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Polypropylene multilayer composite film for milk storage bag and preparation method thereof

A multi-layer composite film, polypropylene technology, used in chemical instruments and methods, applications, household appliances, etc., can solve problems such as food safety hazards, achieve less easily degradable components, good rigidity and smoothness, and molecular weight ratio. small effect

Active Publication Date: 2022-02-01
RENOLIT HENGXUN PACKAGING TECH BEIJING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005]However, although the above measures have improved the heat resistance and radiation resistance of the film to a certain extent, it may reduce the taste of milk storage bags; A variety of small molecule additives are added to the post-membrane material. These small molecules are easy to migrate into breast milk during long-term contact, which brings food safety hazards on the other hand.

Method used

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  • Polypropylene multilayer composite film for milk storage bag and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] This embodiment prepares a kind of multi-layer co-extruded polypropylene film, and uses it to make milk storage bag; Including the following process:

[0027]Adopt melt index to be 2.5g / 10min, the homopolypropylene that the molecular weight distribution dispersion coefficient is 4 as outer layer raw material; Adopt the ethylene propylene copolymer (molecular weight distribution dispersion coefficient is 2.8) that the ethylene content of 20wt.% is 7wt.%. 35wt.% of ethylene-propylene copolymer with ethylene content of 2wt.% (molecular weight distribution dispersion coefficient is 3.6), 45wt.% metallocene catalyzed ethylene-octene copolymer (molecular weight distribution dispersion coefficient is 1.6) blended, the mixture melted The index is 4.3g / 10min, as the middle layer raw material; use no antioxidant, melting point 142 ℃, melt index is 4, friction coefficient is 0.4, molecular weight distribution dispersion coefficient is 1.9 random copolymerized polypropylene as the i...

Embodiment 2

[0035] This embodiment prepares a kind of multi-layer co-extruded polypropylene film, and uses it to make milk storage bag; Including the following process:

[0036] Homopolypropylene with a melt index of 4g / 10min and a molecular weight distribution dispersion coefficient of 1.4 is used as the outer layer raw material; 30wt.% ethylene-propylene copolymer with a ethylene content of 7wt.% (molecular weight distribution dispersion coefficient is 1.8), 40wt.% % Ethylene-propylene copolymer with ethylene content of 3wt.% (molecular weight distribution dispersion coefficient is 2.6), 30wt.% metallocene catalyzed ethylene-octene copolymer (molecular weight distribution dispersion coefficient is 2.3) blending, the melt index of the mixture is 3.4g / 10min, as the middle layer raw material; using random copolymerized polypropylene without antioxidant, melting point 142°C, melting index 5, friction coefficient 0.4, molecular weight distribution dispersion coefficient 2.6 as the inner laye...

Embodiment 3

[0048] This embodiment adopts the polypropylene multilayer film prepared in Example 1, and carries out solvent-free compounding with Adcote 811A-EA+CATALYST 9L10 of Dow's aliphatic polyurethane glue for PET film of 12 microns. After curing for 72 hours, it is combined with PP zipper The milk storage bags were prepared on the bag machine, and related tests were carried out. The specific data are shown in Table 1.

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Abstract

The invention discloses a polypropylene multilayer composite film for a milk storage bag and a preparation method thereof. The polypropylene multilayer composite film at least comprises an outer layer, a middle layer and an inner layer, wherein the outer layer is made of homo-polypropylene; the middle layer is formed by blending an ethylene-propylene copolymer with the ethylene content of more than 5wt.%, an ethylene-propylene copolymer with the ethylene content of less than 5wt.% and a metallocene catalyzed ethylene-octylefin copolymer; the inner layer is made of polypropylene random copolymer. The temperature in the preparation process is lower than 180 DEG C, and no antioxidant, light stabilizer, nucleating agent or other micromolecular additives are added in the whole process. The milk storage bag prepared from the polypropylene multilayer composite film has no peculiar smell after being unsealed, has no peculiar smell after irradiation sterilization, has good flexibility and low temperature resistance, does not leak liquid or break the bag under a freezing condition after containing breast milk, and can be widely applied to packaging of liquid food and medicines needing to be refrigerated and frozen.

Description

technical field [0001] The invention relates to the field of plastic packaging, in particular to a polypropylene multilayer composite film for milk storage bags and a preparation method thereof. Background technique [0002] Plastic packaging and plastic packaging products are taking an increasing share in the market, especially composite plastic flexible packaging, which has been widely used in food, medicine, chemical and other fields. These products have brought great convenience to people's lives . With the improvement of people's material and living standards, people pay more and more attention to the quality of packaging materials, especially when it comes to food safety, medical hygiene and other aspects. [0003] At present, there is a type of plastic packaging on the market called milk storage bags, also known as breast milk preservation bags. Breast milk bag is a plastic product used for food packaging, mainly used to store breast milk. Mothers can express milk ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/32B32B27/08B32B27/36B32B7/12B65D65/40B29D7/01
CPCB32B27/32B32B27/327B32B27/08B32B27/36B32B7/12B65D65/40B29D7/01B32B2439/70B32B2439/80B32B2307/558
Inventor 王婧杨萌萌王璧杨得庆
Owner RENOLIT HENGXUN PACKAGING TECH BEIJING CO LTD