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Organic polymeter as electromagnetic shielding material and its prepn process

An electromagnetic shielding material, polymer technology, applied in the direction of magnetic/electric field shielding, electrical components, etc., can solve the problems of insufficient conductivity, poor processability, difficult adjustment of shielding effectiveness, etc., and achieve good vibration resistance and impact resistance , stable electrical and chemical properties, and improved electromagnetic shielding performance

Inactive Publication Date: 2007-03-21
UNIV OF ELECTRONIC SCI & TECH OF CHINA
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  • Application Information

AI Technical Summary

Problems solved by technology

However, they all have the disadvantage of low overall shielding effectiveness.
The reason is that they can only adjust certain influencing factors in the electromagnetic shielding material alone, but cannot adjust the two decisive parameters of electrical conductivity and magnetic permeability at the same time.
At the same time, metals and magnetic ferrites still have shortcomings such as heavy weight, high loss, difficult implementation, and poor regeneration potential, which cannot adapt to the development direction of miniaturization, light weight, and high frequency of electronic devices
Although conductive polymers have overcome the shortcomings of metal materials and magnetic ferrites to a certain extent, they still have problems of poor processability, poor stability, insufficient conductivity, and high prices. It is very difficult to adjust the shielding effectiveness

Method used

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  • Organic polymeter as electromagnetic shielding material and its prepn process
  • Organic polymeter as electromagnetic shielding material and its prepn process
  • Organic polymeter as electromagnetic shielding material and its prepn process

Examples

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Embodiment Construction

[0024] Add 20 g of m-ferrocenylaniline into a three-necked flask containing 100 mL of hydrochloric acid, slowly add an equimolar amount of ammonium persulfate hydrochloric acid solution dropwise, protect with nitrogen, and react at room temperature for 12 hours to obtain a blue-black solid. Filter, wash with hydrochloric acid, distilled water and absolute ethanol in sequence, and dry in vacuum for 12 hours to obtain 18.5 g of the target product. Tetrahydrofuran is used as a solvent, and the number average molecular weight n (polymerization degree) is 180 according to gel chromatography test.

[0025] Mix 4g of the organic polymer electromagnetic shielding material with electric and magnetic properties prepared in the above embodiment with 3g of paraffin wax, melt the paraffin wax, and press a sample with a length of 20.1mm, a width of 10.2mm, and a thickness of 2.91mm with a mold. The conductivity was measured by the four-probe method at 10 -6 ~10S / cm; with HP4291B impedance ...

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Abstract

The organic polymer as electromagnetic shielding material and its preparation process belongs to the field of material science and technology. The organic polymer as electromagnetic shielding material has organic polymer of polymerization degree n of 20-400 in the shown structure as the main component. It is prepared with the monomer with aniline and ferrocene as main material, and through slowly dropping oxidant solution into the monomer solution to polymerize and adding proper amount of dopant. The polymer has in its molecular structure polyaniline as the conducting mother substance and ferrocene as the magnetic radical, so that it has both electric conductivity and magnetism. It has high comprehensive shielding effect, low density, wide applicable frequency range, low temperature coefficient, low magnetic loss and other excellent characteristics, and may find wide application in electromagnetic shielding, wave absorption, etc.

Description

technical field [0001] The invention belongs to functional polymer materials in the field of material technology, in particular to a ferrocene group-containing magnetically conductive high polymer material with polyaniline as a matrix and a preparation method thereof, in particular to the field of electromagnetic shielding applications. Background technique [0002] With the rapid development of modern electronic industry and information industry, the application of various electronic instruments and equipment is also increasing day by day. The main obstacle to the normal functioning of equipment and systems. At the same time, the pollution of electromagnetic waves to human working and living environments has become a serious social problem, threatening human health, and the leakage of electromagnetic radiation often leads to failure of automatic control systems. Risk of misoperation and information theft. [0003] In order to effectively suppress the radiation, leakage and...

Claims

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Application Information

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IPC IPC(8): C08L79/02C08G73/02C08K5/56H05K9/00
Inventor 李元勋刘颖力张怀武燕文琴李少帅
Owner UNIV OF ELECTRONIC SCI & TECH OF CHINA
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