High-temperature-resistant semi-coke dust suppressant and preparation method thereof

A high-temperature-resistant, dust-suppressant technology, applied to chemical instruments and methods, and other chemical processes, can solve the problems of reducing the amount of addition, failing to achieve heat resistance, and reducing dust suppression effects, etc., to achieve strong adhesion and cost-effectiveness. Good film performance and excellent dust suppression effect

Pending Publication Date: 2021-11-23
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this invention, by preparing and adding composite gelling agent and modified straw starch, and rationally adjusting the addition ratio of each component, the addition amount of each component is reduced, achieving a good dust suppression effect and reducing the cost of raw materials; but the dust suppression The modification method of modified straw starch, the raw material of the agent, is pregelatinized starch. Although the heat resistance of pregelatinized starch is improved compared with ordinary starch, it cannot reach the heat resistance of 100 ° C. During the preparation process, in order to ensure the performance parameters such as the grindability of the semi-coke, some manufacturers even dry the semi-coke in an environment of 120°C. Dust suppressants that are not resistant to high temperatures will fail in this environment, and coal dust is difficult to Second, the dust suppressant does not have the characteristics of high bonding strength and toughness, and the semi-coke will vibrate greatly during belt transportation, so the dust suppressant with weaker strength will have a phenomenon of film damage, which will lead to dust suppression. Decreased effect

Method used

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  • High-temperature-resistant semi-coke dust suppressant and preparation method thereof
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  • High-temperature-resistant semi-coke dust suppressant and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031] The high temperature-resistant blue carbon dust suppressant, its preparation raw materials are: carboxymethyl starch 30g; sodium lauryl sulfate 1g; acrylic resin 50g; potassium persulfate 1g; borax 3g; water 15g.

[0032] The preparation method of the dust suppressant is as follows: (1) Add acrylic resin and water into a four-necked bottle equipped with a stirrer, a thermometer, a reflux device, and a heater, and dissolve it completely under a stirring environment of 50r / min. (2) adjust the temperature to 30°C, and add sodium lauryl sulfate to react for 30 minutes under a stirring environment of 200r / min; (3) add potassium persulfate to react for 30 minutes, and then add carboxymethyl starch to the Carry out constant temperature graft copolymerization reaction in the solution for 30 minutes, cool to room temperature; (4) Add 2% borax solution to carry out crosslinking reaction for 30 minutes, after the reaction is completed, the high temperature resistant blue carbon dus...

Embodiment 2

[0034] The high temperature-resistant blue carbon dust suppressant, its preparation raw materials are: 30g of hydroxypropyl starch; 1g of sodium lauryl sulfate; 50g of acrylic resin; 1g of potassium persulfate; 3g of borax; 15g of water.

[0035] The preparation method of the dust suppressant is as follows: (1) Add acrylic resin and part of water into a four-necked bottle equipped with agitator, thermometer, reflux device and heating, and make it completely Dissolve; (2) adjust the temperature to 40°C, and add sodium lauryl sulfate to react for 30 minutes under a stirring environment of 150 r / min; (3) add potassium persulfate to react for 30 minutes, and then add hydroxypropyl starch in three times on average Carry out constant temperature grafting copolymerization reaction in the solution for 30 minutes, cool to room temperature; (4) Add 2% borax solution to carry out crosslinking reaction for 30 minutes, after the reaction is completed, the high temperature resistant semi-car...

Embodiment 3

[0037] High temperature resistant blue charcoal dust suppressant, its preparation raw materials are: 30g of hydroxypropyl carboxymethyl starch; 1g of sodium dodecylbenzenesulfonate; 50g of acrylic resin; 1g of potassium persulfate; 3g of borax; 15g of water.

[0038]The preparation method of the dust suppressant is as follows: (1) Add acrylic resin and water into a four-necked bottle equipped with a stirrer, a thermometer, a reflux device, and a heater, and dissolve it completely under a stirring environment of 120r / min. (2) Adjust the temperature to 55°C, and add sodium dodecylbenzenesulfonate to react for 30 minutes under a stirring environment of 250r / min; (3) Add potassium persulfate to react for 30 minutes, and then add hydroxypropyl carboxymethyl starch Add to the solution three times on average for constant temperature graft copolymerization reaction for 30 minutes, and cool to room temperature; (4) add borax solution with a concentration of 2% for crosslinking reaction ...

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PUM

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Abstract

The invention provides a high-temperature-resistant semi-coke dust suppressant and a preparation method thereof. The dust suppressant is prepared from the following components in percentage by mass: 30-60% of modified starch, 1-5% of an emulsifier, 20-50% of a film-forming agent, 1-3% of an initiator, 1-3% of borax and the balance of water, wherein the modified starch is etherified starch with high substitution degree, and is at least one of hydroxypropyl starch, carboxymethyl starch and hydroxypropyl carboxymethyl starch. The preparation method comprises the following steps: heating and dissolving a film-forming agent and water under a stirring condition; conducting cooling, adding an emulsifier, and conducting stirring for reaction; then adding an initiator for reaction, then adding modified starch for three times for constant-temperature graft copolymerization reaction, and then conducting cooling to room temperature; and finally, adding a borax solution to carry out cross-linking reaction. The prepared high-temperature semi-coke dust suppressant can resist the high temperature of 120 DEG C, and is high in adhesiveness, good in film-forming property and excellent in dust suppression effect; and the dust suppressant does not contain environmental pollutants such as heavy metals and toxic gases, is free of environmental pollution and easy to degrade, and belongs to an environment-friendly product.

Description

technical field [0001] The invention belongs to the technical field of dust suppressants, and in particular relates to a high-temperature-resistant blue carbon dust suppressant and a preparation method thereof Background technique [0002] During the transportation and storage of coal, a large number of coal particles will be scattered and coal dust will be flying. A large amount of coal dust exists in the environment, which will cause extremely serious pollution to soil, water resources, atmosphere and other aspects. For example, when coal dust enters the soil and the trace elements in the soil exceed its critical value, the soil will export pollutants to the environment, polluting other environments, and the composition, structure and function of the soil will change, which will eventually lead to Soil resources are depleted and destroyed. The existence of coal dust will also endanger human health. For example, people who live in a high-dust environment for a long time w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/22C08G81/02
CPCC09K3/22C08G81/02
Inventor 伍林周义来胡雅刘盈杨小于廖致远张保国陈奡
Owner WUHAN UNIV OF SCI & TECH
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