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Chlorine gas decontaminant

A decontamination agent and chlorine gas technology, applied in the direction of dispersed particle separation, chemical instruments and methods, separation methods, etc., can solve the problems of increasing processing steps, chlorine gas hazard transfer, and processing methods to be considered, so as to increase the specific surface area and reduce water pollution. The amount of use, the effect of increasing the reaction rate

Active Publication Date: 2010-12-08
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The physical decontamination method cannot essentially eliminate the impact of chlorine gas on the environment, and if the adsorbent is used, the adsorbed product must be treated, adding treatment steps, and the treatment method has yet to be considered
[0011] The above-mentioned existing traditional methods are difficult to achieve true harmless disposal under a large amount of chlorine gas leakage and harsh environmental conditions, and often cause the harm of chlorine gas to be transferred

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] The sodium oxalate of weighing 96g, joining the mass percent concentration that contains 3g fatty alcohol polyoxyethylene ether sulfosuccinic acid sodium salt (MES) surfactant is in the aqueous solution of 30%, then adds 0.5g polyvinyl alcohol and 0.5g ten Dialkyl dimethyl amine oxide is uniformly blended by ball milling to obtain a chlorine gas decontamination agent.

[0021] Prepare 1L of an aqueous solution with a mass percent concentration of 0.5% using the chlorine gas decontamination agent prepared above; simulate chlorine gas leakage, spray it from the top of the simulated decontamination chamber with a high-pressure water mist nozzle, and test its decontamination effect on chlorine gas. Contrast experiment of decontamination with clean water at the same time. Chlorine gas is prepared by the laboratory preparation method and passed into the simulated decontamination chamber with an initial chlorine gas concentration of 21.209mg / m 3 . The experiment found that f...

Embodiment 2

[0024] Weigh 93g of sodium oxalate, join the mass percent concentration that contains 6.4g fatty alcohol polyoxyethylene ether sulfosuccinic acid sodium salt (MES) surfactant in the aqueous solution of 30%, then add 0.3g polyvinyl alcohol and 0.3g Lauryl dimethyl amine oxide is uniformly blended by ball milling to obtain a chlorine gas decontamination agent.

[0025] Prepare 1L of an aqueous solution with a concentration of 2% by mass using the chlorine gas decontamination agent prepared above; simulate chlorine gas leakage, spray it from the top of the simulated decontamination chamber with a high-pressure water mist nozzle, and test its decontamination effect on chlorine gas. Contrastive experiment of decontamination with water at the same time. Chlorine gas is prepared by the laboratory preparation method and passed into the simulated decontamination chamber with an initial chlorine gas concentration of 15.293mg / m 3 . The experiment found that for the group simulated with...

Embodiment 3

[0028] Weigh the sodium oxalate of 89.8g, join in the aqueous solution that the mass percent concentration that contains 10g fatty alcohol polyoxyethylene ether sulfosuccinic acid sodium salt (MES) surfactant is 30%, add 0.1g polyvinyl alcohol and 0.1g Lauryl dimethyl amine oxide is uniformly blended by ball milling to obtain a chlorine gas decontamination agent.

[0029] Prepare 1L of an aqueous solution with a concentration of 8% by mass using the chlorine decontamination agent prepared above to simulate chlorine gas leakage, spray it from the top of the simulated decontamination chamber with a high-pressure water mist nozzle, and test its decontamination effect on chlorine gas. At the same time, a comparative experiment with water was carried out. Chlorine gas is prepared by the laboratory preparation method and passed into the simulated decontamination chamber with an initial chlorine gas concentration of 22.001mg / m 3 , the experimental results found that, in the group si...

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Abstract

The invention discloses a chlorine decontaminant, which is characterized in that the chlorine decontaminant is prepared by mixing organic reducer accounting for 89.8 percent to 96 percent of the total weight, 3 percent to 10 percent of surfactant, 0.1 percent to 0.5 percent of thickener polyvinyl alcohol (PVA) and 0.1 percent to 0.5 percent of foam stabilizer dodecyl dimethyl amine oxide (DDAO). The organic reducer is chosen from soluble oxalate, citrate or ascorbic acid, starch, glucose, fruit sugar, tartrate, malate or lactate; the surfactant is chosen from polyoxyethylene alkyl ether sulfo-sodium succinate, coco-amide propyl betaine (CAPB), alpha-alkenyl sulfonate sodium, fluorine surfactant or sodium ethoxylated alkyl sulfate. When the decontaminant is carried out, the water solution with the concentration being 0.3 percent to 10 percent (weight percentage) is used and sprayed to the leakage area of chlorine by a fine water atomizing nozzle; the decontaminant of the invention combines physical dilution and chemical reaction, thus inhibiting the diffusion of chlorine and enhancing the reaction ratio, and the remained substances of the reaction are free of contamination and can be easily decomposed.

Description

technical field [0001] The invention belongs to the technical field of chlorine gas decontamination agents, in particular to a chlorine gas decontamination agent containing an organic reducing agent and a surfactant and a preparation method thereof. Background technique [0002] At present, the main treatment methods for chlorine gas leakage include chemical decontamination and physical decontamination. [0003] Existing chemical decontamination methods usually use a large amount of water or add sodium hydroxide, calcium hydroxide or sodium carbonate, sodium bicarbonate to absorb and neutralize chlorine gas. For example, Chinese Patent Publication No. CN1066991A proposes a method for decontaminating chlorine gas leaks, which uses reducing inorganic salts such as sodium thiosulfate, potassium iodide or ammonia water to be dissolved in water and sprayed on the poisoned area or the surface of the contaminated material for reaction absorption; and In the 2006 National Caustic S...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/68B01D53/78
Inventor 胡源伍昱宋磊
Owner UNIV OF SCI & TECH OF CHINA
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