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High-strength ultrathin rock plate and preparation method thereof

A high-strength, ultra-thin technology, applied in the field of slate, can solve the problems of reducing the modulus of rupture and failure strength, high cost, porosity defects, etc., and achieve the effect of reducing post-processing cracking, reducing internal stress, and low cost

Pending Publication Date: 2022-07-29
FOSHAN DONGPENG CERAMIC +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Because slate is a brittle material, it needs to be cut, polished, drilled, chamfered and other mechanical processing before it is used as a home countertop or panel. According to incomplete statistics, 30% to 50% of slate products will be mechanically processed at present. Cutting cracking, for ultra-thin rock slabs with a thickness of ≤3mm, the cutting cracking rate is higher, which seriously affects the later use of the product, increases production costs, and easy cracking during processing has become a bottleneck restricting the development of rock slabs
[0004] The Chinese patent application with the application number 202010954969.8 discloses a high-strength ceramic rock slab and its preparation method. The patent realizes the high strength of the rock slab by designing different compositions of the rock slab, bottom glaze and top glaze, but requires three In order to achieve the above effect, if there are fluctuations in raw materials of billet, bottom glaze and top glaze in actual production, it is not easy to achieve the purpose of improving the strength of rock slabs
[0005] The Chinese patent application with the application number 202010864905.9 discloses a non-fragile rock slab and its preparation method. The application increases the fracture modulus and failure strength of the rock slab by adding silicon carbide and reinforcing agents to the rock slab raw materials. Silicon reacts at high temperature to produce gas, which is easy to produce pore defects inside the rock slab and on the glaze surface, thereby reducing its fracture modulus and failure strength, and it is difficult to achieve the purpose of improving the fracture modulus and failure strength of the rock slab
[0006] The Chinese patent application with application number 202111178761.2 teaches a process technology for preparing toughened rock slabs with layered cloth in different regions. The application uses layered cloth to prepare the rock slab body and adds tetragonal zirconia to the raw material of the rock slab body Powder, due to the volume expansion of tetragonal zirconia during phase transition, it bridges the crack tip, prevents the crack from expanding and increases the crack induction energy of the toughened slab. The application requires the thickness of the slab to be 6mm-20mm. If the ultra-thin rock slab is made of layered cloth, the thickness of each layer is extremely thin, and it is difficult to achieve uniform cloth when re-distributing, so this method is not suitable for the preparation of ultra-thin rock slabs. Add 3-15% tetragonal zirconia powder, the cost is still high

Method used

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  • High-strength ultrathin rock plate and preparation method thereof
  • High-strength ultrathin rock plate and preparation method thereof
  • High-strength ultrathin rock plate and preparation method thereof

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preparation example Construction

[0048] A preparation method of high-strength ultra-thin slate, used for preparing the above-mentioned high-strength ultra-thin slate, comprises the following steps:

[0049] (1) Prepare rock slab blank and zirconia slurry respectively;

[0050] (2) After spraying the zirconia slurry on the bottom of the cloth mold, the rock slab blank is distributed, and after the cloth is completed, the zirconia slurry is sprayed on the surface of the rock slab blank, and the ultra-thin rock slab body is obtained by pressing and molding, and fired. , to obtain high-strength ultra-thin slate.

[0051] It is worth noting that in this technical solution, zirconia slurry is sprayed on the bottom of the cloth mold before the cloth is distributed. After the cloth is completed, the zirconia slurry is uniformly sprayed on the upper layer of the slate blank. Ultra-thin slate with high strength, zirconia is evenly distributed in the upper and lower surface layers of high-strength ultra-thin slate, and...

