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Anticorrosion epoxy powder paint used outside marine steel pipe pile

A technology of epoxy powder and steel pipe piles, applied in anti-corrosion coatings, epoxy resin coatings, coatings, etc., can solve the problem of poor protection performance, coating anti-corrosion life that does not meet the ideal requirements, marine biological fouling, etc. problem, to achieve the effect of good scratch resistance

Active Publication Date: 2010-06-09
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the above anti-corrosion coatings have poor self-protection performance, and they only have a life span of 5 to 20 years in the marine environment. In the tidal zone and splash zone, the coating fails faster due to long-term erosion and impact factors. Due to the overprotection effect of cathodic protection in the full immersion area or submud area, the coating is easy to peel off under the damage of hydrogen evolution and alkaline degradation, and marine organisms are easy to adhere to cause fouling and other effects, and the anti-corrosion life of the coating is not ideal requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment 1SEBF-6-1

[0027] A marine steel pipe pile external anti-corrosion epoxy powder coating SEBF-6-1, its formula is shown in Table 1.

[0028] The formula (percentage by weight) of table 1 coating SEBF-6-1

[0029] raw material

Phenolic modification

permanent epoxy

resin

Bisphenol

A ring

Oxygen tree

fat

linear

Phenolic

to solidify

agent

Phenols

to solidify

agent

2-phenyl

imidazole

Silane

coupling

agent

gas phase

white carbon

black

modified

poly four

Fluorine ethyl

olefin wax

Glass

pink

talcum powder

+Silicon Micro

powder+cloud

mother powder

Tripolyphosphate

Aluminum + iron red

Rutile Titanium

white powder + oxygen

Cuprous chloride

color

material

SEBF-6-1

40~60

0~20

0~10

15...

Embodiment 2

[0032] Example 2SEBF-6-2

[0033] A marine steel pipe pile external anti-corrosion epoxy powder coating SEBF-6-2, its formula is shown in Table 2.

[0034] The formula (percentage by weight) of table 2 coating SEBF-6-2

[0035] raw material

Phenolic modification

permanent epoxy

resin

Bisphenol

A ring

Oxygen tree

fat

linear

Phenolic

to solidify

agent

Phenols

to solidify

agent

2-phenyl

imidazole

Silane

coupling

agent

gas phase

white carbon

black

modified

poly four

Fluorine ethyl

olefin wax

Glass

pink

talcum powder

+Silicon Micro

powder+cloud

mother powder

Tripolyphosphate

Aluminum + iron red

Rutile Titanium

white powder + oxygen

Cuprous chloride

color

material

SEBF-6-2

40~60

0~20

5~10

10~20...

Embodiment 3

[0038] Example 3SEBF-6-3

[0039] A marine steel pipe pile external anti-corrosion epoxy powder coating SEBF-6-3, its formula is shown in Table 3.

[0040] The formula (percentage by weight) of table 3 coating SEBF-6-3

[0041] raw material

Phenolic

modified

epoxy

resin

Bisphenol

A ring

Oxygen tree

fat

linear

Phenolic

to solidify

agent

Phenols

to solidify

agent

2-phenyl

imidazole

Silane

coupling

agent

gas phase

white carbon

black

Phenylbenzo

Triazole UV

thread absorber

and hindered amine

light stabilizer

change

sex

get together

Four

fluorine

Second

ene

wax

Glass

pink

talc

Powder+

silicon micro

Powder+

Mica

pink

...

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PUM

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Abstract

The invention provides an anticorrosion epoxy powder paint used outside a marine steel pipe pile, which is characterized by comprising resin, a curing agent, an accelerant, a coupling agent, an edge covering agent, a special function auxiliary agent, a stuffing, a pigment and the like, and the formula of the anticorrosion epoxy powder paint comprises the following components in percentage by weight: 40-60 percent of phenol-modified epoxy resin, 0-20 percent of bisphenol A epoxy resin, 0-20 percent of linear phenol curing agent, 5-25 percent of phenol curing agent, 0.3-1.5 percent of 2-phenylimidazole, 0.2-1 percent of silane coupling agent, 0.2-3 percent of gas phase white carbon, 0-2 percent of hydroxy-phenyl benzotriazole ultraviolet absorbent and hindered amine light stabilizer, 0-5 percent of modified polyfluortetraethylene wax, 5-25 percent of glass powder, 5-30 percent of talcum powder, silicon powder and mica powder, 5-10 percent of aluminium triphosphate, iron red, rutile titanium pigment and cuprous oxide and 0-3 percent of pigment. The paint SEBF-6 has the advantages that the surface roughness of a coating satisfies the required built-in strength of a steel pile and the marine geological condition of the steel pile, and the paint has the characteristics of excellent scratch resistance, shock resistance, abrasion resistance, marine biological fouling resistance, ageing resistance, ultraviolet irradiation resistance and the like.

Description

technical field [0001] The present invention relates to the anti-corrosion technology of marine engineering steel structure, specifically, generally refers to the long-term anti-corrosion technology of the outer wall of steel pipe piles and steel sheet piles. Background technique [0002] Steel piles, including steel pipe piles and steel sheet piles, are metal structure support materials widely used in marine foundation projects such as piers, bridges, offshore platforms, and wind power stations. Due to the harsh corrosion environment of the ocean, steel piles made of ordinary steel The annual corrosion rate reaches 1-2 mm / year, and the rate of pitting corrosion due to defects caused by the manufacturing and installation process and the local corrosion caused by the residence of marine organisms is several times greater than that of uniform corrosion. The earliest service life of 20 to 30 years has been increased to the durability requirement of more than 100 years. It is ur...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D5/08
Inventor 陆卫中李京史杰智高英李晓东张立新
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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