Bioldegradation plastic masterbatch and its preparation method

A biodegradable plastic and masterbatch technology, applied in the field of biodegradable plastic series, can solve the problems of insufficient starch particle size, high cost, high energy consumption, etc., and achieve the effects of improving compatibility, protecting the environment and reducing pollution

Inactive Publication Date: 2004-03-03
叶新建
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are generally two problems in the current various starch-based biodegradable plastics: one is that the particle size of the starch is too large; the other is that there are hydrophilic groups such as hydroxyl groups on the surface of the starch and are incompatible with polymer resins.
For example, using pregelatinized starch, using ethylene / acrylic acid copolymer as a compatibilizer, and then modifying the starch by wet method has solved certain above problems, but there are still starch particle sizes that are not small enough, Shortcomings such as weak production continuity, large energy consumption, large land occupation, large investment, and high cost have resulted in the slow development of biodegradable plastics under the influence of the market economy.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Materials

[0041] Starch Corn starch 100kg, moisture content less than 15%

[0042] Resin High-density polyethylene (HDPE) 60kg and linear low-density polyethylene (LLDPE) 60kg

[0043] Polymers Ethylene / acrylic acid copolymer (EAA) 15kg and ethylene / vinyl acetate copolymer (EVA) 15kg

[0044] Plasticizer polyethylene glycol 5kg

[0045] Lubricant stearic acid 2kg, polyethylene wax 10kg

[0046] Oxidation accelerator corn oil 0.5kg

[0047] Cross-linking modifier formaldehyde 0.5kg

[0048] method

[0049] a. Grind 100kg of cornstarch with a moisture content of less than 15% with a CWJ-100 high-speed ultra-fine unit. The speed of the pulverizer is 2500 rpm, and the linear speed can reach more than 100 m / s. The speed of the classifier is 850 rpm. The crushed starch is detected by a laser particle size tester, and the average particle size is 0.006mm;

[0050] b Put this micronized starch into the high mixer of SHR50L / 1000L high and cold mixing unit. The heating t...

Embodiment 2

[0054] Materials

[0055] Starch Corn starch 100kg, moisture content less than 15%

[0056] Resin Polypropylene (PP) 10kg

[0057] Polymer Ethylene / ethyl acrylate copolymer (EEA) 10kg

[0058] Plasticizer Glycerin 20kg and Ethylene Glycol 20kg

[0059] Lubricant Oxidized polyethylene 20kg and paraffin wax 10kg

[0060] Oxidation accelerator sunflower oil 9kg and manganese stearate 1kg,

[0061] Cross-linking modifier Acetaldehyde 10kg.

[0062] a. Grind 100kg of cornstarch with a moisture content of less than 15% with a CWJ-100 high-speed ultra-fine unit. The speed of the pulverizer is 2500 rpm, and the linear speed can reach more than 100 m / s. The speed of the classifier is 850 rpm. The crushed starch is detected by a laser particle size tester, and the average particle size is 0.006mm;

[0063] b Put this refined starch into the high mixer of SHR500L / 1000L high and cold mixing unit. The heating temperature of the high mixer is 100°C, and the speed is 960 rpm. 10kg to ...

Embodiment 3

[0067] Materials

[0068] Starch Corn starch 100kg, moisture content less than 15%

[0069] Resin Low-density polyethylene (LDPE) 7kg

[0070] Polymer Ethylene / acrylic acid copolymer (EAA) 27kg

[0071] Plasticizer Sorbitol 10kg

[0072] Lubricant polyethylene wax 15kg

[0073] Oxidation accelerator epoxy soybean oil 5kg

[0074] Cross-linking modifier Sodium tripolyphosphate 2kg.

[0075] Method is the same as embodiment 1

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Abstract

A mother particle for bioderadation plastic is prepared from starch, resin, polymer, plasticizer with high boiling point, lubricant and oxidizing degradation promoter, through preparing modified superfine starch, mixing with others, and granulating.

Description

technical field [0001] The invention belongs to the series of biodegradable plastics that can be absorbed in nature, and in particular relates to a biodegradable plastic masterbatch used to produce biodegradable plastic products and a preparation method. technical background [0002] Due to the pollution and public hazards caused by plastic waste, people have long been looking for a biodegradable polymer to replace those non-degradable, petroleum-based plastic materials. There are generally two problems in various starch-based biodegradable plastics at present: one is that the particle size of starch is too large; the other is that there are hydrophilic groups such as hydroxyl groups on the surface of starch, which are incompatible with polymer resins. Therefore, people have done a lot of research on the above problems. For example, using pregelatinized starch, using ethylene / acrylic acid copolymer as a compatibilizer, and then modifying the starch by wet method has solved ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K5/05C08L3/04C08L23/00
Inventor 叶新建
Owner 叶新建
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