Compound insecticidal aqueous emulsion containing abamectin and chlorpyrifos, and preparation method thereof
A technology of abamectin and water-emulsion, applied in the field of pesticides, can solve the problems of non-negligible chronic toxicity, many organic chemical materials, difficult removal and separation, etc., achieve good emulsifiable oil stability, improve insecticidal efficacy, and reduce production cost effect
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Embodiment 1
[0025] Embodiment 1: 15% Avi. Chlorpyrifos emulsion in water
[0026] Composition in weight percent: 0.2% abamectin, 14.8% chlorpyrifos, 10% xylene, 6% emulsifier WELL-102 (produced by Fujian Well Biochemical Technology Co., Ltd., which consists of calcium dodecylbenzenesulfonate and three The mixture of phenylethylphenol polyoxypropylene polyoxyethylene block polymer, the weight ratio is 33:67), 5% urea, 0.5% aluminum magnesium silicate, 0.05% silicone defoamer, 0.5% TBHQ, the balance for water.
[0027] According to the formula given above, first dissolve avermectin and chlorpyrifos original drug with xylene solvent, then add WELL-102 emulsifier, urea antifreeze agent, magnesium aluminum silicate thickener, and stabilizer TBHQ to form the oil phase , then slowly add water while stirring, the system gradually thickens, when it reaches the thickest point (that is, the phase inversion point), slow down the stirring speed, and finally make up the remaining water, add silicone d...
Embodiment 2
[0035] Embodiment 2: 35% Avi. Chlorpyrifos emulsion in water
[0036] Composition by weight percentage: 0.5% abamectin, 34.5% chlorpyrifos, 5% methanol, 15% xylene, 7% WELL-102, 3% ethylene glycol, 0.5% xanthan gum, 0.05% silicone defoamer, 0.5% BHA, balance water.
[0037] According to the formula given above, first dissolve abamectin and chlorpyrifos in xylene solvent, then add WELL-102 emulsifier, ethylene glycol antifreeze, xanthan gum thickener, and stabilizer BHA to form oil Then slowly add water while stirring, and the system will gradually thicken. When it reaches the thickest point (that is, the phase inversion point), slow down the stirring speed, and finally make up the remaining water, add silicone defoamer, high The shearing machine shears for about 1 hour (rotational speed 2950rmp), promptly obtains the water emulsion.
[0038] Its physical and chemical performance index values are as follows:
[0039] Abamectin B 1 Quality score, % 0.5
[0040] Chlorpyrif...
Embodiment 3
[0045] Embodiment 3: 31% Avi. Chlorpyrifos emulsion in water
[0046] Composition in weight percent: 1.0% abamectin, 30% chlorpyrifos, 5% cyclohexanone, 15% xylene, 7% emulsifier (calcium dodecylbenzenesulfonate: triphenylethylphenol polyoxypropylene polyoxygenate The weight ratio of ethylene block polymer 1601 is 38:62), 5% propylene glycol, 0.3% xanthan gum, 0.05% silicone defoamer, 0.5% BHA, and the balance is water.
[0047] According to the formula given above, first dissolve abamectin and chlorpyrifos original drug with cyclohexanone and xylene solvent, then add emulsifier, propylene glycol antifreeze agent, xanthan gum thickener, and stabilizer BHA to form the oil phase , then slowly add water while stirring, the system gradually thickens, when it reaches the thickest point (that is, the phase inversion point), slow down the stirring speed, and finally make up the remaining water, add silicone defoamer, high shear The machine sheared for about 0.5 hour (rotating speed ...
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