polyvinylpyrrolidone, polyhexamethylene propionate in sequence Guanidine / metal nanoparticles, set the temperature at 45°C and sonicate for 1.5 hours to obtain a casting film solution; scrape the film on a glass plate to obtain the initial film; quickly transfer it to distilled water, set the temperature at 25°C and soak for 3 days to obtain ethylene - vinyl alcohol copolymer film;
[0035]Step 2: Preparation of polyethylene film: dry and grind the pomegranate peel into powder, mix the powder with ethanol at a mass rat...
Embodiment 2
[0038] Step 1: Preparation of ethylene-vinyl alcohol copolymer film: dissolve polyhexamethylene guanidine propionate in an aqueous solution, add metal nanoparticles, set the temperature at 18°C, stir for 2 hours, filter, and dry at low temperature to obtain polyhexamethylene guanidine propionate Hexamethyleneguanidine / metal nanoparticles, for later use; add ethylene-vinyl alcohol copolymer to dimethyl sulfoxide, set the temperature at 60°C and stir for 1 hour; add polyvinylpyrrolidone, polyhexamethylene propionate in sequence Guanidine / metal nanoparticles, set the temperature at 40°C and sonicate for 1 hour to obtain a casting film solution; scrape it on a glass plate to obtain a primary film; quickly transfer it to distilled water, set the temperature at 20°C and soak for 2 days to obtain ethylene - vinyl alcohol copolymer film;
[0039] Step 2: Preparation of polyethylene film: Dry and grind the pomegranate peel into powder, mix the powder with ethanol at a mass ratio of 1:1...
Embodiment 3
[0042] Step 1: Preparation of ethylene-vinyl alcohol copolymer film: dissolve polyhexamethyleneguanidine propionate in aqueous solution, add metal nanoparticles, set the temperature at 22°C, stir for 3 hours, filter, and dry at low temperature to obtain polyhexamethylene guanidine propionate Hexamethyleneguanidine / metal nanoparticles, for later use; add ethylene-vinyl alcohol copolymer to dimethyl sulfoxide, set the temperature at 70°C and stir for 3 hours; add polyvinylpyrrolidone, polyhexamethylene propionate in sequence Guanidine / metal nanoparticles, set the temperature at 50°C and sonicate for 2 hours to obtain a casting film solution; scrape the film on a glass plate to obtain the initial film; quickly transfer it to distilled water, set the temperature at 30°C and soak for 4 days to obtain ethylene - vinyl alcohol copolymer film;
[0043] Step 2: Preparation of polyethylene film: dry and grind the pomegranate peel into powder, mix the powder with ethanol at a mass ratio ...
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