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Metal corrugated pipe surface treatment acid solution

A metal bellows and surface treatment technology, applied in the field of bellows processing, can solve the problems of toxicity, irritation and corrosion, over-corrosion of scale, weak corrosion, etc., and achieve the effect of improving the quality of pickling and avoiding pitting corrosion

Pending Publication Date: 2021-12-10
浙江交工新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the acid solutions for surface treatment of metal bellows mainly include the following types: 1) hydrochloric acid-sulfuric acid solution, the main components of which are sulfuric acid and nitric acid, both of which are strong acids, which corrode metal bellows very quickly and are easy to If the oxide scale has been corroded, it is difficult to guarantee the pickling quality of the metal bellows; 2) Nitric acid-hydrofluoric acid solution, this type of pickling solution has a strong ability to dissolve the oxide scale and a certain loosening ability, and has a strong impact on the substrate. The corrosiveness of the metal bellows is relatively weak, and it is easy to control the erosion degree of the metal bellows, and the surface residue after pickling is less, but the hydrofluoric acid is volatile and has strong toxicity, irritation and corrosion to the human body. Conducive to safe and stable production
[0004] Therefore, the existing acid solution has the problems of difficult to control the erosion degree and unsafe acidic medium. It is urgent to optimize the formula of the acidic solution to reduce the damage of the acidic medium to the human body while taking into account the quality of pickling.

Method used

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  • Metal corrugated pipe surface treatment acid solution

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Effect test

Embodiment 1

[0021] Embodiment 1: It is a metal bellows surface treatment acid solution disclosed by the present invention, which consists of the following raw materials in parts by weight: 20 parts of hydrochloric acid, 15 parts of nitric acid, 0.17 parts of polyethylene glycol, 0.50 parts of peroxide, and regeneration agent 0.18 parts, 1.00 parts of complexing agent, 0.10 parts of imidazoline corrosion inhibitor, 3.00 parts of multifunctional additives, add water to 100 parts.

[0022] Specifically, the peroxide is composed of the following raw materials by weight, 0.15 parts of carbamide peroxide, 0.10 parts of liquid hydrogen peroxide, and 0.25 parts of solid hydrogen peroxide; the regenerant is composed of the following raw materials by weight, 0.04 parts of hydroxylamine hydrochloride , 0.05 parts of potassium chloride, 0.04 parts of isosorbide dinitrate, and 0.05 parts of ammonium nitrate; the complexing agent is citric acid / D-tartaric acid; the imidazoline corrosion inhibitor is cyc...

Embodiment 2

[0029] Embodiment 2: It is an acid solution for the surface treatment of metal bellows disclosed in the present invention. The difference from Embodiment 1 is that the parts by weight of the components in the raw materials are shown in Table 1. In addition, the complexing agent is aminoacetic acid / mercaptoacetic acid; the imidazoline corrosion inhibitor is 2-methylimidazoline corrosion inhibitor; the cosolvent is diethanolamine; the water-soluble rust inhibitor is water-soluble rust inhibitor L190.

Embodiment 3

[0030] Embodiment 3: an acid solution for the surface treatment of metal bellows disclosed in the present invention. The difference from Embodiment 1 is that the parts by weight of each component in the raw materials are shown in Table 1. In addition, the imidazoline corrosion inhibitor is bis-imidazoline quaternary ammonium salt corrosion inhibitor; the co-solvent is ethanol; the water-soluble rust inhibitor is water-soluble rust inhibitor L190.

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Abstract

The invention relates-a metal corrugated pipe surface treatment acid solution. The metal corrugated pipe surface treatment acid solution is prepared from, by weight, 10-25 parts of hydrochloric acid, 10-25 parts of nitric acid, 0.10-0.20 part of polyethylene glycol, 0.30-0.64 part of peroxide, 0.10-0.20 part of regenerant, 0.80-1.20 parts of complexing agents, 0.09-0.13 part of imidazoline corrosion inhibitor, 2.00-4.00 parts of multifunctional additives and the balance water, totaling 100 parts. An acid pickling system is established through the hydrochloric acid, the nitric acid, the regenerant and the complexing agents, the problem that an existing acid pickling solution containing hydrofluoric acid is unsafe is directly solved, the corrosion amount of the acid solution is adjusted with assistance of peroxide, the imidazoline corrosion inhibitor and the multifunctional additives, and the corrosion degree of oxide skin of a workpiece can be controllable. The corrosion amount can be controlled within a certain range, and the purpose of improving the acid pickling quality is achieved.

Description

technical field [0001] The invention relates to the technical field of bellows processing, in particular to an acid solution for surface treatment of metal bellows. Background technique [0002] Metal bellows refers to metal pipes made of galvanized or non-galvanized low-carbon steel strips with spiral folded joints and used to reserve holes in post-tensioned prestressed concrete structural members. Traditional metal bellows are poor in stain resistance and corrosion resistance, and surface treatment is now mainly used to improve their surface properties. [0003] At present, the acid solutions for surface treatment of metal bellows mainly include the following types: 1) hydrochloric acid-sulfuric acid solution, the main components of which are sulfuric acid and nitric acid, both of which are strong acids, which corrode metal bellows very quickly and are easy to If the oxide scale has been corroded, it is difficult to guarantee the pickling quality of the metal bellows; 2) ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23G1/06C23G1/08
CPCC23G1/063C23G1/085
Inventor 夏新华宁英杰杨湘刚
Owner 浙江交工新材料有限公司