The invention discloses a synthesis method of an MCM-22 family
molecular sieve. The method is characterized by comprising the steps of: adding a
dilute acid water solution into a hexamethyleneimine template agent; adding a
silicon source, an
aluminium source, an alkali source, water and an acidified template agent (R) in proportion so as to prepare gel; conducting hydrothermal
crystallization, opening a valve under constant temperature, carrying out pressure reduced
evaporation to the
molecular sieve slurry, recovering the liquid mixture and the template agent; adding a cold
dilute acid water solution into the residual
slurry, and opening the kettle when the temperature of the residual
slurry drops below 50DEG C, performing
filtration so as to obtain a
solid product, thus obtaining a MCM-22 family
molecular sieve finally. With the method provided in the invention, the template agent no longer volatizes, and damage to the
human body can be avoided. Meanwhile, stability of the synthesis formula and quality of the molecular
sieve is guaranteed. When the template agent is acidified into a salt, the dispersibility is greatly increased, and the obtained MCM-22 family molecular
sieve has a uniform
crystal phase as well as a high degree of
crystallization. After
crystallization, the synthesis slurry is subjected pressure reduced
evaporation and the template agent is recovered. After acidification, the recovered template agent can be used for MCM-22 family molecular
sieve synthesis again.