Polypropylene color master batch suitable for high-magnification foaming process and preparation method of polypropylene color master batch
A polypropylene, high-rate technology, applied in the field of foamed plastics, can solve the problems of poor thermal performance, narrow foaming temperature range, poor foaming performance of polypropylene materials, etc.
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Embodiment 1
[0051] This embodiment is a preparation method of modified glass fiber, comprising the following steps:
[0052] A1: Mix 10mL of hydrogen peroxide solution with a volume fraction of 30%, 10mL of ammonia water with a mass fraction of 15%, and 80mL of deionized water to obtain a mixed solution. Add 30g of glass fiber and the mixed solution to a container equipped with a stirrer and a thermometer In a three-neck flask, the temperature was 20°C and the stirring rate was 250r / min, and stirred for 4h, then vacuum filtered, and the filter cake was washed with distilled water until the pH was 7, and then placed in a vacuum drying oven. Dry at 100°C for 3 hours to obtain pretreated glass fiber;
[0053] A2: Add 10g of pretreated glass fiber and 80mL of hydrogen peroxide solution with a volume fraction of 30% to a three-necked flask equipped with a stirrer, a thermometer and a constant pressure dropping funnel. Add acetic acid drop by drop while stirring under the condition of min, con...
Embodiment 2
[0055] This embodiment is a preparation method of modified glass fiber, comprising the following steps:
[0056] A1: Mix 10mL of hydrogen peroxide solution with a volume fraction of 30%, 10mL of ammonia water with a mass fraction of 20%, and 80mL of deionized water to obtain a mixed solution. Add 30g of glass fiber and the mixed solution to a container equipped with a stirrer and a thermometer. In a three-neck flask, the temperature was 25°C and the stirring rate was 350r / min, and stirred for 5h, then vacuum filtered, and the filter cake was washed with distilled water until the pH was 7, and then placed in a vacuum drying oven. Dry at 110°C for 4 hours to obtain pretreated glass fiber;
[0057] A2: Add 10g of pretreated glass fiber and 100mL of hydrogen peroxide solution with a volume fraction of 30% to a three-necked flask equipped with a stirrer, a thermometer and a constant pressure dropping funnel. Add acetic acid drop by drop while stirring under the condition of min, c...
Embodiment 3
[0059] The present embodiment is a kind of preparation method of reinforcing agent, comprises the following steps:
[0060] B1: Add 0.2mol of acrylamide and 120mL of dichloromethane into a three-necked flask equipped with a stirrer, a thermometer, an air guide tube and a constant pressure dropping funnel, and pass in nitrogen protection at a temperature of -5°C with a stirring rate of 200r Stir for 10 min under the condition of stirring / min, then add 100 mL of phenylphosphonic dichloride dropwise while stirring according to 10 mmol: 10 mL of the phenylphosphonic dichloride solution formed by dissolving in dichloromethane, and control the rate of addition to 1 drop / s. After the dropwise addition, the temperature was raised to 50°C and the reaction was continued for 10 h with stirring. After the reaction, the reaction product was rotary evaporated to dryness, and the evaporated product was recrystallized with chloroform to obtain intermediate 1;
[0061] B2: Add 10mmol p-nitrobe...
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