The invention relates to a method and a device for treating and recycling
copper-containing acid
wastewater of mines. The method comprises the following steps: mixing two wastewaters, namely
copper pit water and
raffinate, in a certain volume proportion, so as to form mixed acid
wastewater; carrying out
fractional precipitation on valuable
heavy metals in the mixed acid
wastewater by virtue of a combined medicament, so as to reduce neutralizing residue and recycle
copper; recycling copper in the acid wastewater through the synergic effect generated in a
metabolic process of chemical precipitates and
sulfate reducing
bacteria; and preparing a compound
fertilizer from organic
sludge generated by virtue of a biochemical method, and reusing the compound
fertilizer in the
rehabilitation and afforesting of the mines. According to the device for implementing the method,
hydrogen sulfide circulating and absorbing equipment is additionally arranged, a reaction device is optimized, and combinedfillers of a
bioreactor are optimized, so that the conversion efficiency of
sulfate reducing
bacteria to SO4<2-> is increased, and the repeated cyclic utilization of
hydrogen sulfide is realized. A process adopted in the method is environment-friendly and has good universality to working conditions of the mines, so that the method has the advantages that the recycling rate of copper in the acid wastewater is more than or equal to 92%, the reduction amount of the neutralizing residue is more than or equal to 70%, the storage capacity pressure of
tailings can be effectively reduced, and the like.