Embodiment 1-5

[0060] A preparation method of high-strength ultra-thin rock slab, comprising the following steps:

[0061] (1) Preparation of slate blank and zirconia slurry, wherein, in parts by mass, the raw materials of slate blank include 15-25 parts of calcined bauxite, 15-25 parts of high alumina sand, 15-20 parts of kaolin, 10-15 parts of strong mud and 18-25 parts of diopside, calculated by mass percentage, the content of silicon dioxide in the chemical composition of the slate blank is 50-59%; the zirconia slurry includes 60% of yttrium stabilized oxide Zirconium powder, 0.2% of dispersant and the balance of solvent (water), wherein the yttrium-stabilized zirconia powder is composed of 1.4% of yttrium oxide and the balance of tetragonal zirconia;

[0062] The preparation method of the zirconia slurry is as follows: after mixing the yttrium-stabilized zirconia powder, the dispersant and the solvent (water) according to the formula, grind for 45 minutes to obtain the zirconia slurry; ...

Embodiment 6

[0072] A preparation method of high-strength ultra-thin rock slab, comprising the following steps:

[0073](1) Preparation of slate blank and zirconia slurry, wherein, in parts by mass, the raw materials of slate blank include 21 parts of calcined bauxite, 20 parts of high alumina sand, 18 parts of kaolin, 13 parts of super clay, 22 parts of pyroxene, calculated by mass percentage, the content of silica in the slate blank is 52.39%; the zirconia slurry includes 60% of yttrium-stabilized zirconia powder, 0.2% of dispersant and the balance of solvent (water). ), wherein the yttrium-stabilized zirconia powder is composed of 1.4% yttrium oxide and 98.6% tetragonal zirconia;

[0074] The preparation method of the zirconia slurry is as follows: after mixing the yttrium-stabilized zirconia powder, the dispersant and the solvent (water) according to the formula, grinding for 45 minutes to obtain the zirconia slurry;

[0075] (2) After spraying 2 layers of zirconia slurry on the botto...

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Abstract

The invention discloses a high-strength ultrathin rock plate and a preparation method thereof, and relates to the technical field of rock plates. The high-strength ultrathin rock plate comprises a green body layer, and the top and the bottom of the green body layer are each provided with a zirconium oxide layer; the raw material of the blank layer is a rock plate blank, and the content of silicon dioxide in the chemical composition of the rock plate blank is less than 60% according to the mass percent; and the thickness of the high-strength ultrathin rock plate is less than or equal to 3mm. According to the technical scheme, the zirconium oxide layers are arranged at the top and the bottom of the blank body layer respectively, and zirconium oxide is uniformly distributed on the upper surface layer and the lower surface layer of the high-strength ultrathin rock plate after compression molding and sintering, so that the cracking phenomenon of the thin rock plate during later processing can be greatly reduced.

Description

technical field [0001] The invention relates to the technical field of rock slabs, in particular to a high-strength ultra-thin rock slab and a preparation method thereof. Background technique [0002] In the past two years, slate has become the new favorite of major ceramic companies. The thickness of slate ranges from 3mm to 20mm, and the size ranges from 900*1800mm to 1600*3800mm. There are even 1800*9000mm super-large slate. There are also various types. Ultra-thin slate with a thickness of ≤3mm is not only light in weight, easy to transport and install, but also can reduce the cost of raw materials and increase profits for ceramic enterprises. Ultra-thin slate is used in furniture panels, electrical panels, and walls. It is widely used in decoration and other fields. [0003] Since slate is a brittle material, it needs to be cut, polished, drilled, chamfered and other mechanical processing before being used as a home countertop or panel. Cutting and cracking, the cutti...

Claims

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Application Information

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IPC IPC(8): C04B35/14C04B35/622C04B41/87
CPCC04B35/14C04B35/622C04B41/87C04B41/009C04B41/5042C04B2235/3217C04B2235/349C04B2235/3436C04B2235/3272C04B2235/3232C04B2235/3208C04B2235/3206C04B2235/95C04B2235/3201C04B2235/96C04B41/4501C04B41/4543Y02P40/60
Inventor 赵威李智鸿徐登翔钟保民古文灿
Owner FOSHAN DONGPENG CERAMIC
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