The invention belongs to the technical field of fracturing propping agent materials, and discloses a long-acting stable multi-
solid-waste composite propping agent and a preparation method thereof. According to the proppant, steel
slag,
fly ash and granulated blast-furnace
slag are used as main raw materials, a
mullite-
pyroxene composite mineral phase framework is formed by
sintering at 1120-1260 DEG C by controlling the adding
molar ratio of the raw materials, and the long-term stability of
high density and non-collapsing structure under high temperature and
high pressure is achieved. Fluorosilane and polyphosphinocarboxylic acid are further adopted for surface synergistic
grafting, a
composite film layer with hydrophobic and anti-
pollution functions is constructed, stratum
particle adsorption and inorganic salt scaling are remarkably reduced, and long-term smoothness of a crack flow guide channel is maintained. Results show that the proppant has excellent
mechanical strength and service stability, the long-term flow
conductivity retention rate in a high-temperature and high-
salinity fracturing fluid environment exceeds 90%, the
structural integrity is good, the compressive property reaches 69 MPa or above, and the proppant is suitable for long-term fracturing support requirements of complex reservoirs.