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Polymer solid sheet type tantalum electrolyte capacitor and its manufacturing method

A technology of tantalum electrolytic capacitors and manufacturing methods, which is applied in the direction of solid electrolytic capacitors, electrolytic capacitors, capacitors, etc., can solve the problems of limited frequency of use, large cathode impedance, and capacitors that cannot be used in high-frequency circuits, and achieve improved safety and excellent high performance. The effect of frequency performance

Active Publication Date: 2011-04-13
BEIJING 718 YOUYI ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The high impedance of the capacitor, especially the high high-frequency impedance, will make the inductive reactance of the capacitor also high. The inductance and impedance of the capacitor will become capacitive reactance with the increase of frequency, resulting in a decrease in the capacity of the capacitor, which makes this capacitor unable to operate Higher frequencies maintain a certain capacity
This kind of capacitor cannot be used in high-frequency circuits. If it is used in a high-frequency circuit, the capacitor capacity will decrease with the increase of frequency.
[0003] Tantalum electrolytic capacitors with excellent performance in various circuits have the above-mentioned shortcomings. The capacity and test or use frequency of tantalum electrolytic capacitors are as follows: figure 1 The relationship shown: that is, when the test or use frequency increases to a certain value, the capacity of the tantalum electrolytic capacitor will decrease with the increase of frequency, and when the frequency increases to the same resonant frequency as the tantalum electrolytic capacitor, the capacity of the tantalum electrolytic capacitor will decrease loss, and becomes an inductor
[0004] The reason for this phenomenon of tantalum electrolytic capacitors is that the cathode of ordinary chip tantalum electrolytic capacitors uses manganese dioxide, an electronic conductivity type semiconductor material, which makes the cathode impedance of chip tantalum electrolytic capacitors larger, which in turn makes the inductance and impedance of tantalum electrolytic capacitors It will become a capacitive reactance with the increase of frequency, resulting in a decrease in the capacity of tantalum electrolytic capacitors, and the existing technology can no longer make the high-frequency impedance of tantalum electrolytic capacitors lower through process technology, so that chip tantalum electrolytic capacitors with excellent performance are due to high frequency Impedance [ESR] is high, the frequency of use is strictly limited, and it is almost impossible to use it in circuits with operating frequencies above the MHZ level
However, due to the rapid development of microelectronics technology, the main operating frequency of ordinary processors in existing microelectronic circuits may reach MHZ or above. In digital circuits with complex logic operations, the operating frequency is higher, so the use of carbon dioxide Chip tantalum electrolytic capacitors with manganese as the cathode basically cannot be used as filter elements in such circuits
This shortcoming of tantalum electrolytic capacitors greatly limits the application range of chip tantalum electrolytic capacitors

Method used

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  • Polymer solid sheet type tantalum electrolyte capacitor and its manufacturing method
  • Polymer solid sheet type tantalum electrolyte capacitor and its manufacturing method
  • Polymer solid sheet type tantalum electrolyte capacitor and its manufacturing method

Examples

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Embodiment 1

[0043] This embodiment provides a polymer solid chip tantalum electrolytic capacitor. The tantalum electrolytic capacitor uses a polymer conductive material as the cathode, which effectively reduces the high-frequency impedance of the tantalum electrolytic capacitor. image 3 , Figure 4 As shown, the tantalum electrolytic capacitor specifically includes:

[0044] A tantalum capacitor particle 3 is provided in an epoxy resin packaging case 1, and the tantalum capacitor particle 3 is composed of a tantalum block anode 21 with a tantalum wire lead-out wire 5, a dielectric layer 22, and a polymer cathode layer 23. The tantalum block anode 21 The external coating dielectric layer 22, the dielectric layer 22 external coating polymer cathode layer 23, the polymer cathode layer 23 is made of polythiophene material (3,4 ethylenedioxythiophene, English abbreviation PEDT, specific structural formula see figure 2) is a structural layer formed by polymerization on the outer dielectric l...

Embodiment 2

[0066] This embodiment provides a method for manufacturing a polymer solid chip tantalum electrolytic capacitor, specifically as follows:

[0067] (1) Anode formation: Press tantalum powder with a specific volume of 7000uF.v / g into a compact of tantalum wire lead-out wire at a pressing density of 6 mg / CC, at a temperature of 1700°C and a vacuum of 5×0.0004Pa The anode compact is obtained after vacuum high-temperature sintering;

[0068] (2) Dielectric layer is formed: in the nitric acid solution of 0.4%, adopt the DC voltage of 60V as forming voltage, the current density of 80 milliampere / gram in step (1) the surface of the anode compact that sinters obtains uses electrochemical method To form a dielectric layer, the thickness of the dielectric layer can be controlled according to the withstand voltage set by the capacitor to be prepared. If it is thicker, the electrochemical formation time can be controlled longer, and if it is shorter, the control time can be shorter;

[00...

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Abstract

The invention discloses a polymer solid chip Ta electrolytic capacitor and a preparation method thereof; wherein, the capacitor comprises Ta capacitor grains which are arranged in an encapsulation shell; the Ta capacitor grain consists of a Ta anode with a Ta eduction wire, a medium layer and a polymer cathode layer; the Ta anode is covered by the medium layer which is covered by the polymer cathode layer, the high-frequency conductivity of which is 20S / cm; the Ta eduction wire of the Ta anode is electrically connected with the anode eduction wire of the encapsulation shell; the polymer cathode layer is electrically connected with the cathode eduction wire of the encapsulation shell; the Ta electrolytic capacitor takes a 3, 4-ethylene dioxythiophene PEDT layer as the cathode so as to leadthe cathode resistance of the Ta electrolytic capacitor to be reduced by one magnitude compared with the MnO2 cathode and to improve the working frequency by 1-2 magnitude; the Ta electrolytic capacitor has excellent high-frequency performance, effectively improves the safety, and generates no combustion or explosion as the products which take the MnO2 as the cathode when accidental breakdown occurs during the usage process.

Description

technical field [0001] The invention relates to the field of electronic components, in particular to a polymer solid chip tantalum electrolytic capacitor and a manufacturing method thereof. Background technique [0002] The high impedance of the capacitor, especially the high high-frequency impedance, will make the inductive reactance of the capacitor also high. The inductance and impedance of the capacitor will become capacitive reactance with the increase of frequency, resulting in a decrease in the capacity of the capacitor, which makes this capacitor unable to operate Higher frequencies maintain a certain capacity. This kind of capacitor cannot be used in high-frequency circuits. If it is used in a circuit with high frequency, the capacitor capacity will decrease with the increase of frequency. [0003] Tantalum electrolytic capacitors with excellent performance in various circuits have the above-mentioned shortcomings. The capacity and test or use frequency of tantalum...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G9/15H01G9/042H01G9/048H01G9/08H01G9/008
Inventor 祁怀荣
Owner BEIJING 718 YOUYI ELECTRONICS