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Preparation process of water-based fluorine-modified polyester anti-oxidation automobile chassis coating

An automotive chassis, anti-oxidation technology, used in polyurea/polyurethane coatings, anti-corrosion coatings, coatings, etc., can solve the problems of ineffective resistance to oxidation and corrosion, and achieve the effect of strong commercial value and excellent weather resistance

Pending Publication Date: 2022-07-22
深圳市深赛尔股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Automobile chassis coating is also called automobile chassis armor. Its scientific name is automobile chassis anti-collision, anti-rust and sound-proof primer. It is a high-tech adhesive rubber asphalt coating. Spray on the exposed parts of the vehicle chassis, wheels, fuel tanks, car lower panels, trunks, etc., and form a firm elastic protective layer after quick drying, which can prevent the impact of flying stones and gravel, and avoid moisture, acid rain, and salt on the metal of the vehicle chassis. to prevent the chassis from rusting and rusting, and to protect the driving safety of the car owner, while the automobile chassis coating is often exposed to corrosive substances such as mud during use. The oxidation resistance is essential, but the existing automobile chassis coatings cannot effectively resist oxidation and corrosion. In order to improve the oxidation resistance and corrosion resistance of automobile chassis coatings, a water-based fluorine-modified polyester Preparation Technology of Oxidative Automobile Chassis Coating

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A preparation process of a water-based fluorine-modified polyester anti-oxidative automotive chassis coating:

[0022] The water-based acrylic resin solution, ethylene glycol, triethylhexyl phosphoric acid, defoamer, rust inhibitor, thickener, antioxidant 168, halogen flame retardant and deionized water were introduced into the reactor to stir for 20min-30min, And after nitrogen protection for 10min-13min, add environmentally friendly inorganic pigment and kaolin to the reaction kettle and stir for 20min-30min to obtain an antioxidant coating solution;

[0023] Using monohydroxyfluorocarbon chain monohydric alcohol as organic fluorine modifier, organic fluorine anionic water-based polyester with soft segment containing ionic groups was synthesized through molecular design. The contact angle of organic fluorine anionic water-based polyurethane to water was increased from 73° to 107° °, the water absorption and swelling rate decreased by 66%, and the temperature of the ma...

Embodiment 2

[0026] Based on Embodiment 1, a preparation process of an anti-oxidative automobile chassis coating of water-based fluorine-modified polyester:

[0027] Aqueous acrylic resin solution, propylene glycol, methyl amyl alcohol, defoamer, rust inhibitor, thickener, antioxidant 168, a combination of antioxidant 1010 and antioxidant 1076 oxidant, halogen flame retardant and deionized water are introduced into the reaction Stir in the kettle for 20min-30min, and after nitrogen protection for 10min-13min, add environmentally friendly inorganic pigments and kaolin to the reactor and stir for 20min-30min to obtain an antioxidant coating solution;

[0028] Using hexamethylene diisocyanate (HDI) as the hard segment and polyether diol as the soft segment to synthesize the prepolymer, and using tetrafluorobutanediol as the chain extender to polymerize under ultraviolet light irradiation, fluorine-containing polyester was synthesized, in which fluorine-containing polyester was synthesized. At...

Embodiment 3

[0031] Based on Embodiment 1, a preparation process of an anti-oxidative automobile chassis coating of water-based fluorine-modified polyester:

[0032] Aqueous acrylic resin solution, propylene glycol, methyl amyl alcohol, defoamer, rust inhibitor, thickener, antioxidant 168, a combination of antioxidant 1010 and antioxidant 1076 oxidant, halogen flame retardant and deionized water are introduced into the reaction Stir in the kettle for 20min-30min, and after nitrogen protection for 10min-13min, add environmentally friendly inorganic pigments and kaolin to the reactor and stir for 20min-30min to obtain an antioxidant coating solution;

[0033] The fluorine-containing polyether diol, isophorone diisocyanate (IPDI) and ethylenediamine (EDA) were synthesized into anionic water-based fluorine-containing polyester, isophorone diisocyanate (IPDI) was used as the hard segment, and fluorine-containing Diol is the soft segment, dimethylol propionic acid (DMPA) is the hydrophilic group...

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Abstract

The invention discloses a preparation process of a water-based fluorine-modified polyester oxidation-resistant automobile chassis coating, which comprises the following raw materials: a water-based resin solution, an auxiliary agent, deionized water, an environment-friendly inorganic pigment, a filler, an organic fluorine modifier, isophorone diisocyanate and the like, and comprises the following steps: introducing the water-based resin solution, the auxiliary agent and the deionized water into a reaction kettle, and stirring for 20-30 minutes; adding the environment-friendly inorganic pigment and the filler into the reaction kettle after the nitrogen protection for 10-13 minutes, and stirring for 20-30 minutes, so as to obtain an anti-oxidation coating solution. According to the water-based fluorine-modified polyester anti-oxidation automobile chassis coating provided by the invention, a fluorine-containing compound is combined with a polyester chain extension to generate a fluorine-containing high polymer, and the fluorine-modified polyester and the water-based resin coating are subjected to a mixed reaction to generate a coating product; the paint shows excellent weather resistance, corrosion resistance, ultraviolet resistance, flexibility, pollution resistance and low friction, and has high commercial value.

Description

technical field [0001] The invention relates to the technical field of coating preparation, in particular to a preparation process of an anti-oxidative automobile chassis coating of water-based fluorine-modified polyester. Background technique [0002] Car chassis coating, also known as car chassis armor, its scientific name is car chassis anti-collision anti-rust sound insulation primer, is a high-tech adhesive rubber asphalt coating, it has non-toxic, high coverage, high adhesion, can be It is sprayed on the exposed parts of the vehicle chassis, wheel hub, fuel tank, car lower coaming, trunk and other exposed parts. After quick drying, it forms a firm elastic protective layer, which can prevent the impact of flying stones and gravel, and prevent moisture, acid rain and salt from affecting the metal of the vehicle chassis. The corrosion of the chassis can prevent the chassis from rusting and rusting, and protect the driving safety of the car owner. During the use of the car...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/00C09D175/08C09D151/08C09D175/04C09D5/08C08G18/66C08G18/48C08G18/32C08G18/38C08G18/50C08G18/34C08F283/00C08F220/14C08F220/24
CPCC09D133/00C09D175/08C09D151/08C09D175/04C09D5/08C08G18/6688C08G18/4854C08G18/3206C08G18/3275C08G18/2885C08G18/6666C08G18/3812C08G18/4825C08G18/5015C08G18/348C08G18/6692C08F283/008C08L75/08C08L33/00C08L51/08C08L75/04C08F220/14C08F220/24
Inventor 石素娜刘国民陈柏华
Owner 深圳市深赛尔股份有限公司
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