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Polypropylene color master batch suitable for high-magnification foaming process and preparation method of polypropylene color master batch

A polypropylene, high-rate technology, applied in the field of foamed plastics, can solve the problems of poor thermal performance, narrow foaming temperature range, poor foaming performance of polypropylene materials, etc.

Active Publication Date: 2022-05-27
广东九彩新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to overcome the above-mentioned technical problems, the object of the present invention is to provide a polypropylene color masterbatch suitable for high-magnification foaming process and its preparation method: by combining polypropylene, polyethylene, dispersant, modified glass fiber and The reinforcing agent is added to the mixer and mixed evenly to obtain a compound, which is added to a twin-screw extruder to fully melt and mix the compound, and then add a foaming agent to continue melting and mixing to obtain a foam. It is granulated at the template of the underwater granulator, and the cut granules are dried, and then classified and packaged according to the particle size to obtain the polypropylene color masterbatch suitable for the high-magnification foaming process, which solves the problem of the existing polypropylene material The foaming temperature range is too narrow and the thermal properties are not good, resulting in poor foaming performance of polypropylene materials. It is difficult to obtain polypropylene material foam through conventional foaming treatment of polypropylene materials

Method used

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  • Polypropylene color master batch suitable for high-magnification foaming process and preparation method of polypropylene color master batch
  • Polypropylene color master batch suitable for high-magnification foaming process and preparation method of polypropylene color master batch

Examples

Experimental program
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Effect test

Embodiment 1

[0051] This embodiment is a preparation method of modified glass fiber, comprising the following steps:

[0052] A1: Mix 10mL of hydrogen peroxide solution with a volume fraction of 30%, 10mL of ammonia water with a mass fraction of 15%, and 80mL of deionized water to obtain a mixed solution. Add 30g of glass fiber and the mixed solution to a container equipped with a stirrer and a thermometer In a three-neck flask, the temperature was 20°C and the stirring rate was 250r / min, and stirred for 4h, then vacuum filtered, and the filter cake was washed with distilled water until the pH was 7, and then placed in a vacuum drying oven. Dry at 100°C for 3 hours to obtain pretreated glass fiber;

[0053] A2: Add 10g of pretreated glass fiber and 80mL of hydrogen peroxide solution with a volume fraction of 30% to a three-necked flask equipped with a stirrer, a thermometer and a constant pressure dropping funnel. Add acetic acid drop by drop while stirring under the condition of min, con...

Embodiment 2

[0055] This embodiment is a preparation method of modified glass fiber, comprising the following steps:

[0056] A1: Mix 10mL of hydrogen peroxide solution with a volume fraction of 30%, 10mL of ammonia water with a mass fraction of 20%, and 80mL of deionized water to obtain a mixed solution. Add 30g of glass fiber and the mixed solution to a container equipped with a stirrer and a thermometer. In a three-neck flask, the temperature was 25°C and the stirring rate was 350r / min, and stirred for 5h, then vacuum filtered, and the filter cake was washed with distilled water until the pH was 7, and then placed in a vacuum drying oven. Dry at 110°C for 4 hours to obtain pretreated glass fiber;

[0057] A2: Add 10g of pretreated glass fiber and 100mL of hydrogen peroxide solution with a volume fraction of 30% to a three-necked flask equipped with a stirrer, a thermometer and a constant pressure dropping funnel. Add acetic acid drop by drop while stirring under the condition of min, c...

Embodiment 3

[0059] The present embodiment is a kind of preparation method of reinforcing agent, comprises the following steps:

[0060] B1: Add 0.2mol of acrylamide and 120mL of dichloromethane into a three-necked flask equipped with a stirrer, a thermometer, an air guide tube and a constant pressure dropping funnel, and pass in nitrogen protection at a temperature of -5°C with a stirring rate of 200r Stir for 10 min under the condition of stirring / min, then add 100 mL of phenylphosphonic dichloride dropwise while stirring according to 10 mmol: 10 mL of the phenylphosphonic dichloride solution formed by dissolving in dichloromethane, and control the rate of addition to 1 drop / s. After the dropwise addition, the temperature was raised to 50°C and the reaction was continued for 10 h with stirring. After the reaction, the reaction product was rotary evaporated to dryness, and the evaporated product was recrystallized with chloroform to obtain intermediate 1;

[0061] B2: Add 10mmol p-nitrobe...

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Abstract

The invention relates to the field of foamed plastic, and aims to solve the problems that the foaming performance of the polypropylene material is poor due to the fact that the existing polypropylene material is too narrow in foaming temperature interval and poor in thermal performance, and polypropylene material foam is difficult to obtain by performing conventional foaming treatment on the polypropylene material. In particular to a polypropylene color master batch suitable for a high-magnification foaming process and a preparation method of the polypropylene color master batch, modified glass fibers in the polypropylene color master batch are obtained by modifying glass fibers, the glass fibers have the advantages of high heat resistance and high mechanical strength, and by adding the modified glass fibers, the heat stability of foamed polypropylene can be improved; meanwhile, the mechanical property of the foamed polypropylene can be improved, so that the application range of the foamed polypropylene is widened, the thermal stability and flame retardance of the foamed polypropylene can be greatly improved by adding the reinforcing agent, the foaming temperature interval of the foamed polypropylene is expanded, and the foaming property of the foamed polypropylene is further improved.

Description

technical field [0001] The invention relates to the field of foam plastics, in particular to a polypropylene color masterbatch suitable for a high-magnification foaming process and a preparation method thereof. Background technique [0002] Foam plastic has the advantages of light weight, heat insulation, cushioning, insulation, anti-corrosion and low price. The main varieties of foam plastic include polystyrene, polyurethane and polyolefin, which are widely used in all aspects of production and life. In recent years, with the enhancement of people's awareness of environmental protection, the polyurethane foam will produce toxic isocyanate residues during the foaming process, the product waste is difficult to dispose of, and the disadvantages of burning and releasing harmful gases have gradually attracted people's attention. As one of the polyolefin foam plastics Compared with polyvinyl chloride and polystyrene, the expanded polypropylene material has better tensile properti...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L23/06C08K9/02C08K7/14C08K9/06C08K5/527C08J3/22C08J9/10C07F9/6574
CPCC08J3/226C08J9/103C08J9/102C07F9/65746C08J2423/12C08J2423/06C08J2203/04C08K9/02C08K7/14C08K9/06C08K5/527
Inventor 李刚林文丹曹畅崔永哲方珂琦
Owner 广东九彩新材料有限公司
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