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Special-purpose material for beta nucleater modified random copolymerization polypropylene pipe and preparation method thereof

A polypropylene pipe, random copolymerization technology, used in the field of plastic materials, can solve the problems of decreased tensile strength and tensile modulus, low notched impact strength, poor UV resistance, etc., to improve weather resistance and rigidity. , the effect of excellent mechanical properties

Inactive Publication Date: 2008-04-30
合诚技术股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current disadvantages of random copolymerized polypropylene pipe materials are: the notched impact strength is not high, the thermal expansion coefficient is large when the temperature is higher than 95 ° C, and the temperature is less than 100 ° C and the lower working pressure is very obvious. Creep phenomenon, poor UV resistance, and its moldability, rigidity and heat resistance need to be improved
Generally, the α-nucleating agent increases the crystallinity of polypropylene, thereby increasing the rigidity, while the overall impact strength shows a downward trend. The β-nucleating agent greatly increases the content of β-crystal in polypropylene, and the unique bundle-like aggregation structure of β-crystal When the force is applied, a crack band is produced, which greatly increases the toughness, but the tensile strength and tensile modulus will decrease

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] 55 parts by weight of random copolymerized polypropylene, 30 parts by weight of polypropylene homopolymer, 10 parts by weight of calcium carbonate, 3 parts by weight of ethylene-methyl acrylate copolymer, 1.5 parts by weight of zinc oxide, 0.1 parts by weight of Coupling agent KH550, 0.2 parts by weight of antioxidant B215 and 0.2 parts by weight of silicone release agent are mixed, then melted by twin-screw machine, kneaded, extruded, water cooled, dried, pelletized and packaged, That is, the special material for random copolymerized polypropylene pipes modified by the β-nucleating agent is obtained. The temperature of each section of the barrel of the twin-screw extruder used should be kept at 170-245°C, and the screw speed should be 100r / min. When injecting the sample, the barrel temperature should be 190°C, the mold temperature should be 40°C, and the injection pressure should be 80MPa. The molding cycle is 1min. Preparation of β-nucleating agent modified random co...

Embodiment 2

[0023] 50 parts by weight of random copolymerized polypropylene, 10.5 parts by weight of polypropylene homopolymer, 15 parts by weight of calcium carbonate and 15 parts by weight of talcum powder mixture through 0.3 parts by weight of KH550 coupling agent dry pretreated, 6 parts by weight Parts of ethylene-ethyl acrylate copolymer, 3 parts by weight of zinc oxide, and 0.2 parts by weight of light stabilizer 123S are mixed; then melted, kneaded, extruded, water cooled, dried, pelletized and packaged by a twin-screw machine , that is, special materials for pipes of random copolymerized polypropylene modified by β-nucleating agent are obtained. The temperature of each section of the barrel of the twin-screw extruder used should be kept at 170-245°C, and the screw speed should be 100r / min. When injecting the sample, the barrel temperature should be 195°C, the mold temperature should be 450°C, and the injection pressure should be 90MPa. The molding cycle is 1min. Dry pretreatment ...

Embodiment 3

[0026]80 parts by weight of random copolymerized polypropylene, 5 parts by weight of polypropylene homopolymer, 10 parts by weight of talcum powder pretreated by 0.1 parts by weight of KH560 coupling agent, 3 parts by weight of ethylene-butyl acrylate Copolymer, the calcium oxide of 1.5 parts by weight, the antioxidant tris (2,4-di-tert-butylphenyl) phosphite of 0.2 parts by weight and the stearic acid dispersant of 0.2 parts by weight are mixed; Machine melting, kneading, extrusion, water cooling, drying, pelletizing and packaging to obtain special materials for β-nucleating agent modified random copolymerized polypropylene pipes. The temperature of each section of the barrel of the twin-screw extruder used should be kept at 170-245°C. The screw speed is 100r / min. When injecting the sample, the barrel temperature is 200°C, the mold temperature is 40°C, and the injection pressure is 100MPa. The period is 1min. Dry pretreatment is to put talcum powder and KH560 coupling agent ...

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PUM

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Abstract

The invention discloses special material for a Beta nucleating agent modified polypropylene random copolymer pipe product and the preparation method thereof. The invention includes special material components according to the parts by weight as follows: 50 to 80 parts of polypropylene random copolymer, 5 to 30 parts of polypropylene homopolymer, 10 to 30 parts of inorganic mineral filling agent, 1 to 6 parts of ethylene propylene acid copolymer, 0.5 to 3 parts of metal oxide, 0.1 to 0.3 parts of coupling agent, and 0.1 to 0.5 parts of processing aid. All components are mixed according to the quantity measurement disclosed by the invention, graining is extruded through the fusing of a twin-screw squeezing unit, and the special material for the Beta nucleating agent modified polypropylene random copolymer pipe product of the invention can be prepared. The special material for the Beta nucleating agent modified polypropylene random copolymer pipe product provided by the invention has the advantages that the impact resilience, the heat endurance and the creep resistance are prominent, and the special material can be used to produce cold-hot water delivery pipe products and other hot fluid medium chemical pipelines.

Description

technical field [0001] The invention belongs to the technical field of plastic materials, and in particular relates to a special material for random copolymerized polypropylene pipe material modified by a beta nucleating agent and a preparation method thereof. Background technique [0002] Polypropylene homopolymer (PP-H) has excellent heat resistance and rigidity, and its no-load operating temperature can reach above 130°C. It is widely used in the manufacture of pipelines for conveying hot water and chemical pipelines for conveying other hot fluid media. Its impact resistance is not good at low temperature or even at room temperature, and it is easy to be brittle at low temperature. Random copolymerized polypropylene (PP-R) is a copolymer obtained from propylene and ethylene with a mass content of 3.0-7.0% at a certain temperature, pressure and catalyst. The ethylene monomers are randomly distributed in the long chain of propylene, changing the main The regular state of t...

Claims

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Application Information

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IPC IPC(8): C08L23/14C08K9/00C08L23/12C08L23/08C08K5/524C08K3/00C08K5/54
Inventor 李文国李刚蒋文真
Owner 合诚技术股份有限公司
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