Method for preparing biodiesel
A biodiesel and solution technology, applied in the preparation of biological raw materials, biofuels, liquid hydrocarbon mixtures, etc., can solve the problems of waste, environmental pollution, affecting the economic benefits of enterprises, and achieve the effect of reducing pollution and improving the economic benefits of enterprises
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Embodiment 1
[0018] (1) Extraction of fish oil: take 2.5kg of processed mackerel head, wash it, put it in a pressure cooker, cook it for 60 minutes at 1MPa pressure and 100°C, take it out and mash it, add 2.5kg of organic solvent petroleum ether, and stir One hour, centrifugal filtration;
[0019] (2) Remove impurities: add 1.5 kg of 35% phosphoric acid aqueous solution to the filtrate for extraction, wash with water until neutral, concentrate the organic phase under reduced pressure to remove petroleum ether, and dehydrate through polyhydroxy water-absorbing resin;
[0020] (3) transesterification reaction: add 120 g of anhydrous methanol and 10 g of NaOH solid, heat up to 60 degrees, stir and react for 2 hours, and filter;
[0021] (4) Separation and purification of biodiesel: the filtrate was allowed to stand for stratification, the lower layer of glycerol was removed, the upper layer of liquid was washed with water, and the water phase was removed to obtain 650 g of biodiesel.
Embodiment 2
[0023] (1) Extraction of fish oil: take the processed mackerel fish bones, remove the tail, wash, weigh 3.8kg, put them in a pressure cooker, cook at 1.1MPa pressure and 110°C for 20 minutes, take them out and mash them, add 7.6 kg organic solvent ethyl acetate, stirred for one hour, and centrifugally filtered;
[0024] (2) Remove impurities: the filtrate is extracted by adding 1 kg of 40% phosphoric acid aqueous solution, washed to neutrality, the organic phase is concentrated under reduced pressure to remove ethyl acetate, and dehydrated by polyhydroxy water-absorbing resin;
[0025] (3) transesterification reaction: add 80 g of absolute ethanol and 6 g of KOH solid, heat up to 60 degrees, stir and react for 1.5 hours, filter, and the filtrate is layered;
[0026] (4) Separation and purification of biodiesel: remove the lower glycerol. The upper liquid was washed with water, and the water phase was removed to obtain 500 g of biodiesel.
Embodiment 3
[0028] (1) Extraction of fish oil: wash 4.5kg of mackerel viscera, put it in a pressure cooker, cook at 1.2MPa pressure and 120°C for 35 minutes, add 6kg of organic solvent ethyl acetate, stir for one hour, and centrifuge;
[0029] (2) Remove impurities: add 2.5 kg of 45% phosphoric acid aqueous solution to the filtrate for extraction, wash with water until neutral, concentrate the organic phase under reduced pressure, remove ethyl acetate, and dehydrate through polyhydroxy water-absorbing resin;
[0030] (3) Transesterification reaction: add 200 g of absolute ethanol and 20 g of NaOH solid, heat up to 65 degrees, stir and react for 2 hours, filter, and the filtrate is layered;
[0031] (4) Separation and purification of biodiesel: remove the lower glycerol. The upper liquid was washed with water, and the water phase was removed to obtain 1.2 kg of biodiesel.
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