Anti-wave emergency restoration process for polluted natural water body

An emergency repair and anti-storm technology, which is applied in the direction of flotation water/sewage treatment, flocculation/sedimentation water/sewage treatment, etc., can solve the problems such as difficult to form effective communities, slow processing speed, technically difficult to repair, etc., to extend the stability time Effect

Inactive Publication Date: 2010-07-28
QUANZHOU NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage is poor adaptability. In deep water, highly turbid water, sea areas, estuary areas with frequent changes in salinity, when the temperature is too low or too high, the wind and waves are strong, and the polluted waters are particularly serious, it is difficult for specific organisms to survive or It is difficult to form an effective community, making it difficult for this type of technology to implement restoration
[0006] 2. Physical remediation technology, mainly including artificial aeration, sewage interception and filtration, water diversion and flushing, river dredging and other measures to transfer pollutants. The repair cost is high and the processing speed is slow. Usually, it cannot be used as a rapid repair process, and it is easy to cause Leakage or secondary pollution
[0012] However, the inventors found in repeated experiments that the material can indeed capture about 90% of mature conglomerated algae, but cannot remove colloidal algae spores and scattered juvenile unicellular algae, let alone remove eutrophication in water Chemical substances such as phosphorus, which cause the restored water body to still have more algae and reproduce rapidly
At the same time, the material is only used for oil, and heavy metal pollution treatment is not feasible
Its main defect is that: the material is composed of fibers and flocculants. Theoretically, the flocculants can only bridge the net to catch suspended solids, and have poor flocculation ability, so they are ineffective for colloids and dissolved substances; the role played by fibers here is mainly It is to absorb the algae group containing flocculant and also play a role in strengthening the aggregate
However, there are still some shortcomings: 1. The electric float needs to be repaired and the water body can conduct electricity, which is not suitable for use in freshwater waters; 2. The magnetic separation technology requires the water body to be repaired to be shallow water, otherwise the equipment is difficult to install and provide a magnetic field; 3. Including dissolved air All these methods, including floating, have the disadvantage of a. The fragility of flocs cannot be solved. Therefore, in natural rivers, seas and lakes with moderate wind waves and complex hydrological conditions, flocs are easily scattered by wind waves or turbulence, and cannot be captured efficiently or Floating to the surface causes restoration to fail
b. For slightly larger and deeper water bodies, it is necessary to establish an air flotation platform to collect floating flocs, otherwise a large number of air flotation equipment is required, and the investment is too high. However, the disadvantage that still exists after using the platform is that the clean polluted area will be damaged due to untreated Regional polluted water flows are polluted again

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Example 1 Rapid restoration process of algae and phosphorus in landscape water (use hydrogen peroxide to generate gas, or use KMnO 4 / H 2 O 2 Two-component system to treat algae water bodies, currently not retrieved)

[0025] Add chrysotile fibers of 0.01-1% by weight of the water body into the landscape water containing algae through the pipeline, and then add a commercial polyaluminum chloride (flocculant, product containing a large amount of polyferric chloride impurities) aqueous solution, and the amount of water is 0.01~1% by weight. 0.1%, then use another pipe to add 0.5% to 10% concentration of hydrogen peroxide solution, equivalent to H 2 O 2 The dosage is 0.005~0.05%. The role of polyaluminum chloride is to convert dissolved phosphorus into suspended aluminum phosphate, eliminate the main nutrient phosphorus in the water, and initially flocculate algae, spores and other suspended matter together. The role of hydrogen peroxide is to kill algae and its spores throug...

Embodiment 2

[0030] Example 2 Emergency repair process for water polluted by organic matter

[0031] In benzene-contaminated water, an aqueous suspension of coke powder is preliminarily introduced for adsorption. The input amount is usually 50 to 1000 times the benzene content, and the adsorption treatment time is generally more than 1 hour. Then, 0.02-0.1% conventional aluminum salt is used as a flocculant. At this time, a large number of small black flocs are produced in the water body, and the phenyl group is trapped in the black flocs, and the water body is black and turbid.

[0032] Take the aluminum silicate fiber of 0.01-1% by weight of the water body and 0.001-0.2% PAM before mixing with water, and then add it to the water to be treated. The high-pressure dissolved gas water (pre-manufactured on the Plaque dissolved gas system and stored in the dissolved gas (In the tank) discharged into the water body for fiber-reinforced floc / air flotation. At this time, the black water body becomes...

Embodiment 3

[0036] Example 3 An emergency repair process of self-air-floating heavy metal polluted water body (the current technology also does not report Mg / Fe 3 O 4 Composite material synthesis, and examples of its use in water restoration)

[0037] Use 20g of copper sulfate and muddy river water with turbidity to make 1000L of simulated heavy metal polluted water body, and leave it for 72 hours. After filtration, the free copper content in the water is about 2 mg / l. The copper content in suspended matter is about 61mg / l, and the copper content in bottom mud is 135mg / l.

[0038] Add citric acid to the water body to make the concentration about 100mg / l, so that the copper ions adsorbed on the suspended impurities and bottom mud of the water body are converted into citric acid complexed copper ions into the water. Take 0.05-0.1% of the weight of the water body rock wool fiber into the water and mix, and then add Na3T-15 (a heavy metal trap, produced by Korea Harano Chemical Co., Ltd.) in the ...

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PUM

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Abstract

The invention discloses an anti-wave emergency restoration process for a polluted natural water body. In a system for processing the water body by a flocculation method, short fibers accounting for 0.005 to 1 percent of the weight of the water body and a flocculating auxiliary agent accounting for 0.001 to 0.2 percent of the weight of the water body are added and the flocculating auxiliary agent can be cross-linked with a flocculating agent. The process comprises the following steps: firstly, adding the short fibers into the water body in advance or before the addition of the flocculating auxiliary agent and adding the flocculating auxiliary agent after the addition of the flocculating agent; secondly, generating microbubbles in the water body by using materials spontaneously generating gas to make compound flocs catch the microbubbles and achieve a compression compact effect during rising; and finally, catching the flocs and finishing the emergency restoration. The emergency restoration process can be suitable for performing restoration in the various natural water bodies with slight wind waves and complex hydrological conditions and fulfills the aim that the flocs cannot be easily destroyed by the wind waves within certain time, thereby effectively removing pollutants from the water body and solving the problem of effectively removing the pollutants from the water body in a low cost in the presence of wind waves.

Description

Technical field [0001] The invention relates to an emergency repair process for contaminated natural water bodies capable of resisting wind and waves. technical background [0002] Natural water pollution is currently an important environmental protection problem faced by all countries in the world. It is characterized by the uneven distribution of pollutants in water, suspended solids and bottom mud. The ultimate goal of pollution remediation is to remove the pollutants from the water body and restore the normal state of the water body. The key point that is different from industrial sewage treatment is that natural water treatment can be carried out in mild wind and waves, and it is impossible to have the same complete equipment as industrial sewage treatment. [0003] At present, the main repair types in the world are: [0004] 1. Bioremediation technology, mainly using higher aquatic plants and microorganisms, through artificial biological floating islands (initiated by German ...

Claims

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Application Information

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IPC IPC(8): C02F1/56C02F1/24
Inventor 陈楷翰
Owner QUANZHOU NORMAL UNIV
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