Preparation process of water-based fluorine-modified polyester anti-oxidation automobile chassis coating
An automotive chassis, anti-oxidation technology, used in polyurea/polyurethane coatings, anti-corrosion coatings, coatings, etc., can solve the problems of ineffective resistance to oxidation and corrosion, and achieve the effect of strong commercial value and excellent weather resistance
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Embodiment 1
[0021] A preparation process of a water-based fluorine-modified polyester anti-oxidative automotive chassis coating:
[0022] The water-based acrylic resin solution, ethylene glycol, triethylhexyl phosphoric acid, defoamer, rust inhibitor, thickener, antioxidant 168, halogen flame retardant and deionized water were introduced into the reactor to stir for 20min-30min, And after nitrogen protection for 10min-13min, add environmentally friendly inorganic pigment and kaolin to the reaction kettle and stir for 20min-30min to obtain an antioxidant coating solution;
[0023] Using monohydroxyfluorocarbon chain monohydric alcohol as organic fluorine modifier, organic fluorine anionic water-based polyester with soft segment containing ionic groups was synthesized through molecular design. The contact angle of organic fluorine anionic water-based polyurethane to water was increased from 73° to 107° °, the water absorption and swelling rate decreased by 66%, and the temperature of the ma...
Embodiment 2
[0026] Based on Embodiment 1, a preparation process of an anti-oxidative automobile chassis coating of water-based fluorine-modified polyester:
[0027] Aqueous acrylic resin solution, propylene glycol, methyl amyl alcohol, defoamer, rust inhibitor, thickener, antioxidant 168, a combination of antioxidant 1010 and antioxidant 1076 oxidant, halogen flame retardant and deionized water are introduced into the reaction Stir in the kettle for 20min-30min, and after nitrogen protection for 10min-13min, add environmentally friendly inorganic pigments and kaolin to the reactor and stir for 20min-30min to obtain an antioxidant coating solution;
[0028] Using hexamethylene diisocyanate (HDI) as the hard segment and polyether diol as the soft segment to synthesize the prepolymer, and using tetrafluorobutanediol as the chain extender to polymerize under ultraviolet light irradiation, fluorine-containing polyester was synthesized, in which fluorine-containing polyester was synthesized. At...
Embodiment 3
[0031] Based on Embodiment 1, a preparation process of an anti-oxidative automobile chassis coating of water-based fluorine-modified polyester:
[0032] Aqueous acrylic resin solution, propylene glycol, methyl amyl alcohol, defoamer, rust inhibitor, thickener, antioxidant 168, a combination of antioxidant 1010 and antioxidant 1076 oxidant, halogen flame retardant and deionized water are introduced into the reaction Stir in the kettle for 20min-30min, and after nitrogen protection for 10min-13min, add environmentally friendly inorganic pigments and kaolin to the reactor and stir for 20min-30min to obtain an antioxidant coating solution;
[0033] The fluorine-containing polyether diol, isophorone diisocyanate (IPDI) and ethylenediamine (EDA) were synthesized into anionic water-based fluorine-containing polyester, isophorone diisocyanate (IPDI) was used as the hard segment, and fluorine-containing Diol is the soft segment, dimethylol propionic acid (DMPA) is the hydrophilic group...
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