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Chlorine gas decontaminant

A decontamination agent, chlorine technology, applied in the separation of dispersed particles, chemical instruments and methods, separation methods, etc., can solve the problems of increasing treatment steps, chlorine hazard transfer, treatment methods to be considered, etc., to improve specific surface area, reduce water The amount of use, the effect of improving the reaction rate

Active Publication Date: 2008-12-17
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The physical decontamination method cannot essentially eliminate the impact of chlorine gas on the environment, and if the adsorbent is used, the adsorbed product must be treated, adding treatment steps, and the treatment method has yet to be considered
[0011] The above-mentioned existing traditional methods are difficult to achieve true harmless disposal under a large amount of chlorine gas leakage and harsh environmental conditions, and often cause the harm of chlorine gas to be transferred

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Weigh 96g of sodium oxalate, add it to an aqueous solution with a mass percentage concentration of 30% containing 3g of fatty alcohol polyoxyethylene ether sulfosuccinate sodium salt (MES) surfactant, and then add 0.5g of polyvinyl alcohol and 0.5g of ten The dialkyl dimethyl amine oxide is uniformly blended by ball milling to obtain the chlorine decontamination agent.

[0021] Using the chlorine decontamination agent prepared above, prepare 1 L of an aqueous solution with a mass percentage concentration of 0.5%; simulate chlorine leakage, spray it from the top of the simulated decontamination chamber with a high-pressure water mist nozzle, and test its decontamination effect on chlorine. At the same time, it acts as a comparative experiment for decontamination with water. Chlorine gas was prepared by laboratory preparation method and passed into the simulated decontamination chamber. The initial chlorine gas concentration was 21.209mg / m 3 . It was found in the experi...

Embodiment 2

[0024] Weigh 93g of sodium oxalate, add it to an aqueous solution with a mass percentage concentration of 30% containing 6.4g of fatty alcohol polyoxyethylene ether sulfosuccinate sodium salt (MES) surfactant, and then add 0.3g of polyvinyl alcohol and 0.3g of Dodecyl dimethyl amine oxide is uniformly blended by ball milling to obtain chlorine decontamination agent.

[0025] Using the chlorine decontamination agent prepared above, prepare 1 L of an aqueous solution with a mass percentage concentration of 2%; simulate chlorine leakage, spray it from the top of the simulated decontamination chamber with a high-pressure water mist nozzle, and test its decontamination effect on chlorine. Simultaneous effect of water decontamination in a comparative experiment. Chlorine gas was prepared by laboratory preparation method and passed into the simulated decontamination chamber. The initial chlorine gas concentration was 15.293mg / m 3 . The experiment found that, for the group simulated...

Embodiment 3

[0028] Weigh 89.8 g of sodium oxalate, add it to an aqueous solution with a mass percentage concentration of 30% containing 10 g of fatty alcohol polyoxyethylene ether sulfosuccinic acid sodium salt (MES) surfactant, and then add 0.1 g of polyvinyl alcohol and 0.1 g of Dodecyl dimethyl amine oxide is uniformly blended by ball milling to obtain chlorine decontamination agent.

[0029] Using the chlorine decontamination agent prepared above, prepare 1 L of an aqueous solution with a mass percentage concentration of 8%, simulate chlorine leakage, and spray it from the top of the simulated decontamination chamber with a high-pressure water mist nozzle to detect its decontamination effect on chlorine. At the same time, a water comparison experiment was performed. Chlorine gas was prepared by laboratory preparation method and passed into the simulated decontamination chamber. The initial chlorine gas concentration was 22.001 mg / m 3 , the experimental results found that for the grou...

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PUM

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Abstract

The invention discloses a chlorine decontaminant, which is characterized in that the chlorine decontaminant is prepared by mixing organic reducer accounting for 89.8 percent to 96 percent of the total weight, 3 percent to 10 percent of surfactant, 0.1 percent to 0.5 percent of thickener polyvinyl alcohol (PVA) and 0.1 percent to 0.5 percent of foam stabilizer dodecyl dimethyl amine oxide (DDAO). The organic reducer is chosen from soluble oxalate, citrate or ascorbic acid, starch, glucose, fruit sugar, tartrate, malate or lactate; the surfactant is chosen from polyoxyethylene alkyl ether sulfo-sodium succinate, coco-amide propyl betaine (CAPB), alpha-alkenyl sulfonate sodium, fluorine surfactant or sodium ethoxylated alkyl sulfate. When the decontaminant is carried out, the water solution with the concentration being 0.3 percent to 10 percent (weight percentage) is used and sprayed to the leakage area of chlorine by a fine water atomizing nozzle; the decontaminant of the invention combines physical dilution and chemical reaction, thus inhibiting the diffusion of chlorine and enhancing the reaction ratio, and the remained substances of the reaction are free of contamination and can be easily decomposed.

Description

technical field [0001] The invention belongs to the technical field of chlorine gas decontamination agents, in particular to a chlorine gas decontamination agent containing an organic reducing agent and a surfactant and a preparation method thereof. Background technique [0002] At present, the main treatment methods for chlorine leakage are chemical decontamination and physical decontamination. [0003] Existing chemical decontamination methods usually use a large amount of water or water added with sodium hydroxide, calcium hydroxide or sodium carbonate, sodium bicarbonate to absorb and neutralize chlorine gas. For example, Chinese Patent Publication No. CN1066991A proposes a method for decontamination of chlorine leakage, which is dissolved in water with reducing inorganic salts such as sodium thiosulfate, potassium iodide or ammonia, and sprayed on the surface of the contaminated area or contaminated material to react and absorb; In the Proceedings of the National Caust...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/68B01D53/78
Inventor 胡源伍昱宋磊
Owner UNIV OF SCI & TECH OF CHINA
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